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Petrological study of spinel peridotites of Nidar ophiolite, Ladakh Himalaya, India

Abstract

Petrological study of the ultramafic rocks from the Nidar Ophiolite Complex (NOC) of the Indus Suture Zone is carried out. The study of Cr-spinels along with olivine and pyroxenes emphasizes the genesis and tectonic setting of the ultramafites. Olivine from the harzburgite is Mg-rich, with the molar ratio Mg# [Mg/(Mg + Fe2+)] varying between 0.91 and 0.94 and olivine in dunite between 0.92 and 0.94. Clinopyroxene from the harzburgite is TiO2 and Na2O-poor diopside (Wo47–50En47–50Fs2–4). Spinel in harzburgite shows wide Cr#, molar ratio varied between 0.26 and 0.72, and significantly higher in dunites with Cr# ranges from 0.69–0.85. Cr# of the peridotite spinel follow a depletion trend. Calculated equilibrium conditions of the samples are 800–900°C temperature, 32 and 40 kbar pressure, oxygen fugacity −0.09 to 0.55 log units above the FMQ buffer. Residual nature of the harzburgites and the presence of high and low Cr# spinels may be due to the genetic artifact of the different ultramafic units.

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References

  1. Ahmed A H, Arai S, Abdel-Aziz Y M and Rahimi A 2005 Spinel composition as a petrogenetic indicator of the mantle section in the Neoproterozoic Bou Azzer ophiolite, Anti-Atlas, Morocco; Precamb. Res. 138(3–4) 225–234.

  2. Ahmad T, Tanaka T, Sachan H K, Asahara Y, Islam R and Khanna P P 2008 Geochemical and isotopic constraints on the age and origin of the Nidar Ophiolitic Complex, Ladakh, India: Implications for the Neo-Tethyan subduction along the Indus suture zone; Tectonophys. 451 206–224.

  3. Aldanmaz E, Schmidt M W, Gourgaud A and Meisel T 2009 Mid-ocean ridge and supra-subduction geochemical signatures in spinel-peridotites from the Neotethyan ophiolites in SW Turkey: Implications for upper mantle melting processes; Lithos 113 691–708, https://doi.org/10.1016/j.lithos.2009.03.010.

  4. Arai S 1992 Chemistry of chromian spinel in volcanic rocks as a potential guide to magma chemistry; Mineral. Mag. 56 173–184.

  5. Arai S 1994a Compositional variation of olivine-chromian spinel in Mg-rich magmas as a guide to their residual spinel peridotites; J. Volcan. Geotherm. Res. 59 279–293.

  6. Arai S 1994b Characterization of spinel peridotites by olivine–spinel compositional relationships: Review and interpretation; Chem. Geol. 113 191–204, https://doi.org/10.1016/0009-2541(94)90066-3.

  7. Arai S, Okamura H, Kadoshima K, Tanaka C, Suzuki K and Ishimaru S 2011 Chemical characteristics of chromian spinel in plutonic rocks: Implications for deep magma processes and discrimination of tectonic setting; Isl. Arc 20 125–137; https://doi.org/10.1111/j.1440-1738.2010.00747.x.

  8. Ballhaus C, Berry R F and Green D H 1990 Oxygen fugacity controls in the Earth’s upper mantle; Nature 348(6300) 437–440.

  9. Ballhaus C, Berry R F and Green D H 1991 High-pressure experimental calibration of the olivine orthopyroxene-spinel oxygen barometer: Implications for the oxidation state for the upper mantle; Contrib. Mineral. Petrol. 107 27–40.

  10. Batanova V G, Suhr G and Sobolev A V 1998 Origin of geochemical heterogeneity in the mantle peridotites from the Bay of Islands ophiolite, Newfoundland, Canada: Ion probe study of clinopyroxenes; Geochim. Cosmochim. Acta 62(5) 853–866.

  11. Bédard É, Hébert R, Guilmette C, Lesage G, Wang C S and Dostal J 2009 Petrology and geochemistry of the Saga and Sangsang ophiolitic massifs, Yarlung Zangbo Suture Zone, Southern Tibet: Evidence for an arc–back-arc origin; Lithos 113(1) 48–67.

  12. Bodinier J L, Garrido C J, Chanefo I, Bruguier O and Gervilla F 2008 Origin of pyroxenite–peridotite veined mantle by refertilization reactions: Evidence from the Ronda peridotite (Southern Spain); J. Petrol. 49(5) 999–1025.

  13. Choi S H, Shervais J W and Mukasa S B 2008 Supra-subduction and abyssal mantle peridotites of the Coast Range ophiolite, California; Contrib. Mineral. Petrol. 156(5) 551.

  14. Coish R A and Gardner P 2004 Suprasubduction-zone peridotite in the northern USA Appalachians: Evidence from mineral composition; Mineral. Mag. 68(4) 699–708.

  15. Das S, Mukherjee B K, Basu A R and Sen K 2015 Peridotitic minerals of the Nidar ophiolite in the NW Himalaya: Sourced from the depth of the mantle transition zone and above; Geol. Soc. Spec. Publ. 412(1) 271–286.

  16. Das S, Basu A R and Mukherjee B K 2017 In-situ peridotitic diamond in Indus ophiolite sourced from hydrocarbon fluids in the mantle transition zone; Geology 45(8) 755–758.

  17. Dick H J B and Bullen T 1984 Chromian spinel as a petrogenetic indicator in abyssal and Alpine-type peridotites and spatially associated lavas; Contrib. Mineral. Petrol. 86(1) 54–76.

  18. Dijkstra A H, Barth M G, Drury M R, Mason P R and Vissers R L 2003 Diffuse porous melt flow and melt‐rock reaction in the mantle lithosphere at a slow‐spreading ridge: A structural petrology and LA‐ICP‐MS study of the Othris Peridotite Massif (Greece); Geochem. Geophys. Geosyst. 4(8).

  19. Dilek Y and Morishita T 2009 Melt migration and upper mantle evolution during incipient arc construction: Jurassic Eastern Mirdita ophiolite, Albania; Isl. Arc 18 551–554.

  20. Edwards S and Malpas J 1995 Multiple origins for mantle harzburgites: Examples from the Lewis Hills, Bay of Islands ophiolite, Newfoundland; Can. J. Earth Sci. 32(7) 1046–1057.

  21. Fabries J 1979 Spinel–olivine geothermometry in peridotites from ultramafic complex; Contrib. Mineral. Petrol. 6 329–336.

  22. Franz L and Wirth R 2000 Spinel inclusions in olivine of peridotite xenoliths from TUBAF seamount (Bismarck Archipelago/Papua New Guinea): Evidence for the thermal and tectonic evolution of the oceanic lithosphere; Contrib. Miner. Petrol. 140(3) 283–295.

  23. Godard M, Lagabrielle Y, Alard O and Harvey J 2008 Geochemistry of the highly depleted peridotites drilled at ODP Sites 1272 and 1274 (Fifteen–Twenty Fracture Zone, Mid-Atlantic Ridge): Implications for mantle dynamics beneath a slow spreading ridge; Earth Planet. Sci. Lett. 267 410–425.

  24. Gonzalez-Jimenez J M, Proenza J A, Gervilla F, Melgarejo J C, Blanco-Moreno J A, Ruiz-Sanchez R and Griffin W L 2011 High-Cr and high-Al chromitites from the Sagua de Tanamo district, Mayari-Cristal ophiolitic massif (eastern Cuba): Constraints on their origin from mineralogy and geochemistry of chromian spinel and platinum group elements; Lithos 125 101–121.

  25. Green D H, Falloon T J and Taylor W R 1987 Mantle-derived magmas-roles of variable source peridotite and variable CHO fluid compositions; In: Magmatic Processes: Physicochemical Principles (ed.) Mysen B O, Geochem. Soc. Spec. Publ. 1 139–154.

  26. Haggerty S E 1989 Upper mantle opaque mineral stratigraphy and the genesis of metasomites and alkali-rich melts; Kimberlites and Related Rocks 2 687–699.

  27. Hanghøj K, Kelemen P B, Hassler D and Godard M 2010 Composition and genesis of depleted mantle peridotites from the Wadi Tayin Massif, Oman Ophiolite; major and trace element geochemistry, and Os isotope and PGE systematics; J. Petrol. 51(1–2) 201–227.

  28. Hébert R, Huot F, Wang C and Liu Z 2003 Yarlung Zangbo ophiolites (Southern Tibet) revisited: Geodynamic implications from the mineral record; Geol. Soc. Spec. Publ. 218(1) 165–190.

  29. Hellebrand E, Snow J E, Hoppe P and Hofmann A W 2002 Garnet field Melting and Late stage Refertilization in ‘Residual' Abyssal Peridotites from the Central Indian Ridge; J. Petrol. 43(12) 2305–2338.

  30. Hellebrand E, Snow J E, Dick H J B and Hoffmann A W 2001 Coupled major and trace elements as indicators of extent of melting in mid-ocean-ridge peridotites; Nature 410 677–681.

  31. Himmelberg G R and Loney R A 1973 Petrology of the Vulcan Peak Alpine-type Peridotite, Southwestern Oregon; Bull. Geol. Soc. Am. 84(5) 1585–1600.

  32. Hirose K and Kawamoto T 1995 Hydrous partial melting of lherzolite at 1 GPa: The effect of H2O on the genesis of basaltic magmas; Earth Planet. Sci. Lett. 133(3–4) 463–473.

  33. Ishii T, Robinson P T, Maekawa H and Fiske R 1992 Petrological studies of peridotites from diapiric serpentinite seamounts in the Izu–Mariana fore-arc, Leg 125; In: Proceedings of the Ocean Drilling Program, Scientific Results (eds) Fryer P, Pearce J A and Stokking L B, College Station, Texas, USA, 125 445–485.

  34. Jan M Q and Windley B F 1990 Chromian spinel-silicate chemistry in ultramafic rocks of the Jijal complex, Northwest Pakistan; J. Petrol. 31(3) 667–715.

  35. Johnson K T M, Dick H J B and Shimizu N 1990 Melting in the oceanic upper mantle: An ion microprobe study of diopsides in abyssal periodites; J. Geophys. Res. 95 2661–2678.

  36. Juteau T, Berger E and Cannat M 1990 Serpentinized, residual mantle peridotites from the MAR Median Valley, ODP hole 670A (21°10′N, 45°02′W, Leg 109): Primary mineralogy and geothermometry; In: Proceedings of Ocean Drilling Program, Scientific Results, 106/109.

  37. Kamenetsky V S, Crawford A J and Meffre S 2001 Factors controlling chemistry of magmatic spinel: An empirical study of associated olivine, Cr-spinel and melt inclusions from primitive rocks; J. Petrol. 42 655–671, https://doi.org/10.1093/petrology/42.4.655.

  38. Kapsiotis A 2014 Composition and alteration of Cr-spinels from Milia and Pefki serpentinized mantle peridotites, Pindos Ophiolite Complex, Greece; Geol. Carpathica 65 83–95.

  39. Kapsiotis A N 2016 Physiognomy and timing of metasomatism in the southern Vourinos ultramafic suite, NW Greece: A chronicle of consecutive episodes of melt extraction and stagnation in the Neotethyan lithospheric mantle; Inter. J. Earth Sci. 105(3) 983–1013.

  40. Kelemen P B 1990 Reaction between ultramafic rock and fractionating basaltic magma I. Phase relations, the origin of calc-alkaline magma series, and the formation of discordant dunite; J. Petrol. 31 55–98.

  41. Kelemen P B, Dick H J and Quick J E 1992 Formation of harzburgite by pervasive melt/rock reaction in the upper mantle; Nature 358(6388) 635–641.

  42. Khalil A E S and Azer M K 2008 Supra-subduction affinity in the Neoproterozoic serpentinites in the Eastern Desert, Egypt: Evidence from mineral composition; J. Afr. Earth Sci. 49 136–152.

  43. Le Fort P 1975 Himalayas: The collided range, Present knowledge of the continental arc; Amer. J. Sci. 275(1) 1–44.

  44. Liipo J, Vuollo J, Nykänen V, Piirainen T, Pekkarinen L and Tuokko I 1995 Chromites from the early Proterozoic Outokumpu–Jormua ophiolite belt: A comparison with chromites from Mesozoic ophiolites; Lithos 36(1) 15–27.

  45. Maheo G, Berttrand H, Guillot S, Villa I M, Keller F and Capiez P 2004 The South Ladakh Ophiolites (NW Himalaya, India): An intra-oceanic tholeiitic arc origin with implications for the closure of the Neo-Tethys; Chem. Geol. 203 273–303.

  46. Moghadam H S, Khedr M Z, Arai S, Stern R J, Ghorbani G, Tamura A and Ottley C J 2015 Arc-related harzburgite–dunite–chromitite complexes in the mantle section of the Sabzevar ophiolite, Iran: A model for formation of podiform chromitites; Gondwana Res. 27(2) 575–593.

  47. Molnar P and Tapponnier P 1975 Cenozoic tectonics of Asia: Effects of a continental collision; Science 189 419–426.

  48. Monnier C, Girardeau J, Maury R C and Cotten J 1995 Back-arc basin origin for the East Sulawesi ophiolite (eastern Indonesia); Geology 23(9) 851–854.

  49. Mukherjee B K, Sachan H K, Ogasawara Y, Muko A and Yoshioka N 2003 Carbonate-bearing UHPM rocks from the Tso-Morari region, Ladakh, India: Petrological implications; Int. Geol. Rev. 45(1) 49–69.

  50. Mysen B O and Kushiro I 1977 Compositional variations of coexisting phases with degree of melting of peridotite in the upper mantle; Am. Mineral. 62(9–10) 843–865.

  51. Nicolas A 1989 Structures of Ophiolites and Dynamics of Oceanic Lithosphere, Kluwer Academic, Dordrecht, 367p.

  52. Nimis P and Taylor W R 2000 Single clinopyroxene thermobarometry for garnet peridotites, Part I. Calibration and testing of a Cr-in-Cpx barometer and an enstatite-in-Cpx thermometer; Contrib. Mineral. Petrol. 139(5) 541–554.

  53. Niu Y, Langmuir C H and Kinzler R J 1997 The origin of abyssal peridotites: A new perspective; Earth Planet. Sci. Lett. 152(1) 251–265.

  54. Ohara Y and Ishii T 1998 Peridotites from the southern Mariana forearc: Heterogeneous fluid supply in the mantle wedge; Isl. Arc 7 541–558.

  55. Okamura H, Arai S and Kim Y U 2006 Petrology of forearc peridotite from the Hahajima Seamount, the Izu-Bonin arc, with special reference to chemical characteristics of chromian spinel; Mineral. Mag. 70 15–26.

  56. Parkinson I J and Pearce J A 1998 Peridotites from the Izu-Bonin-Mariana forearc (ODP Leg 125): Evidence for mantle melting and melt–mantle interaction in a suprasubduction zone setting; J. Petrol. 39 1577–1618.

  57. Pearce J A, Barker P F, Edwards S J, Parkinson I J and Leat P T 2000 Geochemistry and tectonic significance of peridotites from the South Sandwich arc–basin system, South Atlantic; Contrib. Mineral. Petrol. 139(1) 36–53.

  58. Pearce J A, Alabaster T, Shelton A W and Searle M P 1981 The Oman ophiolite as a Cretaceous arc-basin complex: Evidence and implications; Philos. Trans. R. Soc. London A 300(1454) 299–317.

  59. Peighambari S, Ahmadipour H, Stosch H G and Daliran F 2011 Evidence for multi-stage mantle metasomatism at the Dehsheikh peridotite massif and chromite deposits of the Orzuieh coloured mélange belt, southeastern Iran; Ore Geol. Rev. 39 245–264.

  60. Pudsey C J 1986 The Northern Suture, Pakistan: Margin of a Cretaceous island arc; Geol. Mag. 123 405–423.

  61. Rampone E, Piccardo G B and Hofmann A W 2008 Multi-stage melt–rock interaction in the Mt. Maggiore (Corsica, France) ophiolitic peridotites: Microstructural and geochemical evidence; Contrib. Mineral. Petrol. 156(4) 453–475.

  62. Ravikant V, Pal T and Das D 2004 Chromites from the Nidar ophiolite and Karzok complex, Transhimalaya, Eastern Ladakh: Their magmatic evolution; J. Asian Earth Sci. 24 177–184.

  63. Sachan H K and Mukherjee B K 2003 Genesis of chromite in ophiolites from Indus Suture Zone, Ladakh, India: Evidence from mineral chemistry of solid inclusions in chromite; Himal. Geol. 24 63–74.

  64. Sachan H K, Mukherjee B K and Bodner R J 2007 Methane (CH4) in upper mantle rocks from the Indus Suture Zone, Ladakh (India): Evidence from fluid inclusion and Raman spectroscopy; Earth Planet. Sci. Lett. 257 47–59.

  65. Sachan H K 2001 Supra-subduction origin of the Nidar ophiolitic sequence, Indus Suture Zone, Ladakh, India: Evidence from mineral chemistry of upper mantle rocks; Ofioliti 26(1) 23–32.

  66. Searle M P, Khan M A, Fraser J E and Gough S J 1999 The tectonic evolution of the Kohistan–Karakoram collision belt along the Karakoram Highway transect, north Pakistan; Tectonics 18 929–949.

  67. Sen K, Das S, Mukherjee B K and Sen K 2013 Bimodal stable isotope signatures of Zildat Ophiolitic Mélange, Indus Suture Zone, Himalaya: Implications for emplacement of an ophiolitic mélange in a convergent setup; Int. J. Earth Sci. 102(7) 2033–2042.

  68. Sharma K K and Gupta K R 1982 Northern Ladakh, a scene of explosive volcanic activity in early Cenozoic; Contrib. Himal. Geol. 2 87–95.

  69. Siddaiah N S 2001 Serpentinization, rodingitization, high-pressure metamorphism and mineralization in the Nidar ophiolite of Indus Suture Zone, Eastern Ladakh, Himalaya, India, Extended Abstract; In: UHPM Workshop, Waseda University, Japan, pp. 79–82.

  70. Siddaiah N S and Masuda A 2001 Noble metals in the Nidar ophiolite of the Indus Suture zone, Eastern Ladakh, Himalaya, India; Geol. Surv. India, Spec. Publ. 58 465–469.

  71. Tahirkheli R K, Mattauer M, Proust F and Tapponnier P 1979 The India Eurasia suture zone in northern Pakistan: Synthesis and interpretation of recent data at plate scale, Geodynamics of Pakistan, Geol. Surv. Pakistan, Quetta, pp. 125–130.

  72. Takazawa E, Frey F A, Shimizu N and Obata M 2000 Whole rock compositional variations in an upper mantle peridotite (Horoman, Hokkaido, Japan): Are they consistent with a partial melting process? Geochim. Cosmochim. Acta 64(4) 695–716.

  73. Taylor W R and Green D H 1988 Measurement of reduced peridotite-COH solidus and implications for redox melting of the mantle; Nature 332(6162) 349.

  74. Thakur V C and Bhat M I 1983 Interpretation of tectonic environment of Nidar ophiolite: A geochemical approach; Geology of Indus Suture Zone of Ladakh, pp. 21–31.

  75. Thakur V C and Mishra D K 1984 Tectonic framework of Indus and Shyok Suture Zones in eastern Ladakh, Northwest Himalaya; Tectonophys. 101 207–220.

  76. Uysal I, Ersoy E Y, Karslı O, Dilek Y, Sadıklar M B, Ottley C J and Meisel T 2012 Coexistence of abyssal and ultra-depleted SSZ type mantle peridotites in a Neo-Tethyan Ophiolite in SW Turkey: Constraints from mineral composition, whole-rock geochemistry (major–trace–REE–PGE), and Re–Os isotope systematics; Lithos 132 50–69.

  77. Uysal I, Kaliwoda M, Karslı O, Tarkian M, Sadıklar M B and Ottley C J 2007 Compositional variations in whole rock and coexisting phases with partial melting and melt–peridotite interaction in an upper mantle section from the Ortaca Area, Southwestern Turkey; Can. Mineral. 45 1471–1493.

  78. Zhou M F, Sun M, Keays R R and Kerrich R W 1998 Controls on platinum-group elemental distributions of podiform chromitites: A case study of high-Cr and high-Al chromitites from Chinese orogenic belts; Geochim. Cosmochim. Acta 62 677–688.

  79. Zhou M F, Robinson P T, Malpas J, Edwards S J and Qi L 2005 REE and PGE geochemical constraints on the formation of dunites in the Luobusa ophiolite, Southern Tibet; J. Petrol. 46(3) 615–639.

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Acknowledgements

RN acknowledges financial support from the Department of Science and Technology, Government of India as Fast Track Young Scientist (Grant no. SR/FTP/ES-60/2014). RN gratefully acknowledges Dr Stenzin and his family for all the help and support during the fieldwork at Ladakh. Also grateful to Dr C P Dorjey for the logistics during the fieldwork. The author is thankful to Dr Sakthi Saravanan Chinnasamy for extending his Lab facilities for the execution of the DST project. The manuscript is greatly improved from the thoughtful comments by the anonymous reviewers of the journal and language improvement by Akmaz. The author is indebted to Prof Rajneesh Bhutani, for valuable suggestions and editorial handling.

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Correspondence to Ranjit Nayak.

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Nayak, R., Maibam, B. Petrological study of spinel peridotites of Nidar ophiolite, Ladakh Himalaya, India. J Earth Syst Sci 129, 47 (2020). https://doi.org/10.1007/s12040-019-1308-1

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Keywords

  • Spinel peridotites
  • Nidar Ophiolite Complex (NOC)
  • supra-subduction zone (SSZ)
  • partial melting