Transition metal oxide loaded MCM catalysts for photocatalytic degradation of dyes
Article
First Online:
Received:
Revised:
Accepted:
- 310 Downloads
- 10 Citations
Abstract
Transition metal oxide (TiO2, Fe2O3, CoO) loaded MCM-41 and MCM-48 were synthesized by a two-step surfactant based process. Nanoporous, high surface area compounds were obtained after calcination of the compounds. The catalysts were characterized by SEM, XRD, XPS, UV-vis and BET surface area analysis. The catalysts showed high activity for the photocatalytic degradation of both anionic and cationic dyes. The degradation of the dyes was described using Langmuir–Hinshelwood kinetics and the associated rate parameters were determined.
Keywords
Mesoporous materials characterization photocatalytic degradation metal oxide dopingPreview
Unable to display preview. Download preview PDF.
Supplementary material
References
- 1.Hoffmann M R, Martin S T, Choi W and Bahnemann D W 1995 Chem. Rev. 95 69CrossRefGoogle Scholar
- 2.Chen X and Mao S S 2007 Chem. Rev. 107 2891CrossRefGoogle Scholar
- 3.Thompson T L and Yates, Jr. J T 2006 Chem. Rev. 106 4428CrossRefGoogle Scholar
- 4.Nagaveni K, Hegde M S, Ravishankar N, Subbanna G N and Madras G 2004 Langmuir 20 2900CrossRefGoogle Scholar
- 5.Sivalingam G, Nagaveni K, Hegde M S and Madras G 2003 Appl. Catal. B: Environ. 45 23CrossRefGoogle Scholar
- 6.Liu X, Sun H and Yang Y 2008 J. Colloid Interf. Sci. 319 377CrossRefGoogle Scholar
- 7.Sadasivan S and Sukhorukov G B 2006 J. Colloid Interf. Sci. 304 437CrossRefGoogle Scholar
- 8.Weidenkaff A 2004 Adv. Eng. Mater. 6 709CrossRefGoogle Scholar
- 9.Mao H, Li B, Li X, Yue L, Liu Z and Ma W 2010 Ind. Eng. Chem. Res. 49 583CrossRefGoogle Scholar
- 10.Valdes-Solis T and Fuertes A B 2006 Mater. Res. Bull. 41 2187CrossRefGoogle Scholar
- 11.Goltner C G and Antonietti M 1997 Adv. Mater. 9 431CrossRefGoogle Scholar
- 12.Zanjanchi M A, Golmodeh H and Arvind M 2009 J. Hazard. Mater. 169 233CrossRefGoogle Scholar
- 13.Yang H, Deng Y and Du C 2009 Coll. Surf. A. 339 111CrossRefGoogle Scholar
- 14.Mihai G D, Meynen V, Beyers E, Mertens M, Bilba N, Cool P and Vansant E F 2009 J. Porous. Mater. 16 109CrossRefGoogle Scholar
- 15.Sun B, Reddy E P and Panagiotis P G 2005 Appl. Catal. B: Environ. 57 139CrossRefGoogle Scholar
- 16.Signoretto M, Ghedini E, Trevisan V, Bianchi C L, Ongaro M and Cruciani G 2010 Appl. Catal. B: Environ. 95 130CrossRefGoogle Scholar
- 17.Parida K M and Rath D 2009 J. Colloid Interf. Sci. 340 209CrossRefGoogle Scholar
- 18.Liu H, Lu G, Guo Y, Wang Y and Guo Y 2010 J. Colloid Interf. Sci. 346 486CrossRefGoogle Scholar
- 19.Zheng Y, Li Z, Zheng Y, Shen X and Lin L 2006 Mater. Lett. 60 3221CrossRefGoogle Scholar
- 20.Hua D, Chen S, Yuan G and Wang Y 2010 J. Porous. Mater. doi: 10.1007/s10934-010-9434-9 Google Scholar
- 21.Karunakaran C and Senthivelan S 2006 Electrochem. Commun. 8 95CrossRefGoogle Scholar
- 22.Karunakaran C and Dhanalakshmi R 2009 Radiation Phys. Chem. 78 8–12CrossRefGoogle Scholar
- 23.Karunakaran C, Dhanalakshmi R and Karuthapandian S 2005 J. Photochem. Photobiol. A: Chem. 170 233–238CrossRefGoogle Scholar
- 24.Karunakaran C and Anilkumar P 2007 J. Mol. Catal. A: Chem. 265 153CrossRefGoogle Scholar
- 25.Karunakaran C and Anilkumar P 2008 Solar Energy Mater. Solar Cell. 92 490CrossRefGoogle Scholar
- 26.Zanjachi M A, Ebrahimian A and Arvand M 2010 J. Hazard. Mater. 175 992CrossRefGoogle Scholar
- 27.Bai J 2009 Mater. Lett. 63 1485CrossRefGoogle Scholar
- 28.Yang Q, Choi H, Al-Abed S R, Dionysiou D D 2009 Appl. Catal. B: Environ. 88 462CrossRefGoogle Scholar
- 29.Chiang K, Amal R and Tran T 2002 Adv. Environ. Res. 6 471CrossRefGoogle Scholar
- 30.Khan S U M, Al-Shahry M and Ingler Jr. W B 2002 Science 297 2243CrossRefGoogle Scholar
- 31.Artkla S, Kim W, Choi W and Wittayakun J 2009 Appl. Catal. B: Environ. 91 157CrossRefGoogle Scholar
- 32.Cojocaru B, Neatu S, Parvulescu V I, Dumbuya K, Steinruck H-P, Gottfried J M, Aprile C, Garcia H and Scaiano J C 2009 Phys. Chem. Chem. Phys. 11 5569CrossRefGoogle Scholar
- 33.Laughlin R B 1980 Phys. Rev. B 22 3021CrossRefGoogle Scholar
- 34.Shen J L and Cheng C F 2003 Curr. Opinion Solid State Mater. Sci. 7 427CrossRefGoogle Scholar
- 35.Strunk J, Vining W C and Bell A T 2010 J. Phys. Chem. C 114 16937CrossRefGoogle Scholar
- 36.Reddy E, Davydov L and Smirniotis P G 2002 J. Phys. Chem. B 106 3394CrossRefGoogle Scholar
- 37.Priya M H and Madras G 2006 J. Photochem. Photobio. 178 1CrossRefGoogle Scholar
- 38.Aarthi T and Madras G 2007 Ind. Eng. Chem. Res. 46 7CrossRefGoogle Scholar
- 39.Aarthi T, Narahari P and Madras G 2007 J. Hazard. Mater. 149 725CrossRefGoogle Scholar
- 40.Vinu R, Akki S U and Madras G 2010 J. Hazard. Mater. 176 765CrossRefGoogle Scholar
Copyright information
© Indian Academy of Sciences 2011