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Synthesis, characterization and anticorrosion behaviour of a novel hydrazide derivative on mild steel in hydrochloric acid medium

  • P Preethi Kumari
  • Prakash ShettyEmail author
  • Suma A Rao
  • Dhanya Sunil
  • T Vishwanath
Article
  • 40 Downloads

Abstract

A novel corrosion inhibitor, namely \(N'\)-[(4-methyl-1H-imidazole-5-yl)methylidene]-2-(naphthalen-2-yloxy) acetohydrazide (IMNH), has been synthesized and characterized by \(^{1}\)H NMR and FTIR spectroscopic techniques. The anticorrosion behaviour of IMNH on mild steel in 1 M hydrochloric acid (HCl) medium was studied by potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) techniques. The percentage inhibition efficiency of IMNH increased with increase in its concentration and temperature. The adsorption of IMNH followed chemisorption and obeyed Langmuir’s adsorption isotherm. PDP study revealed that IMNH functioned as a mixed type inhibitor. Theoretical study of the adsorption behaviour of this inhibitor was carried out by quantum chemical calculations using density functional theory (DFT). Scanning electron microscopy (SEM), atomic force microscopy (AFM) and energy-dispersive X-ray spectroscopy (EDX) studies confirmed the formation of a protective film of IMNH on the mild steel surface.

Keywords

Mild steel hydrazide derivative polarization impedance chemisorption SEM/AFM 

Notes

Acknowledgements

The authors are grateful to Manipal Institute of Technology and Manipal Academy of Higher Education, Manipal, for providing laboratory facilities.

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Copyright information

© Indian Academy of Sciences 2020

Authors and Affiliations

  • P Preethi Kumari
    • 1
  • Prakash Shetty
    • 1
    Email author
  • Suma A Rao
    • 1
  • Dhanya Sunil
    • 1
  • T Vishwanath
    • 2
  1. 1.Department of Chemistry, Manipal Institute of TechnologyManipal Academy of Higher EducationManipalIndia
  2. 2.Department of Materials ScienceMangalore UniversityMangalagangotriIndia

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