Synthesis and enhanced photocatalytic activity of g-\(\hbox {C}_{3}\mathrm{N}_{4}\) hybridized CdS nanoparticles
- 109 Downloads
Abstract
The highly effective g-\(\hbox {C}_{3}\hbox {N}_{4}\) hybridized CdS photocatalysts were synthesized via a successive calcination and hydrothermal process. The as-prepared photocatalysts were characterized by X-ray powder diffraction, transmission electron microscopy and UV–Vis diffuse reflectance spectroscopy. The photocatalytic performance of the \(\hbox {C}_{3}\hbox {N}_{4}\)/CdS nanocomposites was evaluated by the photodegradation of RhB under visible light irradiation. The results showed that photocatalytic ability of the \(\hbox {C}_{3}\hbox {N}_{4}\)/CdS nanocomposites was higher than that of pure \(\hbox {C}_{3}\hbox {N}_{4}\) and CdS. The enhanced photocatalytic activity could be attributed to the high separation efficiency of the photo-excited electron-hole pairs. A possible mechanism of the photocatalytic degradation of RhB on \(\hbox {C}_{3}\hbox {N}_{4}/\)CdS nanocomposites was also proposed.
Keywords
\(\hbox {C}_{3}\hbox {N}_{4}\) CdS photocatalytic nanocompositesReferences
- 1.Cao Q W, Cui X, Zheng Y F and Song X C 2016 J. Alloys Compd. 670 12CrossRefGoogle Scholar
- 2.Yin H, Wang X, Wang L, Nie Q, Zhang Y, Yuan Q et al 2016 J. Alloys Compd. 657 44CrossRefGoogle Scholar
- 3.Yin H, Wang X, Wang L, Nie Q and Zhao H 2015 J. Alloys Compd. 640 68CrossRefGoogle Scholar
- 4.Yin H, Wang X, Wang L, Nie Q, Zhang Y and Wu W 2015 Mater. Res. Bull. 72 176CrossRefGoogle Scholar
- 5.Kumar S, Surendar T, Kumar B, Baruah A and Shanker V 2013 J. Phys. Chem. C 117 26135CrossRefGoogle Scholar
- 6.Liu W, Wang M, Xu C, Chen S and Fu X 2013 J. Mol. Catal. A 368 9CrossRefGoogle Scholar
- 7.He Y, Cai J, Li T, Wu Y, Lin H, Zhao L et al 2013 Chem. Eng. J. 721 215Google Scholar
- 8.Wang Y, Bai X, Pan C, Heb J and Zhu Y 2012 J. Mater. Chem. 22 11568CrossRefGoogle Scholar
- 9.Fu J, Tian Y, Chang B, Xi F and Dong X 2012 J. Mater. Chem. 22 21159CrossRefGoogle Scholar
- 10.Lan Y, Qian X, Zhao C, Zhang Z, Chen X and Li Z 2013 J. Colloid Interface Sci. 395 75Google Scholar
- 11.Shi Y, Li H, Wang L, Shen W and Chen H 2012 ACS Appl. Mater. Interfaces 4 4800CrossRefGoogle Scholar
- 12.Li Q, Guo B, Yu J, Ran J, Zhang B and Yan H 2011 J. Am. Chem. Soc. 133 10878CrossRefGoogle Scholar
- 13.Khanchandani S, Kundu S, Patra A and Ganguli A K 2012 J. Phys. Chem. C 116 23653CrossRefGoogle Scholar
- 14.Zhang L J, Li S, Liu B K, Wang D J and Xie T F 2014 ACS Catal. 4 3724CrossRefGoogle Scholar
- 15.Zhang J Y, Wang Y H, Jin J, Zhang J, Lin Z, Huang F et al 2013 ACS Appl. Mater. Interfaces 5 10317CrossRefGoogle Scholar
- 16.Matsumoto S, Xie E and Izumi F 1999 Diam. Relat. Mater. 8 1175CrossRefGoogle Scholar
- 17.Li W T, Zheng Y F, Yin H Y and Song X C 2015 J. Nanopart. Res. 17 271CrossRefGoogle Scholar
- 18.Cui X, Huang W Z, Zhou H, Yin H Y, Zheng Y F and Song X C 2015 Curr. Nanosci. 11 360CrossRefGoogle Scholar