Bulletin of Materials Science

, Volume 31, Issue 1, pp 7–13 | Cite as

Pressure induced graft-co-polymerization of acrylonitrile onto Saccharum cilliare fibre and evaluation of some properties of grafted fibre

  • A. S. Singha
  • Anjali Shama
  • Vijay Kumar Thakur


In the present work, graft co-polymerization of acrylonitrile (AN) onto Saccharum cilliare fibre has been carried out in the presence of potassium persulphate and ferrous ammonium sulphate (FAS-KPS) as redox initiator. The reactions were carried out under pressure in an autoclave. Various reaction parameters such as pressure, time, pH, concentrations of initiator and monomer were optimized to get maximum graft yield (35·59%). Grafted and ungrafted Saccharum cilliare fibres were then subjected to evaluation of some of their properties like swelling behaviour in different solvents, moisture absorbance under different humidity levels, water uptake and resistance towards chemicals such as hydrochloric acid and sodium hydroxide. The characterization of the graft copolymers were carried out by FTIR spectrophotometer, X-ray diffraction (XRD) and scanning electron microscopic (SEM) studies.


Saccharum cilliare fibre acrylonitrile graft copolymer redox initiator chemical resistance 


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  1. Chauhan G S, Bhatt S S, Kaur I, Singha A S and Kaith B S 2000 J. Polym. Degrad. & Stab. 69 261CrossRefGoogle Scholar
  2. Guthrie J J and Haa Z 1974 Polymer 15 133CrossRefGoogle Scholar
  3. Habish J A and Mehta P C 1967 Textile Res. J. 37 9115Google Scholar
  4. Habish J A and Mehta P C 1968 Appl. Polym. Sci. 121 625Google Scholar
  5. Hurdue N and Scheider I A 1970 Cell Chem. Technol. 4 195Google Scholar
  6. Kaith B S, Singha A S and Sharma S K 2003 J. Polym. Mater. 20 195Google Scholar
  7. Kaizerman S, Mino G and Meinheld C F 1962 Textile Res. J. 32 136Google Scholar
  8. Krassto H A and Stannet V T 1965 Adv. Polym. Sci. 4 111CrossRefGoogle Scholar
  9. Mino G and Kaizerman S 1958 J. Polym. Sci. 31 242CrossRefGoogle Scholar
  10. Nishioka N, Nakano Y, Hirota T and Fujiwara N 1996 J. Appl. Polym. Sci. 59 1203CrossRefGoogle Scholar
  11. Philips R B, Ouere J, Quiroy Z and Stannet V T 1972 Tappi 558 58Google Scholar
  12. Schwob E, Stannett V T, Rakowiz W H and Margane J K 1962 Tappi 45 390Google Scholar
  13. Segal L C, Martin A E and Conrad C M 1959 Textile Res. J. 29 786Google Scholar
  14. Singha A S, Kaith B S and Sarwade B D 2002 Hung. J. Industr. Chem. VESZPREM 30 289Google Scholar
  15. Singha A S, Kaith B S, Ashish Chauhan and Misra B N 2006 J. Polym. Mater. 23 3456Google Scholar
  16. Verma D S and Narsimha V 1972 J. Appl. Polym. Sci. 16 3325CrossRefGoogle Scholar
  17. Yang P Y and Kokot S 1996 J. Appl. Polym. Sci. 62 49CrossRefGoogle Scholar

Copyright information

© Indian Academy of Sciences 2008

Authors and Affiliations

  • A. S. Singha
    • 1
  • Anjali Shama
    • 1
  • Vijay Kumar Thakur
    • 1
  1. 1.Material Science LaboratoryNational Institute of TechnologyHamirpurIndia

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