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A review on application of carbon nanostructures as nanofiller in corrosion-resistant organic coatings

  • Sepideh Pourhashem
  • Ebrahim Ghasemy
  • Alimorad RashidiEmail author
  • Mohammad Reza Vaezi
Review Article
First Online:

Abstract

Since corrosion has tremendous economic effects, academics and industries have sought to develop more effective coatings. These efforts have led to profound importance of nanocomposite coatings based on polymers and carbon nanostructures. It is shown that good reinforcement, advanced mechanical properties, and high corrosion resistance are only found at relatively low levels of nanocarbon (i.e., fullerene, carbon black, carbon nanotubes, graphene, graphene oxide, and carbon dots) loadings in coating compositions. Herein, a survey of breakthrough scientific studies on application of carbon nanostructures in corrosion-resistant organic coatings is carried out to pave the way for future developments in novel nanocoatings.

Keywords

Carbon nanostructures Polymer composites Coatings Corrosion 
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Notes

Acknowledgments

The authors would like to thank Iranian Elite National Foundation (Bonyad Melli Nokhbegan) as Allameh Tabatabaei’s Award for financial support.

References

  1. 1.
    Wang, N, et al., “Dopamine Modified Metal-Organic Frameworks on Anti-Corrosion Properties of Waterborne Epoxy Coatings.” Prog. Org. Coat., 109 126–134 (2017)CrossRefGoogle Scholar
  2. 2.
    He, P, et al., “Synergistic Effect of Polyaniline Grafted Basalt Plates for Enhanced Corrosion Protective Performance of Epoxy Coatings.” Prog. Org. Coat., 110 1–9 (2017)CrossRefGoogle Scholar
  3. 3.
    Ramezanzadeh, B, et al., “Corrosion Protection of Steel with Zinc Phosphate Conversion Coating and Post-Treatment by Hybrid Organic-Inorganic Sol-Gel Based Silane Film.” J. Electrochem. Soc., 164 (6) C224–C230 (2017)CrossRefGoogle Scholar
  4. 4.
    Qiu, S, et al., “Long-Term Corrosion Protection of Mild Steel by Epoxy Coating Containing Self-Doped Polyaniline Nanofiber.” Synth. Met., 229 39–46 (2017)CrossRefGoogle Scholar
  5. 5.
    Chang, K-C, et al., “Room-Temperature Cured Hydrophobic Epoxy/Graphene Composites as Corrosion Inhibitor for Cold-Rolled Steel.” Carbon, 66 144–153 (2014)CrossRefGoogle Scholar
  6. 6.
    Shifler, DA, “Understanding Material Interactions in Marine Environments to Promote Extended Structural Life.” Corros. Sci., 47 (10) 2335–2352 (2005)CrossRefGoogle Scholar
  7. 7.
    Hung, W-I, Chang, K-C, Chang, Y-H, Yeh, J-M, “Advanced Anticorrosive Coatings Prepared From Polymer-Clay Nanocomposite Materials.” In: Advances in Nanocomposites-Synthesis, Characterization and Industrial Applications. IntechOpen (2011)Google Scholar
  8. 8.
    Shipping, ABO, Guidance Notes on the Inspection, Maintenance and Application of Marine Coating Systems. American Bureau of Shipping (ABS) (2007).Google Scholar
  9. 9.
    Mitchelson, B, “Protective Coatings Solutions for Deepwater Projects.” Brief. Explor. Prod. Oil Gas Rev., 2 1–4 (2003)Google Scholar
  10. 10.
    Dennis, RV, et al., “Hybrid Nanostructured Coatings for Corrosion Protection of Base Metals: A Sustainability Perspective.” Mater. Res. Express, 2 (3) 032001 (2015)CrossRefGoogle Scholar
  11. 11.
    Böhm, S, “Graphene Against Corrosion.” Nat. Nanotechnol., 9 (10) 741 (2014)CrossRefGoogle Scholar
  12. 12.
    Aneja, KS, et al., “Graphene Based Anticorrosive Coatings for Cr(VI) Replacement.” Nanoscale, 7 (42) 17879–17888 (2015)CrossRefGoogle Scholar
  13. 13.
    Förstner, U, Wittmann, GT, Metal Pollution in the Aquatic Environment. Springer, Berlin (2012)Google Scholar
  14. 14.
    Husain, E, et al., “Marine Corrosion Protective Coatings of Hexagonal Boron Nitride Thin Films on Stainless Steel.” ACS Appl. Mater. Interfaces., 5 (10) 4129–4135 (2013)CrossRefGoogle Scholar
  15. 15.
    Pourhashem, S, et al., “Corrosion Protection Properties of Novel Epoxy Nanocomposite Coatings Containing Silane Functionalized Graphene Quantum Dots.” J. Alloy. Compd., 731 1112–1118 (2018)CrossRefGoogle Scholar
  16. 16.
    Richards, CAJ, et al., “Evaluation of Multi-Layered Graphene Nano-Platelet Composite Coatings for Corrosion Control Part I—Contact Potentials and Gas Permeability.” Corros. Sci., 136 285–291 (2018)CrossRefGoogle Scholar
  17. 17.
    Wei, H, et al., “Anticorrosive Conductive Polyurethane Multiwalled Carbon Nanotube Nanocomposites.” J. Mater. Chem. A, 1 (36) 10805–10813 (2013)CrossRefGoogle Scholar
  18. 18.
    Wu, Y, et al., “Synthesis of Graphene/Epoxy Resin Composite via 1,8-Diaminooctane by Ultrasonication Approach for Corrosion Protection.” Ultrason. Sonochem., 42 464–470 (2018)CrossRefGoogle Scholar
  19. 19.
    Yao, X, et al., “Comparison of Carbon Nanotubes and Graphene Oxide Coated Carbon Fiber for Improving the Interfacial Properties of Carbon Fiber/Epoxy Composites.” Compos. B Eng., 132 170–177 (2018)CrossRefGoogle Scholar
  20. 20.
    Zhan, Y, et al., “Epoxy Composites Coating with Fe3O4 Decorated Graphene Oxide: Modified Bio-Inspired Surface Chemistry, Synergistic Effect and Improved Anti-Corrosion Performance.” Appl. Surf. Sci., 436 756–767 (2018)CrossRefGoogle Scholar
  21. 21.
    Krishnamoorthy, K, et al., “Graphene Oxide Nanopaint.” Carbon, 72 328–337 (2014)CrossRefGoogle Scholar
  22. 22.
    Aglan, A, et al., “Formulation and Evaluation of Nano-Structured Polymeric Coatings for Corrosion Protection.” Surf. Coat. Technol., 202 (2) 370–378 (2007)CrossRefGoogle Scholar
  23. 23.
    Brooman, E, “Modifying Organic Coatings to Provide Corrosion Resistance: Part II—Inorganic Additives and Inhibitors.” Met. Finish., 100 (5) 424449–424753 (2002)CrossRefGoogle Scholar
  24. 24.
    Chico, B, et al., “Corrosion Resistance of Steel Treated with Different Silane/Paint Systems.” J. Coat. Technol. Res., 9 (1) 3–13 (2012)CrossRefGoogle Scholar
  25. 25.
    Armelin, E, et al., “Marine Paint Fomulations: Conducting Polymers as Anticorrosive Additives.” Prog. Org. Coat., 59 (1) 46–52 (2007)CrossRefGoogle Scholar
  26. 26.
    Rawlins, JW, et al, The Waterborne Symposium: Proceedings of the Thirty-Ninth Annual International Waterborne, High-Solids, and Powder Coatings Symposium Held in New Orleans, DEStech Publications, Louisiana February 13–17, 2012Google Scholar
  27. 27.
    Wang, X, et al., “Fabrication and Characterization of Graphene-Reinforced Waterborne Polyurethane Nanocomposite Coatings by the Sol–Gel Method.” Surf. Coat. Technol., 206 (23) 4778–4784 (2012)CrossRefGoogle Scholar
  28. 28.
    Alessi, P, “New Tech Against Corrosion.” Nanotech Magazine (2014)Google Scholar
  29. 29.
    Kaiser, J-P, Zuin, S, Wick, P, “Is Nanotechnology Revolutionizing the Paint and Lacquer Industry? A Critical Opinion.” Sci. Total Environ., 442 282–289 (2013)CrossRefGoogle Scholar
  30. 30.
    Kaiser, J, Diener, L, Wick, P, “Nanoparticles in Paints: A New Strategy to Protect Façades And Surfaces?” J. Phys. Conf. Ser., 429 012036 (2013)CrossRefGoogle Scholar
  31. 31.
    Geim, AK, Novoselov, KS, “The Rise of Graphene.” Nat. Mater., 6 (3) 183–191 (2007)CrossRefGoogle Scholar
  32. 32.
    Hu, H, et al., “Enhanced Dispersion of Carbon Nanotube in Silicone Rubber Assisted by Graphene.” Polymer, 53 (15) 3378–3385 (2012)CrossRefGoogle Scholar
  33. 33.
    Wiese, G, et al, “Methods of Forming Protecting Coatings on Substrate Surfaces.” Google Patents (2013)Google Scholar
  34. 34.
    González-Domínguez, JM, et al., “Reactive Fillers Based on SWCNTs Functionalized with Matrix-Based Moieties for the Production of Epoxy Composites with Superior and Tunable Properties.” Nanotechnology, 23 (28) 285702 (2012)CrossRefGoogle Scholar
  35. 35.
    Shenderova, O, Zhirnov, V, Brenner, D, “Carbon Nanostructures.” Crit. Rev. Solid State Mater. Sci., 27 (3–4) 227–356 (2002)CrossRefGoogle Scholar
  36. 36.
    Martin-Gallego, M, et al., “Comparison of Filler Percolation and Mechanical Properties in Graphene and Carbon Nanotubes Filled Epoxy Nanocomposites.” Eur. Polym. J., 49 (6) 1347–1353 (2013)CrossRefGoogle Scholar
  37. 37.
    Rafiee, MA, et al., “Fullerene–Epoxy Nanocomposites-Enhanced Mechanical Properties at Low Nanofiller Loading.” J. Nanopart. Res., 13 (2) 733–737 (2011)CrossRefGoogle Scholar
  38. 38.
    Kuilla, T, et al., “Recent Advances in Graphene Based Polymer Composites.” Prog. Polym. Sci., 35 (11) 1350–1375 (2010)CrossRefGoogle Scholar
  39. 39.
    Mauter, MS, Elimelech, M, “Environmental Applications of Carbon-Based Nanomaterials.” Environ. Sci. Technol., 42 (16) 5843–5859 (2008)CrossRefGoogle Scholar
  40. 40.
    Potts, JR, et al., “Graphene-Based Polymer Nanocomposites.” Polymer, 52 (1) 5–25 (2011)CrossRefGoogle Scholar
  41. 41.
    Young, RJ, et al., “The Mechanics of Graphene Nanocomposites: A Review.” Compos. Sci. Technol., 72 (12) 1459–1476 (2012)CrossRefGoogle Scholar
  42. 42.
    Naffakh, M, et al., “Opportunities and Challenges in the Use of Inorganic Fullerene-Like Nanoparticles to Produce Advanced Polymer Nanocomposites.” Prog. Polym. Sci., 38 (8) 1163–1231 (2013)CrossRefGoogle Scholar
  43. 43.
    Howell, DNL, “Technical Field and Industrial Applicability of the Invention.” Google Patents (2011)Google Scholar
  44. 44.
    Yadav, B, Kumar, R, “Structure, Properties and Applications of Fullerenes.” Int. J. Nanotechnol. Appl., 2 (1) 15–24 (2008)Google Scholar
  45. 45.
    Wang, C, et al., “Polymers Containing Fullerene or Carbon Nanotube Structures.” Prog. Polym. Sci., 29 (11) 1079–1141 (2004)CrossRefGoogle Scholar
  46. 46.
    Ogasawara, T, Ishida, Y, Kasai, T, “Mechanical Properties of Carbon Fiber/Fullerene-Dispersed Epoxy Composites.” Compos. Sci. Technol., 69 (11) 2002–2007 (2009)CrossRefGoogle Scholar
  47. 47.
    Goel, A, Howard, JB, Vander Sande, JB, “Size Analysis of Single Fullerene Molecules by Electron Microscopy.” Carbon, 42 (10) 1907 (2004)CrossRefGoogle Scholar
  48. 48.
    Bergmann, CP, Machado, FM (eds.), “Carbon Nanoadsorbents.” In: Carbon Nanomaterials as Adsorbents for Environmental and Biological Applications, pp. 11–32. Springer (2015)Google Scholar
  49. 49.
    Tea, N, et al., “Thermal Conductivity of C60 and C70 Crystals.” Appl. Phys. A, 56 (3) 219–225 (1993)CrossRefGoogle Scholar
  50. 50.
    Ivetic, M, Mojovic, Z, Matija, L, “Electrical Conductivity of Fullerene Derivatives.” Materials Science Forum. Trans Tech Publications Ltd., Zurich-Uetikon (2003)Google Scholar
  51. 51.
    Gopakumar, T, Patel, N, Xanthos, M, “Effect of Nanofillers on the Properties of Flexible Protective Polymer Coatings.” Polym. Compos., 27 (4) 368–380 (2006)CrossRefGoogle Scholar
  52. 52.
    Badamshina, E, Gafurova, M, “Polymeric Nanocomposites Containing Non-covalently Bonded Fullerene C 60: Properties and Applications.” J. Mater. Chem., 22 (19) 9427–9438 (2012)CrossRefGoogle Scholar
  53. 53.
    Lim, SY, Effect of Fullerenes Nanofiller and Carbon Black Filler of Corrosion Activities on Paint, Universiti Teknikal Malaysia Melaka, Durian Tunggal (2009)Google Scholar
  54. 54.
    Liu, D, et al., “Comparative Tribological and Corrosion Resistance Properties of Epoxy Composite Coatings Reinforced with Functionalized Fullerene C60 and Graphene.” Surf. Coat. Technol., 286 354–364 (2016)CrossRefGoogle Scholar
  55. 55.
    Aschberger, K, et al., “Review of Fullerene Toxicity and Exposure–Appraisal of a Human Health Risk Assessment, Based on Open Literature.” Regul. Toxicol. Pharmacol., 58 (3) 455–473 (2010)CrossRefGoogle Scholar
  56. 56.
    Silva, TA, et al, “Electrochemical Biosensors Based on Nanostructured Carbon Black: A Review.” J. Nanomater., 2017 4571614 (2017)Google Scholar
  57. 57.
    Ghasemi-Kahrizsangi, A, et al., “Effect of SDS Modification of Carbon Black Nanoparticles on Corrosion Protection Behavior of Epoxy Nanocomposite Coatings.” Polym. Bull., 72 (9) 2297–2310 (2015)CrossRefGoogle Scholar
  58. 58.
    Nascarella, MA, Valberg, PA, “Carbon Black vs. Black Carbon and Other Airborne Materials Containing Elemental Carbon: Physical and Chemical Distinctions.” Environ. Pollut., 181 271–286 (2013)CrossRefGoogle Scholar
  59. 59.
    Wei, YH, Zhang, LX, Ke, W, “Evaluation of Corrosion Protection of Carbon Black Filled Fusion-Bonded Epoxy Coatings on Mild Steel During Exposure to a Quiescent 3% NaCl Solution.” Corros. Sci., 49 (2) 287–302 (2007)CrossRefGoogle Scholar
  60. 60.
    Zhang, W-G, et al., “Corrosion Protection Properties of Lacquer Coatings on Steel Modified by Carbon Black Nanoparticles in NaCl Solution.” Corros. Sci., 49 (2) 654–661 (2007)CrossRefGoogle Scholar
  61. 61.
    Foyet, A, et al., “Corrosion Protection and Delamination Mechanism of Epoxy/Carbon Black Nanocomposite Coating on AA2024-T3.” J. Electrochem. Soc., 160 (4) C159–C167 (2013)CrossRefGoogle Scholar
  62. 62.
    Ghasemi-Kahrizsangi, A, et al., “Corrosion Behavior of Modified Nano Carbon Black/Epoxy Coating in Accelerated Conditions.” Appl. Surf. Sci., 331 115–126 (2015)CrossRefGoogle Scholar
  63. 63.
    Marchebois, H, et al., “Zinc-Rich Powder Coatings Corrosion in Sea Water: Influence of Conductive Pigments.” Prog. Org. Coat., 45 (4) 415–421 (2002)CrossRefGoogle Scholar
  64. 64.
    Marchebois, H, et al., “Electrochemical Behavior of Zinc-Rich Powder Coatings in Artificial Sea Water.” Electrochim. Acta, 49 (17) 2945–2954 (2004)CrossRefGoogle Scholar
  65. 65.
    Sheng, X, et al., “Synthesis of Functionalized Graphene/Polyaniline Nanocomposites with Effective Synergistic Reinforcement on Anticorrosion.” Ind. Eng. Chem. Res., 55 (31) 8576–8585 (2016)CrossRefGoogle Scholar
  66. 66.
    Breuer, O, Sundararaj, U, “Big Returns from Small Fibers: A Review of Polymer/Carbon Nanotube Composites.” Polym. Compos., 25 (6) 630–645 (2004)CrossRefGoogle Scholar
  67. 67.
    D’Souza, F, Handbook of Carbon Nano Materials. World Scientific, Singapore (2012)CrossRefGoogle Scholar
  68. 68.
    Ma, P-C, et al., “Dispersion and Functionalization of Carbon Nanotubes for Polymer-Based Nanocomposites: A Review.” Compos. A Appl. Sci. Manuf., 41 (10) 1345–1367 (2010)CrossRefGoogle Scholar
  69. 69.
    Irzhak, VI, “Epoxide Composite Materials with Carbon Nanotubes.” Russ. Chem. Rev., 80 (8) 787–806 (2011)CrossRefGoogle Scholar
  70. 70.
    Greßler, S, Fries, R, Simkó, M “Carbon Nanotubes – Part I: Introduction, Production, Areas of Application (NanoTrust Dossier No. 022en – February 2012), Wien”, p. 6 (2012)Google Scholar
  71. 71.
    Hammer, P, dos Santos, FC, Cerrutti, BM, Pulcinelli, SH, Santilli, CV, “Corrosion Resistant Coatings Based on Organic-inorganic Hybrids Reinforced by Carbon Nanotubes.” In: Recent Researches in Corrosion Evaluation and Protection. InTech (2012)Google Scholar
  72. 72.
    Wang, H, et al., “Tribological Behaviors of Aligned Carbon Nanotube/Fullerene-Epoxy Nanocomposites.” Polym. Eng. Sci., 48 (8) 1467–1475 (2008)CrossRefGoogle Scholar
  73. 73.
    Xiong, J, et al., “The Thermal and Mechanical Properties of a Polyurethane/Multi-Walled Carbon Nanotube Composite.” Carbon, 44 (13) 2701–2707 (2006)CrossRefGoogle Scholar
  74. 74.
    Hayashi, T, et al., “Mechanical Properties of Carbon Nanomaterials.” ChemPhysChem, 8 (7) 999–1004 (2007)CrossRefGoogle Scholar
  75. 75.
    Ramanathan, T, et al., “Functionalized Graphene Sheets for Polymer Nanocomposites.” Nat. Nanotechnol., 3 (6) 327–331 (2008)CrossRefGoogle Scholar
  76. 76.
    Ramirez, AP, “Carbon Nanotubes for Science and Technology.” Bell Labs Tech. J., 10 (3) 171–185 (2005)CrossRefGoogle Scholar
  77. 77.
    Gojny, F, et al., “Carbon Nanotube-Reinforced Epoxy-Composites: Enhanced Stiffness and Fracture Toughness at Low Nanotube Content.” Compos. Sci. Technol., 64 (15) 2363–2371 (2004)CrossRefGoogle Scholar
  78. 78.
    Moniruzzaman, M, Winey, KI, “Polymer Nanocomposites Containing Carbon Nanotubes.” Macromolecules, 39 (16) 5194–5205 (2006)CrossRefGoogle Scholar
  79. 79.
    Harris, PJ, “Carbon Nanotube Composites.” Int. Mater. Rev., 49 (1) 31–43 (2004)CrossRefGoogle Scholar
  80. 80.
    Endo, M, Strano, MS, Ajayan, PM, “Potential Applications of Carbon Nanotubes.” In: Carbon Nanotubes, pp. 13–62. Springer, Berlin (2007)Google Scholar
  81. 81.
    Baughman, RH, Zakhidov, AA, De Heer, WA, “Carbon Nanotubes–the Route Toward Applications.” Science, 297 (5582) 787–792 (2002)CrossRefGoogle Scholar
  82. 82.
    De Volder, MF, et al., “Carbon Nanotubes: Present and Future Commercial Applications.” Science, 339 (6119) 535–539 (2013)CrossRefGoogle Scholar
  83. 83.
    Bandaru, PR, “Electrical Properties and Applications of Carbon Nanotube Structures.” J. Nanosci. Nanotechnol., 7 (4–1) 1239–1267 (2007)CrossRefGoogle Scholar
  84. 84.
    Peigney, A, et al., “Specific Surface Area of Carbon Nanotubes and Bundles of Carbon Nanotubes.” Carbon, 39 (4) 507–514 (2001)CrossRefGoogle Scholar
  85. 85.
    Laurent, C, Flahaut, E, Peigney, A, “The Weight and Density of Carbon Nanotubes Versus the Number of Walls and Diameter.” Carbon, 48 (10) 2994–2996 (2010)CrossRefGoogle Scholar
  86. 86.
    Lukes, JR, Zhong, H, “Thermal Conductivity of Individual Single-Wall Carbon Nanotubes.” J. Heat Transfer, 129 (6) 705–716 (2007)CrossRefGoogle Scholar
  87. 87.
    Yu, M-F, et al., “Tensile Loading of Ropes of Single Wall Carbon Nanotubes and Their Mechanical Properties.” Phys. Rev. Lett., 84 (24) 5552 (2000)CrossRefGoogle Scholar
  88. 88.
    Aqel, A, et al., “Carbon Nanotubes, Science and Technology Part (I) Structure, Synthesis and Characterisation.” Arab. J. Chem., 5 (1) 1–23 (2012)CrossRefGoogle Scholar
  89. 89.
    Yu, M-F, et al., “Strength and Breaking Mechanism of Multiwalled Carbon Nanotubes Under Tensile Load.” Science, 287 (5453) 637–640 (2000)CrossRefGoogle Scholar
  90. 90.
    Khun, N, Troconis, BR, Frankel, G, “Effects of Carbon Nanotube Content on Adhesion Strength and Wear and Corrosion Resistance of Epoxy Composite Coatings on AA2024-T3.” Prog. Org. Coat., 77 (1) 72–80 (2014)CrossRefGoogle Scholar
  91. 91.
    Kumar, A, et al., “Thermo-Mechanical and Anti-Corrosive Properties of MWCNT/Epoxy Nanocomposite Fabricated by Innovative Dispersion Technique.” Compos. B Eng., 113 291–299 (2017)CrossRefGoogle Scholar
  92. 92.
    Kumar, A, et al., “Thermo-Mechanical and Anti-Corrosive Properties of MWCNT/Epoxy Nanocomposite Fabricated by Innovative Dispersion Technique.” Compos. B Eng., 113 291–299 (2017)CrossRefGoogle Scholar
  93. 93.
    Zhdanok, S, et al., “Influence of Carbon Nanomaterials on the Properties of Paint Coatings.” J. Eng. Phys. Thermophys., 84 (6) 1242–1246 (2011)CrossRefGoogle Scholar
  94. 94.
    Choi, Y-K, et al., “Processing and Characterization of Epoxy Nanocomposites Reinforced by Cup-Stacked Carbon Nanotubes.” Polymer, 46 (25) 11489–11498 (2005)CrossRefGoogle Scholar
  95. 95.
    Yokozeki, T, et al., “Fracture Toughness Improvement of CFRP Laminates by Dispersion of Cup-Stacked Carbon Nanotubes.” Compos. Sci. Technol., 69 (14) 2268–2273 (2009)CrossRefGoogle Scholar
  96. 96.
    Dunleavy, M., Dyke, HA, Haq, S, “Structural Health Monitoring Using Sprayable Paint Formulations.” Google Patents (2015)Google Scholar
  97. 97.
    Beigbeder, A, et al., “Preparation and Characterisation of Silicone-Based Coatings Filled with Carbon Nanotubes and Natural Sepiolite and Their Application as Marine Fouling-Release Coatings.” Biofouling, 24 (4) 291–302 (2008)CrossRefGoogle Scholar
  98. 98.
    Beigbeder, A, et al., “Marine Fouling Release Silicone/Carbon Nanotube Nanocomposite Coatings: On the Importance of the Nanotube Dispersion State.” J. Nanosci. Nanotechnol., 10 (5) 2972–2978 (2010)CrossRefGoogle Scholar
  99. 99.
    Il’darkhanova, F, et al., “Development of Paint Coatings with Superhydrophobic Properties.” Prot. Met. Phys. Chem. Surf., 48 (7) 796–802 (2012)CrossRefGoogle Scholar
  100. 100.
    Cui, M, et al., “Non-covalent Functionalized Multi-Wall Carbon Nanotubes Filled Epoxy Composites: Effect on Corrosion Protection and Tribological Performance.” Surf. Coat. Technol., 340 74–85 (2018)CrossRefGoogle Scholar
  101. 101.
    Subramanian, AS, et al., “Synergistic Bond Strengthening in Epoxy Adhesives Using Polydopamine/MWCNT Hybrids.” Polymer, 82 285–294 (2016)CrossRefGoogle Scholar
  102. 102.
    Cai, G, et al., “Polydopamine-Wrapped Carbon Nanotubes to Improve the Corrosion Barrier of Polyurethane Coating.” RSC Adv., 8 (42) 23727–23741 (2018)CrossRefGoogle Scholar
  103. 103.
    Yang, S-Y, et al., “Synergetic Effects of Graphene Platelets and Carbon Nanotubes on the Mechanical and Thermal Properties of Epoxy Composites.” Carbon, 49 (3) 793–803 (2011)CrossRefGoogle Scholar
  104. 104.
    Yang, H, et al., “Convenient Preparation of Tunably Loaded Chemically Converted Graphene Oxide/Epoxy Resin Nanocomposites from Graphene Oxide Sheets Through Two-Phase Extraction.” J. Mater. Chem., 19 (46) 8856–8860 (2009)CrossRefGoogle Scholar
  105. 105.
    Dennis, RV, et al., “Graphene Nanocomposite Coatings for Protecting Low-Alloy Steels from Corrosion.” Am. Ceram. Soc. Bull., 92 (5) 18–24 (2013)Google Scholar
  106. 106.
    Jackson, P, et al., “Bioaccumulation and Ecotoxicity of Carbon Nanotubes.” Chem. Cent. J., 7 (1) 154 (2013)CrossRefGoogle Scholar
  107. 107.
    Bystrzejewska-Piotrowska, G, Golimowski, J, Urban, PL, “Nanoparticles: Their Potential Toxicity, Waste and Environmental Management.” Waste Manag., 29 (9) 2587–2595 (2009)CrossRefGoogle Scholar
  108. 108.
    Gu, B-E, et al., “Effects of Multiwall Carbon Nanotube Addition on the Corrosion Resistance and Underwater Acoustic Absorption Properties of Polyurethane Coatings.” Prog. Org. Coat., 121 226–235 (2018)CrossRefGoogle Scholar
  109. 109.
    Pham, GV, et al., “Incorporation of Fe3O4/CNTs Nanocomposite in an Epoxy Coating for Corrosion Protection of Carbon Steel.” Adv. Nat. Sci. Nanosci. Nanotechnol., 5 (3) 035016 (2014)CrossRefGoogle Scholar
  110. 110.
    Yang, Y, et al., “Graphene Based Materials for Biomedical Applications.” Mater. Today, 16 (10) 365–373 (2013)CrossRefGoogle Scholar
  111. 111.
    Soldano, C, Mahmood, A, Dujardin, E, “Production, Properties and Potential of Graphene.” Carbon, 48 (8) 2127–2150 (2010)CrossRefGoogle Scholar
  112. 112.
    Edwards, RS, Coleman, KS, “Graphene Synthesis: Relationship to Applications.” Nanoscale, 5 (1) 38–51 (2013)CrossRefGoogle Scholar
  113. 113.
    Rong, J, et al., “Solution Ionic Strength Engineering as a Generic Strategy to Coat Graphene Oxide (GO) on Various Functional Particles and Its Application in High-Performance Lithium–Sulfur (Li–S) Batteries.” Nano Lett., 14 (2) 473–479 (2013)CrossRefGoogle Scholar
  114. 114.
    Berry, V, “Impermeability of Graphene and Its Applications.” Carbon, 62 1–10 (2013)CrossRefGoogle Scholar
  115. 115.
    Dhand, V, et al., “A Comprehensive Review of Graphene Nanocomposites: Research Status and Trends.” J. Nanomater., 2013 158 (2013)CrossRefGoogle Scholar
  116. 116.
    Liang, J, et al., “Electromagnetic Interference Shielding of Graphene/Epoxy Composites.” Carbon, 47 (3) 922–925 (2009)CrossRefGoogle Scholar
  117. 117.
    Yang, H, et al., “Covalent Functionalization of Chemically Converted Graphene Sheets via Silane and Its Reinforcement.” J. Mater. Chem., 19 (26) 4632–4638 (2009)CrossRefGoogle Scholar
  118. 118.
    Yang, H, et al., “Covalent Functionalization of Polydisperse Chemically-Converted Graphene Sheets with Amine-Terminated Ionic Liquid.” Chem. Commun., 26 3880–3882 (2009)CrossRefGoogle Scholar
  119. 119.
    Verdejo, R, et al., “Graphene Filled Polymer Nanocomposites.” J. Mater. Chem., 21 (10) 3301–3310 (2011)CrossRefGoogle Scholar
  120. 120.
    Guo, Y, et al., “In Situ Polymerization of Graphene, Graphite Oxide, and Functionalized Graphite Oxide into Epoxy Resin and Comparison Study of on-the-Flame Behavior.” Ind. Eng. Chem. Res., 50 (13) 7772–7783 (2011)CrossRefGoogle Scholar
  121. 121.
    Rafiee, MA, et al., “Enhanced Mechanical Properties of Nanocomposites at Low Graphene Content.” ACS Nano, 3 (12) 3884–3890 (2009)CrossRefGoogle Scholar
  122. 122.
    Bao, C, et al., “Functionalized Graphene Oxide for Fire Safety Applications of Polymers: A Combination of Condensed Phase Flame Retardant Strategies.” J. Mater. Chem., 22 (43) 23057–23063 (2012)CrossRefGoogle Scholar
  123. 123.
    Wang, S, et al., “Thermal Expansion of Graphene Composites.” Macromolecules, 42 (14) 5251–5255 (2009)CrossRefGoogle Scholar
  124. 124.
    Das, TK, Prusty, S, “Graphene-Based Polymer Composites and Their Applications.” Polym.-Plast. Technol. Eng., 52 (4) 319–331 (2013)CrossRefGoogle Scholar
  125. 125.
    Huang, G, et al., “How Can Graphene Reduce the Flammability of Polymer Nanocomposites?” Mater. Lett., 66 (1) 187–189 (2012)CrossRefGoogle Scholar
  126. 126.
    Seresht, RJ, et al., “Synthesize and Characterization of Graphene Nanosheets with High Surface Area and Nano-Porous Structure.” Appl. Surf. Sci., 276 672–681 (2013)CrossRefGoogle Scholar
  127. 127.
    Kuang, D, et al., “Graphene–Nickel Composites.” Appl. Surf. Sci., 273 484–490 (2013)CrossRefGoogle Scholar
  128. 128.
    Novoselov, KS, et al., “A Roadmap for Graphene.” Nature, 490 (7419) 192–200 (2012)CrossRefGoogle Scholar
  129. 129.
    Kousalya, AS, et al., “Graphene: An Effective Oxidation Barrier Coating for Liquid and Two-Phase Cooling Systems.” Corros. Sci., 69 5–10 (2013)CrossRefGoogle Scholar
  130. 130.
    Singhbabu, Y, et al., “Corrosion-Protective Reduced Graphene Oxide Coated Cold Rolled Steel Prepared Using Industrial Setup: A Study of Protocol Feasibility for Commercial Production.” Surf. Coat. Technol., 349 119–132 (2018)CrossRefGoogle Scholar
  131. 131.
    Qiu, J, Wang, S, “Enhancing Polymer Performance Through Graphene Sheets.” J. Appl. Polym. Sci., 119 (6) 3670–3674 (2011)CrossRefGoogle Scholar
  132. 132.
    Zhu, Y, et al., “Graphene and Graphene Oxide: Synthesis, Properties, and Applications.” Adv. Mater., 22 (35) 3906–3924 (2010)CrossRefGoogle Scholar
  133. 133.
    Yu, A, et al., “Graphite Nanoplatelet—Epoxy Composite Thermal Interface Materials.” J. Phys. Chem. C, 111 (21) 7565–7569 (2007)CrossRefGoogle Scholar
  134. 134.
    Yavari, F, et al., “Dramatic Increase in Fatigue Life in Hierarchical Graphene Composites.” ACS Appl. Mater. Interfaces., 2 (10) 2738–2743 (2010)CrossRefGoogle Scholar
  135. 135.
    Wang, X, et al., “Covalent Functionalization of Graphene with Organosilane and Its Use as a Reinforcement in Epoxy Composites.” Compos. Sci. Technol., 72 (6) 737–743 (2012)CrossRefGoogle Scholar
  136. 136.
    Grande, L, et al., “Graphene for Energy Harvesting/Storage Devices and Printed Electronics.” Particuology, 10 (1) 1–8 (2012)CrossRefGoogle Scholar
  137. 137.
    Ping, J, et al., “Simultaneous Determination of Ascorbic Acid, Dopamine and Uric Acid Using High-Performance Screen-Printed Graphene Electrode.” Biosens. Bioelectron., 34 (1) 70–76 (2012)CrossRefGoogle Scholar
  138. 138.
    Xu, Y, et al., “Inkjet-Printed Energy Storage Device Using Graphene/Polyaniline Inks.” J. Power Sources, 248 483–488 (2014)CrossRefGoogle Scholar
  139. 139.
    Shao, Y, et al., “Graphene Based Electrochemical Sensors and Biosensors: A Review.” Electroanalysis, 22 (10) 1027–1036 (2010)CrossRefGoogle Scholar
  140. 140.
    Gadipelli, S, Guo, ZX, “Graphene-Based Materials: Synthesis and Gas Sorption, Storage and Separation.” Prog. Mater Sci., 69 1–60 (2015)CrossRefGoogle Scholar
  141. 141.
    Yang, L, et al., “A High Throughput Method for Preparation of Highly Conductive Functionalized Graphene and Conductive Polymer Nanocomposites.” RSC Adv., 2 (6) 2208–2210 (2012)CrossRefGoogle Scholar
  142. 142.
    Pop, E, Varshney, V, Roy, AK, “Thermal Properties of Graphene: Fundamentals and Applications.” MRS Bull., 37 (12) 1273–1281 (2012)CrossRefGoogle Scholar
  143. 143.
    Yoo, BM, et al, “Graphene and Graphene Oxide and Their Uses in Barrier Polymers.” J. Appl. Polym. Sci.131 (1) (2014).Google Scholar
  144. 144.
    Li, X, et al., “Synthesis, Characterization, and Properties of Large-Area Graphene Films.” ECS Trans., 19 (5) 41–52 (2009)CrossRefGoogle Scholar
  145. 145.
    Lee, C, et al., “Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene.” Science, 321 (5887) 385–388 (2008)CrossRefGoogle Scholar
  146. 146.
    Sun, W, et al., “The Role of Graphene Loading on the Corrosion-Promotion Activity of Graphene/Epoxy Nanocomposite Coatings.” Compos. B Eng., 173 106916 (2019)CrossRefGoogle Scholar
  147. 147.
    Christopher, G, Anbu Kulandainathan, M, Harichandran, G, “Comparative Study of Effect of Corrosion on Mild Steel with Waterborne Polyurethane Dispersion Containing Graphene Oxide Versus Carbon Black Nanocomposites.” Prog. Org. Coat., 89 199–211 (2015)CrossRefGoogle Scholar
  148. 148.
    Monetta, T, Acquesta, A, Bellucci, F, “Graphene/Epoxy Coating as Multifunctional Material for Aircraft Structures.” Aerospace, 2 (3) 423–434 (2015)CrossRefGoogle Scholar
  149. 149.
    Liu, S, et al., “Corrosion Resistance of Graphene-Reinforced Waterborne Epoxy Coatings.” J. Mater. Sci. Technol., 32 (5) 425–431 (2016)CrossRefGoogle Scholar
  150. 150.
    Zhang, Z, et al., “Mechanical and Anticorrosive Properties of Graphene/Epoxy Resin Composites Coating Prepared by In Situ Method.” Int. J. Mol. Sci., 16 (1) 2239–2251 (2015)CrossRefGoogle Scholar
  151. 151.
    Chang, C-H, et al., “Novel Anticorrosion Coatings Prepared from Polyaniline/Graphene Composites.” Carbon, 50 (14) 5044–5051 (2012)CrossRefGoogle Scholar
  152. 152.
    Chen, C, et al., “Achieving High Performance Corrosion and Wear Resistant Epoxy Coatings Via Incorporation of Noncovalent Functionalized Graphene.” Carbon, 114 356–366 (2017)CrossRefGoogle Scholar
  153. 153.
    Sun, W, et al., “Inhibiting the Corrosion-Promotion Activity of Graphene.” Chem. Mater., 27 (7) 2367–2373 (2015)CrossRefGoogle Scholar
  154. 154.
    Zhu, K., et al., “Electrochemical and Anti‐Corrosion Behaviors of Water Dispersible Graphene/Acrylic Modified Alkyd Resin Latex Composites Coated Carbon Steel.” J. Appl. Polym. Sci.134 (11) (2017).Google Scholar
  155. 155.
    Ding, R, et al., “Study of Water Permeation Dynamics and Anti-Corrosion Mechanism of Graphene/Zinc Coatings.” J. Alloy. Compd., 748 481–495 (2018)CrossRefGoogle Scholar
  156. 156.
    Zhou, S, et al., “Designing Reduced Graphene Oxide/Zinc Rich Epoxy Composite Coatings for Improving the Anticorrosion Performance of Carbon Steel Substrate.” Mater. Des., 169 107694 (2019)CrossRefGoogle Scholar
  157. 157.
    Upadhyayula, VK, et al., “Screening-Level Life Cycle Assessment of Graphene-Poly(ether imide) Coatings Protecting Unalloyed Steel from Severe Atmospheric Corrosion.” ACS Sustain. Chem. Eng., 5 (3) 2656–2667 (2017)CrossRefGoogle Scholar
  158. 158.
    Glover, C, et al., “In-Coating Graphene Nano-Platelets for Environmentally-Friendly Corrosion Protection of Iron.” Corros. Sci., 114 169–172 (2017)CrossRefGoogle Scholar
  159. 159.
    Ding, R, et al., “Study on Evolution of Coating State and Role of Graphene in Graphene-Modified Low-Zinc Waterborne Epoxy Anticorrosion Coating by Electrochemical Impedance Spectroscopy.” J. Mater. Eng. Perform., 26 (7) 3319–3335 (2017)CrossRefGoogle Scholar
  160. 160.
    Luo, X, et al., “Cationic Reduced Graphene Oxide as Self-Aligned Nanofiller in the Epoxy Nanocomposite Coating with Excellent Anticorrosive Performance and Its High Antibacterial Activity.” ACS Appl. Mater. Interfaces., 10 (21) 18400–18415 (2018)CrossRefGoogle Scholar
  161. 161.
    Lin, Y-T, et al “Improvement of Mechanical Properties and Anticorrosion Performance of Epoxy Coatings by the Introduction of Polyaniline/Graphene Composite.” Surf. Coat. Technol., 374 1128–1138 (2018)CrossRefGoogle Scholar
  162. 162.
    Yang, T, et al., “Enhancement of the Corrosion Resistance of Epoxy Coating by Highly Stable 3, 4, 9, 10-Perylene Tetracarboxylic Acid Functionalized Graphene.” J. Hazard. Mater., 357 475–482 (2018)CrossRefGoogle Scholar
  163. 163.
    Mahmudzadeh, M. et al, “Urtica dioica Extract as a Facile Green Reductant of Graphene Oxide for UV Resistant and Corrosion Protective Polyurethane Coating Fabrication.” J. Ind. Eng. Chem., 78 125–136 (2019)CrossRefGoogle Scholar
  164. 164.
    Wang, M-H, et al., “Effect of Oxygen-Containing Functional Groups in Epoxy/Reduced Graphene Oxide Composite Coatings on Corrosion Protection and Antimicrobial Properties.” Appl. Surf. Sci., 448 351–361 (2018)CrossRefGoogle Scholar
  165. 165.
    Zhang, WL, Choi, HJ, “Silica-Graphene Oxide Hybrid Composite Particles and Their Electroresponsive Characteristics.” Langmuir, 28 (17) 7055–7062 (2012)CrossRefGoogle Scholar
  166. 166.
    Huang, H-D, et al., “High Barrier Graphene Oxide Nanosheet/Poly(vinyl alcohol) Nanocomposite Films.” J. Membr. Sci., 409 156–163 (2012)CrossRefGoogle Scholar
  167. 167.
    Montes-Navajas, P, et al., “Surface Area Measurement of Graphene Oxide in Aqueous Solutions.” Langmuir, 29 (44) 13443–13448 (2013)CrossRefGoogle Scholar
  168. 168.
    Mu, X, et al., “Thermal Transport in Graphene Oxide–From Ballistic Extreme to Amorphous Limit.” Sci. Rep., 4 3909 (2014)CrossRefGoogle Scholar
  169. 169.
    Mitrakas, D, Danikas, M “Insulating Properties of Graphene Oxide.” Funktech. J. (10) (2016)Google Scholar
  170. 170.
    Cao, C, et al., “High Strength Measurement of Monolayer Graphene Oxide.” Carbon, 81 497–504 (2015)CrossRefGoogle Scholar
  171. 171.
    Chang, K-C, et al., “Synergistic Effects of Hydrophobicity and Gas Barrier Properties on the Anticorrosion Property of PMMA Nanocomposite Coatings Embedded with Graphene Nanosheets.” Polym. Chem., 5 (3) 1049–1056 (2013)CrossRefGoogle Scholar
  172. 172.
    Jiang, F, et al., “Anti-Corrosion Behaviors of Epoxy Composite Coatings Enhanced via Graphene Oxide with Different Aspect Ratios.” Prog. Org. Coat., 127 70–79 (2019)CrossRefGoogle Scholar
  173. 173.
    Rajabi, M, Rashed, G, Zaarei, D, “Assessment of Graphene Oxide/Epoxy Nanocomposite as Corrosion Resistance Coating on Carbon Steel.” Corros. Eng. Sci. Technol., 50 (7) 509–516 (2015)CrossRefGoogle Scholar
  174. 174.
    Pourhashem, S, et al., “Exploring Corrosion Protection Properties of Solvent Based Epoxy-Graphene Oxide Nanocomposite Coatings on Mild Steel.” Corros. Sci., 115 78–92 (2017)CrossRefGoogle Scholar
  175. 175.
    Gudarzi, MM, Sharif, F, “Enhancement of Dispersion and Bonding of Graphene-Polymer Through Wet Transfer of Functionalized Graphene Oxide.” Express Polym. Lett.6 (12) 1017–1031 (2012)CrossRefGoogle Scholar
  176. 176.
    Chen, L, et al., “A Design of Gradient Interphase Reinforced by Silanized Graphene Oxide and Its Effect on Carbon Fiber/Epoxy Interface.” Mater. Chem. Phys., 145 (1) 186–196 (2014)CrossRefGoogle Scholar
  177. 177.
    Georgakilas, V, et al., “Functionalization of Graphene: Covalent and Non-covalent Approaches.” Deriv. Appl. Chem. Rev., 112 (11) 6156–6214 (2012)Google Scholar
  178. 178.
    Ramezanzadeh, B, et al., “Enhancement of Barrier and Corrosion Protection Performance of an Epoxy Coating Through Wet Transfer of Amino Functionalized Graphene Oxide.” Corros. Sci., 103 283–304 (2016)CrossRefGoogle Scholar
  179. 179.
    Ramezanzadeh, B, et al., “Covalently-Grafted Graphene Oxide Nanosheets to Improve Barrier and Corrosion Protection Properties of Polyurethane Coatings.” Carbon, 93 555–573 (2015)CrossRefGoogle Scholar
  180. 180.
    Yu, Y-H, et al., “High-Performance Polystyrene/Graphene-Based Nanocomposites with Excellent Anti-Corrosion Properties.” Polym. Chem., 5 (2) 535–550 (2014)CrossRefGoogle Scholar
  181. 181.
    Zheng, H., et al., “Reinforcing the Corrosion Protection Property of Epoxy Coating by Using Graphene Oxide–Poly (Urea–Formaldehyde) Composites.” Corros. Sci., 123 267–277 (2017)CrossRefGoogle Scholar
  182. 182.
    Mo, M, et al., “Excellent Tribological and Anti-Corrosion Performance of Polyurethane Composite Coatings Reinforced with Functionalized Graphene and Graphene Oxide Nanosheets.” RSC Adv., 5 (70) 56486–56497 (2015)CrossRefGoogle Scholar
  183. 183.
    Dong, R, Liu, L, “Preparation and Properties of Acrylic Resin Coating Modified by Functional Graphene Oxide.” Appl. Surf. Sci., 368 378–387 (2016)CrossRefGoogle Scholar
  184. 184.
    Pourhashem, S, et al., “Distinctive Roles of Silane Coupling Agents on the Corrosion Inhibition Performance of Graphene Oxide in Epoxy Coatings.” Prog. Org. Coat., 111 47–56 (2017)CrossRefGoogle Scholar
  185. 185.
    Pourhashem, S, et al., “Excellent Corrosion Protection Performance of Epoxy Composite Coatings Filled with Amino-Silane Functionalized Graphene Oxide.” Surf. Coat. Technol., 317 1–9 (2017)CrossRefGoogle Scholar
  186. 186.
    Qian, R, et al., “Alumina-Coated Graphene Sheet Hybrids for Electrically Insulating Polymer Composites with High Thermal Conductivity.” RSC Adv., 3 (38) 17373–17379 (2013)CrossRefGoogle Scholar
  187. 187.
    Sun, C-L, et al., “The Simultaneous Electrochemical Detection of Ascorbic Acid, Dopamine, and Uric Acid Using Graphene/Size-Selected Pt Nanocomposites.” Biosens. Bioelectron., 26 (8) 3450–3455 (2011)CrossRefGoogle Scholar
  188. 188.
    Yu, Z, et al., “Fabrication of Graphene Oxide–Alumina Hybrids to Reinforce the Anti-Corrosion Performance of Composite Epoxy Coatings.” Appl. Surf. Sci., 351 986–996 (2015)CrossRefGoogle Scholar
  189. 189.
    Yu, Z, et al., “Preparation of Graphene Oxide Modified by Titanium Dioxide to Enhance the Anti-Corrosion Performance of Epoxy Coatings.” Surf. Coat. Technol., 276 471–478 (2015)CrossRefGoogle Scholar
  190. 190.
    Ma, Y, et al., “Fabrication of Silica-Decorated Graphene Oxide Nanohybrids and the Properties of Composite Epoxy Coatings Research.” Appl. Surf. Sci., 360 936–945 (2016)CrossRefGoogle Scholar
  191. 191.
    Ramezanzadeh, B, Haeri, Z, Ramezanzadeh, M, “A Facile Route of Making Silica Nanoparticles-Covered Graphene Oxide Nanohybrids (SiO2-GO); Fabrication of SiO2-GO/Epoxy Composite Coating with Superior Barrier and Corrosion Protection Performance.” Chem. Eng. J., 303 511–528 (2016)CrossRefGoogle Scholar
  192. 192.
    Pourhashem, S, Vaezi, MR, Rashidi, A, “Investigating the Effect of SiO2-Graphene Oxide Hybrid as Inorganic Nanofiller on Corrosion Protection Properties of Epoxy Coatings.” Surf. Coat. Technol., 311 282–294 (2017)CrossRefGoogle Scholar
  193. 193.
    Liu, J, et al., “Silane Modification of Titanium Dioxide-Decorated Graphene Oxide Nanocomposite for Enhancing Anticorrosion Performance of Epoxy Coatings on AA-2024.” J. Alloy. Compd., 744 728–739 (2018)CrossRefGoogle Scholar
  194. 194.
    Liu, Y, et al., “Cost-Effective Reduced Graphene Oxide-Coated Polyurethane Sponge as a Highly Efficient and Reusable Oil-Absorbent.” ACS Appl. Mater. Interfaces., 5 (20) 10018–10026 (2013)CrossRefGoogle Scholar
  195. 195.
    Caldona, EB, et al., “On the Enhanced Corrosion Resistance of Elastomer-Modified Polybenzoxazine/Graphene Oxide Nanocomposite Coatings.” React. Funct. Polym., 123 10–19 (2018)CrossRefGoogle Scholar
  196. 196.
    Cui, M, et al., “Polydopamine Coated Graphene Oxide for Anticorrosive Reinforcement of Water-Borne Epoxy Coating.” Chem. Eng. J., 335 255–266 (2018)CrossRefGoogle Scholar
  197. 197.
    Li, X, et al., “Fabrication of Functionalized Graphene Oxide/Maleic Anhydride Grafted Polypropylene Composite Film with Excellent Gas Barrier and Anticorrosion Properties.” J. Membr. Sci., 547 80–92 (2018)CrossRefGoogle Scholar
  198. 198.
    Hayatgheib, Y, et al., “A Comparative Study on Fabrication of a Highly Effective Corrosion Protective System Based on Graphene Oxide-Polyaniline Nanofibers/Epoxy Composite.” Corros. Sci., 133 358–373 (2018)CrossRefGoogle Scholar
  199. 199.
    Zhang, X, et al., “Corrosion Resistance of Organic Coating Based on Polyhedral Oligomeric Silsesquioxane-Functionalized Graphene Oxide.” Appl. Surf. Sci., 484 814–824 (2019)CrossRefGoogle Scholar
  200. 200.
    Haghdadeh, P, et al., “The Role of Functionalized Graphene Oxide on the Mechanical and Anti-Corrosion Properties of Polyurethane Coating.” J. Taiwan Inst. Chem. Eng., 86 199–212 (2018)CrossRefGoogle Scholar
  201. 201.
    Ramezanzadeh, B, Bahlakeh, G, Ramezanzadeh, M, “Polyaniline-Cerium Oxide (PAni-CeO2) Coated Graphene Oxide for Enhancement of Epoxy Coating Corrosion Protection Performance on Mild Steel.” Corros. Sci., 137 111–126 (2018)CrossRefGoogle Scholar
  202. 202.
    Taheri, NN, Ramezanzadeh, B, Mahdavian, M, “Application of Layer-by-Layer Assembled Graphene Oxide Nanosheets/Polyaniline/Zinc Cations for Construction of an Effective Epoxy Coating Anti-Corrosion System.” J. Alloys Compd., 800 532–549 (2019)CrossRefGoogle Scholar
  203. 203.
    Teng, S, et al., “Zinc-Reduced Graphene Oxide for Enhanced Corrosion Protection of Zinc-Rich Epoxy Coatings.” Prog. Org. Coat., 123 185–189 (2018)CrossRefGoogle Scholar
  204. 204.
    Zhang, Z, et al., “Graphene Quantum Dots: An Emerging Material for Energy-Related Applications and Beyond.” Energy Environ. Sci., 5 (10) 8869–8890 (2012)CrossRefGoogle Scholar
  205. 205.
    Hu, Y, et al., “Waste Frying Oil as a Precursor for One-Step Synthesis of Sulfur-Doped Carbon Dots with pH-Sensitive Photoluminescence.” Carbon, 77 775–782 (2014)CrossRefGoogle Scholar
  206. 206.
    Namdari, P, Negahdari, B, Eatemadi, A, “Synthesis, Properties and Biomedical Applications of Carbon-Based Quantum Dots: An Updated Review.” Biomed. Pharmacother., 87 209–222 (2017)CrossRefGoogle Scholar
  207. 207.
    Sun, H, et al., “Recent Advances in Graphene Quantum Dots for Sensing.” Mater. Today, 16 (11) 433–442 (2013)CrossRefGoogle Scholar
  208. 208.
    Zhu, S, et al., “The Photoluminescence Mechanism in Carbon Dots (Graphene Quantum Dots, Carbon Nanodots, and Polymer Dots): Current State and Future Perspective.” Nano Res., 8 (2) 355–381 (2015)CrossRefGoogle Scholar
  209. 209.
    Cui, M, et al., “Carbon Dots as New Eco-Friendly and Effective Corrosion Inhibitor.” J. Alloy. Compd., 726 680–692 (2017)CrossRefGoogle Scholar
  210. 210.
    Konwar, A, et al., “Green Chitosan–Carbon Dots Nanocomposite Hydrogel Film with Superior Properties.” Carbohyd. Polym., 115 238–245 (2015)CrossRefGoogle Scholar
  211. 211.
    Zhu, C, et al., “Carbon Dots as Fillers Inducing Healing/Self‐Healing and Anticorrosion Properties in Polymers.” Adv. Mater., 29 (32) 1701399 (2017)CrossRefGoogle Scholar
  212. 212.
    Ramezanzadeh, B, et al., “Synthesis and Characterization of Polyaniline Tailored Graphene Oxide Quantum Dot as an Advance and Highly Crystalline Carbon-Based Luminescent Nanomaterial for Fabrication of an Effective Anti-Corrosion Epoxy System on Mild Steel.” J. Taiwan Inst. Chem. Eng., 95 369–382 (2019)CrossRefGoogle Scholar
  213. 213.
    Ren, S, et al., “Effect of Nitrogen-Doped Carbon Dots on the Anticorrosion Properties of Waterborne Epoxy Coatings.” Surf. Topogr. Metrol. Prop., 6 (2) 024003 (2018)CrossRefGoogle Scholar
  214. 214.
    Hu, H, et al., “Synergistic Effect of Functional Carbon Nanotubes and Graphene Oxide on the Anti-Corrosion Performance of Epoxy Coating.” Polym. Adv. Technol., 28 (6) 754–762 (2017)CrossRefGoogle Scholar
  215. 215.
    Almajid, A, et al., “Effects of Graphene and CNT on Mechanical, Thermal, Electrical and Corrosion Properties of Vinylester Based Nanocomposites.” Plast. Rubber Compos., 44 (2) 50–62 (2015)CrossRefGoogle Scholar
  216. 216.
    Asthana, A, et al., “Multifunctional Superhydrophobic Polymer/Carbon Nanocomposites: Graphene, Carbon Nanotubes, or Carbon Black?” ACS Appl. Mater. Interfaces., 6 (11) 8859–8867 (2014)CrossRefGoogle Scholar
  217. 217.
    Yang, C, et al., “Polymer Nanocomposites for Energy Storage, Energy Saving, and Anticorrosion.” J. Mater. Chem. A, 3 (29) 14929–14941 (2015)CrossRefGoogle Scholar
  218. 218.
    Grundmeier, G, Schmidt, W, Stratmann, M, “Corrosion Protection by Organic Coatings: Electrochemical Mechanism and Novel Methods of Investigation.” Electrochim. Acta, 45 (15) 2515–2533 (2000)CrossRefGoogle Scholar
  219. 219.
    Sørensen, PA, et al., “Anticorrosive Coatings: A Review.” J. Coat. Technol. Res., 6 (2) 135–176 (2009)CrossRefGoogle Scholar
  220. 220.
    Shi, X, et al., “Effect of Nanoparticles on the Anticorrosion and Mechanical Properties of Epoxy Coating.” Surf. Coat. Technol., 204 (3) 237–245 (2009)CrossRefGoogle Scholar
  221. 221.
    Zhao, X, et al., “Enhanced Mechanical Properties of Graphene-Based Poly(vinyl alcohol) Composites.” Macromolecules, 43 (5) 2357–2363 (2010)CrossRefGoogle Scholar
  222. 222.
    Liu, S, et al., “Effect of Graphene Nanosheets on Morphology, Thermal Stability and Flame Retardancy of Epoxy Resin.” Compos. Sci. Technol., 90 40–47 (2014)CrossRefGoogle Scholar
  223. 223.
    Sagade, AA, et al., “Graphene-Based Nanolaminates as Ultra-High Permeation Barriers.” npj 2D Mater. Appl., 1 (1) 35 (2017)CrossRefGoogle Scholar
  224. 224.
    Yu, F, et al., “Complete Long-Term Corrosion Protection with Chemical Vapor Deposited Graphene.” Carbon, 132 78–84 (2018)CrossRefGoogle Scholar
  225. 225.
    Wan, Y-J, et al., “Grafting of Epoxy Chains onto Graphene Oxide for Epoxy Composites with Improved Mechanical and Thermal Properties.” Carbon, 69 467–480 (2014)CrossRefGoogle Scholar
  226. 226.
    Wan, Y-J, et al., “Improved Dispersion and Interface in the Graphene/Epoxy Composites Via a Facile Surfactant-Assisted Process.” Compos. Sci. Technol., 82 60–68 (2013)CrossRefGoogle Scholar
  227. 227.
    Smulders, S, et al., “Toxicity of Nanoparticles Embedded in Paints Compared with Pristine Nanoparticles in Mice.” Toxicol. Sci., 141 (1) 132–140 (2014)CrossRefGoogle Scholar
  228. 228.
    Colvin, VL, “The Potential Environmental Impact of Engineered Nanomaterials.” Nat. Biotechnol., 21 (10) 1166 (2003)CrossRefGoogle Scholar
  229. 229.
    Ong, YT, et al., “A Review on Carbon Nanotubes in an Environmental Protection and Green Engineering Perspective.” Braz. J. Chem. Eng., 27 (2) 227–242 (2010)CrossRefGoogle Scholar
  230. 230.
    Zhang, Y, et al., “Cytotoxicity Effects of Graphene and Single-Wall Carbon Nanotubes in Neural Phaeochromocytoma-Derived PC12 Cells.” ACS Nano, 4 (6) 3181–3186 (2010)CrossRefGoogle Scholar
  231. 231.
    Lewinski, N, Colvin, V, Drezek, R, “Cytotoxicity of Nanoparticles.” Small, 4 (1) 26–49 (2008)CrossRefGoogle Scholar
  232. 232.
    Nel, A, et al., “Toxic Potential of Materials at the Nanolevel.” Science, 311 (5761) 622–627 (2006)CrossRefGoogle Scholar
  233. 233.
    Magrez, A, et al., “Cellular Toxicity of Carbon-Based Nanomaterials.” Nano Lett., 6 (6) 1121–1125 (2006)CrossRefGoogle Scholar
  234. 234.
    Young Park, S, et al., “Eco-Friendly Carbon-Nanodot-Based Fluorescent Paints for Advanced Photocatalytic Systems.” Sci. Rep., 5 12420 (2015)CrossRefGoogle Scholar
  235. 235.
    Yang, S-T, et al., “Carbon Dots as Nontoxic and High-Performance Fluorescence Imaging Agents.” J. Phys. Chem. C, 113 (42) 18110–18114 (2009)CrossRefGoogle Scholar
  236. 236.
    Saber, AT, et al., “Inflammatory and Genotoxic Effects of Sanding Dust Generated from Nanoparticle-Containing Paints and Lacquers.” Nanotoxicology, 6 (7) 776–788 (2012)CrossRefGoogle Scholar
  237. 237.
    Saber, AT, et al., “Nanotitanium Dioxide Toxicity in Mouse Lung is Reduced in Sanding Dust from Paint.” Part. Fibre Toxicol., 9 (1) 4 (2012)CrossRefGoogle Scholar

Copyright information

© American Coatings Association 2019

Authors and Affiliations

  • Sepideh Pourhashem
    • 1
  • Ebrahim Ghasemy
    • 2
  • Alimorad Rashidi
    • 1
    Email author
  • Mohammad Reza Vaezi
    • 3
  1. 1.Nanotechnology Research CenterResearch Institute of Petroleum Industry (RIPI)TehranIran
  2. 2.Nanotechnology Department, School of New TechnologiesIran University of Science and TechnologyTehranIran
  3. 3.Department of Nanotechnology and Advanced MaterialsMaterials and Energy Research CenterKarajIran

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