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Enhanced corrosion resistance and weathering resistance of waterborne epoxy coatings with polyetheramine-functionalized graphene oxide

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Abstract

Polyetheramine (D230), an epoxy curing agent, was grafted on graphene oxide (GO) surfaces, which can be stably dispersed in a waterborne curing agent for more than 8 months. Waterborne epoxy coatings reinforced by D230-functionalized GO (DGO) were prepared on carbon steel surfaces. According to the electrochemical impedance spectra, the impedance modulus at 0.1 Hz remained at 2.2 × 109 Ω after 150 days of immersion in 3.5% NaCl electrolytes for 0.2 wt% DGO-reinforced waterborne epoxy coatings, while that of the neat epoxy coatings dropped below 1 × 107 Ω after 10 days. Besides, the addition of DGO enhanced the weathering resistance of waterborne epoxy coatings. After 60 days of the UV aging test, the yellow color index of neat epoxy coatings was 1.6 times that of 0.5 wt% DGO/epoxy coatings. The residual pencil hardness of the 0.5 wt% DGO/epoxy coatings was three levels higher than that of neat epoxy coatings.

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References

  1. 1.

    Wang, SB, Ang, HM, Tade, MO, “Volatile Organic Compounds in Indoor Environment and Photocatalytic Oxidation: State of the Art.” Environ. Int., 33 (5) 694–705 (2007)

  2. 2.

    Harkal, UD, Muehlberg, AJ, Edwards, PA, Webster, DC, “Novel Water-Dispersible Glycidyl Carbamate (GC) Resins and Waterborne Amine-Cured Coatings.” J. Coat. Technol. Res., 8 (6) 735–747 (2011)

  3. 3.

    Yu, J, Pan, H, Zhou, X, “Preparation of Waterborne Phosphated Acrylate-Epoxy Hybrid Dispersions and Their Application as Coil Coating Primer.” J. Coat. Technol. Res., 11 (3) 361–369 (2014)

  4. 4.

    Wang, Z, Han, E, Liu, F, Qian, Z, Zhu, L, “Waterborne Epoxy Nanocoatings Modified by Nanoemulsions and Nanoparticles.” J. Mater. Sci. Technol., 30 (10) 1036–1042 (2014)

  5. 5.

    Ai, L, Liu, Y, Zhang, XY, Ouyang, XH, Ge, ZY, “A Facile and Template-Free Method for Preparation of Polythiophene Microspheres and Their Dispersion for Waterborne Corrosion Protection Coatings.” Synth. Met., 191 41–46 (2014)

  6. 6.

    Rahman, OU, Kashif, M, Ahmad, S, “Nanoferrite Dispersed Waterborne Epoxy-Acrylate: Anticorrosive Nanocomposite Coatings.” Prog. Org. Coat., 80 77–86 (2015)

  7. 7.

    Chang, K-C, Lu, H-I, Peng, C-W, Lai, M-C, Hsu, S-C, Hsu, M-H, Tsai, Y-K, Chang, C-H, Hung, W-I, Wei, Y, Yeh, J-M, “Nanocasting Technique to Prepare Lotus-Leaf-Like Superhydrophobic Electroactive Polyimide as Advanced Anticorrosive Coatings.” ACS Appl. Mater. Interfaces, 5 (4) 1460–1467 (2013)

  8. 8.

    Zhang, F, Zhang, C, Song, L, Zeng, R, Li, S, Cui, H, “Fabrication of the Superhydrophobic Surface on Magnesium Alloy and Its Corrosion Resistance.” J. Mater. Sci. Technol., 31 (11) 1139–1143 (2015)

  9. 9.

    Ramezanzadeh, B, Haeri, Z, Ramezanzadeh, M, “A Facile Route of Making Silica Nanoparticles-Covered Graphene Oxide Nanohybrids (SiO2-GO); Fabrication of SiO2-GO/Epoxy Composite Coating with Superior Barrier and Corrosion Protection Performance.” Chem. Eng. J., 303 511–528 (2016)

  10. 10.

    Conradi, M, Kocijan, A, Kek-Merl, D, Zorko, M, Verpoest, I, “Mechanical and Anticorrosion Properties of Nanosilica-Filled Epoxy-Resin Composite Coatings.” Appl. Surf. Sci., 292 432–437 (2014)

  11. 11.

    Wang, N, Fu, W, Zhang, J, Li, X, Fang, Q, “Corrosion Performance of Waterborne Epoxy Coatings Containing Polyethylenimine Treated Mesoporous-TiO2 Nanoparticles on Mild Steel.” Prog. Org. Coat., 89 114–122 (2015)

  12. 12.

    Cui, M, Ren, S, Chen, J, Liu, S, Zhang, G, Zhao, H, Wang, L, Xue, Q, “Anticorrosive Performance of Waterborne Epoxy Coatings Containing Water-Dispersible Hexagonal Boron Nitride (h-BN) Nanosheets.” Appl. Surf. Sci., 397 77–86 (2017)

  13. 13.

    Li, J, Gan, L, Liu, Y, Mateti, S, Lei, W, Chen, Y, Yang, J, “Boron Nitride Nanosheets Reinforced Waterborne Polyurethane Coatings for Improving Corrosion Resistance and Antifriction Properties.” Eur. Polym. J., 104 57–63 (2018)

  14. 14.

    Liu, S, Gu, L, Zhao, H, Chen, J, Yu, H, “Corrosion Resistance of Graphene-Reinforced Waterborne Epoxy Coatings.” J. Mater. Sci. Technol., 32 (5) 425–431 (2016)

  15. 15.

    Gu, L, Liu, S, Zhao, H, Yu, H, “Facile Preparation of Water-Dispersible Graphene Sheets Stabilized by Carboxylated Oligoanilines and Their Anticorrosion Coatings.” ACS Appl. Mater. Interfaces, 7 (32) 17641–17648 (2015)

  16. 16.

    Li, Y, Yang, Z, Qiu, H, Dai, Y, Zheng, Q, Li, J, Yang, J, “Self-Aligned Graphene as Anticorrosive Barrier in Waterborne Polyurethane Composite Coatings.” J. Mater. Chem. A, 2 (34) 14139–14145 (2014)

  17. 17.

    Li, J, Cui, J, Yang, J, Li, Y, Qiu, H, Yang, J, “Reinforcement of Graphene and Its Derivatives on the Anticorrosive Properties of Waterborne Polyurethane Coatings.” Compos. Sci. Technol., 129 30–37 (2016)

  18. 18.

    Li, H, Wen, J, Yu, R, Meng, J, Wang, C, Wang, C, Sun, S, “Facile Synthesis of a Nanocomposite Based on Graphene and ZnAl Layered Double Hydroxides as a Portable Shelf of a Luminescent Sensor for DNA Detection.” RSC Adv., 5 (13) 9341–9347 (2015)

  19. 19.

    Cui, M, Ren, S, Zhao, H, Xue, Q, Wang, L, “Polydopamine Coated Graphene Oxide for Anticorrosive Reinforcement of Water-Borne Epoxy Coating.” Chem. Eng. J., 335 255–266 (2018)

  20. 20.

    Chen, C, He, Y, Xiao, G, Zhong, F, Li, H, Wu, Y, Chen, J, “Synergistic Effect of Graphene Oxide@phosphate-Intercalated Hydrotalcite for Improved Anti-Corrosion and Self-Healable Protection of Waterborne Epoxy Coating in Salt Environments.” J. Mater. Chem. C, 7 (8) 2318–2326 (2019)

  21. 21.

    Jiang, F, Zhao, W, Wu, Y, Wu, Y, Liu, G, Dong, J, Zhou, K, “A Polyethyleneimine-Grafted Graphene Oxide Hybrid Nanomaterial: Synthesis and Anti-Corrosion Applications.” Appl. Surf. Sci., 479 963–973 (2019)

  22. 22.

    Alhumade, H, Yu, A, Elkamel, A, Simon, L, Abdala, A, “Enhanced Protective Properties and UV Stability of Epoxy/Graphene Nanocomposite Coating on Stainless Steel.” Express Polym. Lett., 10 (12) 1034–1046 (2016)

  23. 23.

    Awaja, F, Pigram, PJ, “Surface Molecular Characterisation of Different Epoxy Resin Composites Subjected to UV Accelerated Degradation Using XPS and ToF-SIMS.” Polym. Degrad. Stab., 94 (4) 651–658 (2009)

  24. 24.

    Ghasemi-Kahrizsangi, A, Neshati, J, Shariatpanahi, H, Akbarinezhad, E, “Improving the UV Degradation Resistance of Epoxy Coatings Using Modified Carbon Black Nanoparticles.” Prog. Org. Coat., 85 199–207 (2015)

  25. 25.

    Woo, RSC, Chen, Y, Zhu, H, Li, J, Kim, J-K, Leung, CKY, “Environmental Degradation of Epoxy-Organoclay Nanocomposites Due to UV Exposure. Part 1: Photo-Degradation.” Compos. Sci. Technol., 67 (15–16) 3448–3456 (2007)

  26. 26.

    Asmatulu, R, Mahmud, GA, Hille, C, Misak, HE, “Effects of UV Degradation on Surface Hydrophobicity, Crack, and Thickness of MWCNT-Based Nanocomposite Coatings.” Prog. Org. Coat., 72 (3) 553–561 (2011)

  27. 27.

    Li, J, Yang, Z, Qiu, H, Dai, Y, Zheng, Q, Zheng, G-P, Yang, J, “Microwave-Assisted Simultaneous Reduction and Titanate Treatment of Graphene Oxide.” J. Mater. Chem. A, 1 (37) 11451–11456 (2013)

  28. 28.

    Li, J, Lin, H, Yang, Z, Li, J, “A Method for the Catalytic Reduction of Graphene Oxide at Temperatures Below 150°C.” Carbon, 49 (9) 3024–3030 (2011)

  29. 29.

    Guan, L-Z, Wan, Y-J, Gong, L-X, Yan, D, Tang, L-C, Wu, L-B, Jiang, J-X, Lai, G-Q, “Toward Effective and Tunable Interphases in Graphene Oxide/Epoxy Composites by Grafting Different Chain Lengths of Polyetheramine Onto Graphene Oxide.” J. Mater. Chem. A, 2 (36) 15058–15069 (2014)

  30. 30.

    Tang, G, Jiang, Z-G, Li, X, Zhang, H-B, Hong, S, Yu, Z-Z, “Electrically Conductive Rubbery Epoxy/Diamine-Functionalized Graphene Nanocomposites with Improved Mechanical Properties.” Compos. Part B-Eng., 67 564–570 (2014)

  31. 31.

    Giray, D, Balkan, T, Dietzel, B, Sarac, A-S, “Electrochemical Impedance Study on Nanofibers of Poly(m-anthranilic acid)/Polyacrylonitrile Blends.” Eur. Polym. J., 49 2645–2653 (2013)

  32. 32.

    Chunsheng, L, Yiu-Wing, M, “Influence of Aspect Ratio on Barrier Properties of Polymer-Clay Nanocomposites.” Phys. Rev. Lett., 95 (8) 088303 (2005)

  33. 33.

    Li, J, Ma, PC, Chow, WS, Chi, KT, Kim, JK, “Correlations Between Percolation Threshold, Dispersion State, and Aspect Ratio of Carbon Nanotubes.” Adv. Funct. Mater., 17 (16) 3207–3215 (2010)

  34. 34.

    Rabek, JF, Polymer Photodegradation: Mechanisms and Experimental Methods. Springer, London (2012)

  35. 35.

    Paredes, JI, Villar-Rodil, S, Martínez-Alonso, A, Tascón, JMD, “Graphene Oxide Dispersions in Organic Solvents.” Langmuir, 24 (19) 10560–10564 (2008)

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Acknowledgements

The authors gratefully acknowledge the financial support from National Natural Science Foundation of China (U1560108, U1760119) and Science and Technology Commission of Shanghai Municipality (17511101603, 17XD1403000, 18ZR1426300, 15JC-1490700).

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Correspondence to Jing Li or Junhe Yang.

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Li, J., Shan, W., Cui, J. et al. Enhanced corrosion resistance and weathering resistance of waterborne epoxy coatings with polyetheramine-functionalized graphene oxide. J Coat Technol Res 17, 171–180 (2020) doi:10.1007/s11998-019-00252-z

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Keywords

  • Functionalized graphene oxide
  • Waterborne epoxy
  • Corrosion resistance
  • Weathering resistance
  • UV degradation