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Journal of Coatings Technology and Research

, Volume 16, Issue 1, pp 199–211 | Cite as

Water affinity guided tunable superhydrophobicity and optimized wettability of selected natural minerals

  • Hande Alptekin
  • Emre ArkanEmail author
  • Cebrail Özbek
  • Mustafa CanEmail author
  • Amir Farzaneh
  • Mücahit SütçüEmail author
  • Salih Okur
  • Andrew J. Cobley
Article
  • 123 Downloads

Abstract

We present a feasible methodology to prepare nonwetting surfaces from natural minerals. Various ranges of silanes were used for the surface grafting, and the best customization was achieved by monochlorosilane. Water affinity analysis of surface functionalized diatomaceous earth was the key aspect of loading tunable wettability on the particle surface. Covalent attachment was confirmed via X-ray photoelectron spectroscopy (XPS), while thermogravimetric analysis, nitrogen adsorption isotherms, and contact angle measurements were used for the evaluation of grafting density and other fundamental features of hydrophobic particles. Diatomaceous earth was chosen as a prototype to develop an efficient strategy for surface modification which can be apposite to another natural particle, the so-called talc, which represents dichotomic performance to water. The present study paves the way for a new approach that can be employed to any proper inherent texture for the production of superhydrophobic powders.

Keywords

Water affinity Tunable wettability Superhydrophobic minerals Surface grafting Diatomaceous earth 

Notes

Acknowledgment

We gratefully acknowledge the Izmir Katip Celebi University, Scientific Research Foundation for financial support of this study.

Authors’ contribution

The manuscript was written through contributions of all authors. All authors have given approval to the final version of the manuscript.

Supplementary material

11998_2018_115_MOESM1_ESM.docx (705 kb)
Supplementary material 1 (DOCX 705 kb)

Supplementary material 2 (MP4 438 kb)

11998_2018_115_MOESM3_ESM.mp4 (379 kb)
Supplementary material 3 (MP4 379 kb)
11998_2018_115_MOESM4_ESM.mp4 (52 kb)
Supplementary material 4 (MP4 51 kb)

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Copyright information

© American Coatings Association 2018

Authors and Affiliations

  1. 1.Department of Materials Science and Engineering, Faculty of Engineering and Architectureİzmir Katip Çelebi UniversityIzmirTurkey
  2. 2.Department of Engineering Sciences, Faculty of Engineering and Architectureİzmir Katip Çelebi UniversityIzmirTurkey
  3. 3.The Functional Materials Research Group, Centre for Manufacturing and Materials Engineering, Faculty of Engineering Environment and ComputingCoventry UniversityCoventryUK

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