Advertisement

One-pot hydrothermal synthesis of micaceous iron oxide pigment from jarosite waste

  • Xiang Li
  • Yabo Wang
  • Enjie Wei
  • Yi Xie
  • Yu Zeng
  • Panyu Li
  • Yongkui Zhang
Article
  • 19 Downloads

Abstract

In this study, jarosite waste was adopted as feed material for micaceous iron oxide (MIO) pigment preparation by a one-pot hydrothermal reaction. The formation of MIO started from jarosite decomposition into akaganeite (β-FeOOH) nanoparticles in alkali solution, which then recrystallized and transformed into MIO crystals under high temperature and OH concentration. The influences of NaOH concentration and reaction temperature on MIO formation were investigated. It was found that MIO formed when NaOH concentration and reaction temperature were equal to or higher than 2 M and 180°C, respectively. With an increase of NaOH concentration or reaction temperature, the particle size of MIO increased, leading to darkened color of the product. Moreover, quality evaluation indicated that the synthesized MIO fulfilled the required characteristics of micaceous iron oxide pigments for paints and the international standard of ISO 10601-2007 MIO-A1.

Keywords

Jarosite Micaceous iron oxide Hematite Akaganeite Hydrothermal reaction Recycling 

Notes

Compliance with ethical standards

Conflict of interest

All authors declare that they have no conflict of interest.

Supplementary material

11998_2018_98_MOESM1_ESM.doc (29.6 mb)
Supplementary material 1 (DOC 30321 kb)

References

  1. 1.
    Dutrizac, JE, “Factors Affecting the Precipitation of Potassium Jarosite in Sulfate and Chloride Media.” Metall. Mater. Trans. B, 39 771 (2008)CrossRefGoogle Scholar
  2. 2.
    Ju, SH, Zhang, YF, Zhang, Y, Xue, PY, Wang, YH, “Clean Hydrometallurgical Route to Recover Zinc, Silver, Lead, Copper, Cadmium and Iron from Hazardous Jarosite Residues Produced During Zinc Hydrometallurgy.” J. Hazard. Mater., 192 554 (2011)CrossRefGoogle Scholar
  3. 3.
    Dutrizac, JE, Hydrometallurgical Process Fundamentals. Plenum Press, New York (1984)Google Scholar
  4. 4.
    Asokan, P, Saxena, M, Asolekar, SR, “Hazardous Jarosite Use in Developing Non-hazardous Product for Engineering Application.” J. Hazard. Mater., 137 1589 (2006)CrossRefGoogle Scholar
  5. 5.
    Pelino, M, “Recycling of Zinc-Hydrometallurgy Wastes in Glass and Glass Ceramic Materials.” Waste Manag., 20 561 (2000)CrossRefGoogle Scholar
  6. 6.
    Asokan, P, Saxena, M, Asolekar, SR, “Recycling Hazardous Jarosite Waste Using Coal Combustion Residues.” Mater. Charact., 61 1342 (2010)CrossRefGoogle Scholar
  7. 7.
    Katsioti, M, Tsakiridis, PE, Agatzini, SL, Oustadakis, P, “Examination of the Jarosite-Alunite Precipitate Addition in the Raw Meal for the Production of Sulfoaluminate Cement Clinker.” J. Hazard. Mater., 131 187 (2006)CrossRefGoogle Scholar
  8. 8.
    Pappu, A, Saxena, M, Asolekar, SR, “Jarosite Characteristics and Its Utilisation Potentials.” Sci. Total. Environ., 359 232 (2006)CrossRefGoogle Scholar
  9. 9.
    Spratt, H, Rintoul, L, Avdeev, M, Martens, W, “The Thermal Decomposition of Hydronium Jarosite and Ammoniojarosite.” J. Therm. Anal. Calorim., 115 101 (2014)CrossRefGoogle Scholar
  10. 10.
    Mustafa, MK, Mandić, V, Ćurković, L, Šipušić, J, “Investigation of Thermal Decomposition of Jarosite Tailing Waste.” J. Therm. Anal. Calorim., 123 421 (2016)CrossRefGoogle Scholar
  11. 11.
    Ristić, M, Musić, S, Orehovec, Z, “Thermal Decomposition of Synthetic Ammonium Jarosite.” J. Mol. Struct., 744 295 (2005)CrossRefGoogle Scholar
  12. 12.
    Han, HS, Sun, W, Hu, YH, Jia, BL, Tang, HH, “Anglesite and Silver Recovery from Jarosite Residues Through Roasting and Sulfidization-Flotation in Zinc Hydrometallurgy.” J. Hazard. Mater., 278 49 (2014)CrossRefGoogle Scholar
  13. 13.
    Dutrizac, JE, Productivity and Technology in the Metallurgical Industries. TMS-AIME, Warrendale (1989)Google Scholar
  14. 14.
    Wang, JX, Yuan, RH, Xie, LY, Tian, QF, Zhu, SY, Hu, YH, Liu, P, Shi, XH, Wang, DH, “Photochemical Treatment of As(III) with α-Fe2O3 Synthesized from Jarosite Waste.” RSC Adv., 2 1112 (2012)CrossRefGoogle Scholar
  15. 15.
    Vu, H, Jandová, J, Hron, T, “Recovery of Pigment-Quality Magnetite from Jarosite Precipitate.” Hydrometallurgy, 101 1 (2010)CrossRefGoogle Scholar
  16. 16.
    Li, ZG, Yuan, W, “Industrial Waste Utilization Method: Producing Poly-Ferric Sulfate(PFS) from Sodium-Jarosite Residue.” Fron. Env. Sci. Eng., 9 731 (2015)CrossRefGoogle Scholar
  17. 17.
    Mayer, F, Bidwe, AR, Schopf, A, Taheri, K, Zieba, M, Scheffknecht, G, “Comparison of a New Micaceous Iron Oxide and Ilmenite as Oxygen Carrier for Chemical Looping Combustion with Respect to Syngas Conversion.” Appl. Energ., 113 1863 (2014)CrossRefGoogle Scholar
  18. 18.
    Okada, S, Takagi, K, Ozaki, K, “Synthesis of Submicron Plate-Like Hematite Without Organic Additives and Reduction to Plate-Like α-Fe.” Mater. Lett., 140 135 (2014)CrossRefGoogle Scholar
  19. 19.
    Carter, E, “Formulation and Manufacture of Micaceous Iron Oxide Paints.” Pigm. Resin. Technol., 13 8 (1984)CrossRefGoogle Scholar
  20. 20.
    Uchida, S, Sato, T, Okuwaki, A, “Preparation of Micaceous Iron Oxide by the Oxidation of Iron with Pressurized Oxygen in Concentrated Sodium Hydroxide Solution at Elevated Temperatures.” J. Mater. Sci., 27 1332 (1992)CrossRefGoogle Scholar
  21. 21.
    Zheng, YJ, Liu, ZC, “Preparation of Monodispersed Micaceous Iron Oxide Pigment from Pyrite Cinders.” Powder Technol., 207 335 (2011)CrossRefGoogle Scholar
  22. 22.
    Giúdice, CA, Benítez, JC, “Optimising the Corrosion Protective Abilities of Lamellar Micaceous Iron Oxide Containing Primers.” Anti-Corros. Methods Mater., 47 226 (2000)CrossRefGoogle Scholar
  23. 23.
    Gou, X, Wang, G, Park, J, Liu, H, Yang, J, “Monodisperse Hematite Porous Nanospheres: Synthesis, Characterization, and Applications for Gas Sensors.” Nanotechnology, 19 1 (2008)CrossRefGoogle Scholar
  24. 24.
    Cuong, ND, Khieu, DQ, Hoa, TT, Quang, DT, Viet, PH, Lam, TD, Hoa, ND, Hieu, NV, “Facile Synthesis of α-Fe2O3 Nanoparticles for High-Performance CO Gas Sensor.” Mater. Res. Bull., 68 302 (2015)CrossRefGoogle Scholar
  25. 25.
    Zhu, J, Ng, KYS, Deng, D, “Micro Single Crystals of Hematite with Nearly 100% Exposed 104 Facets: Preferred Etching and Lithium Storage.” Cryst. Growth. Des., 14 2811 (2014)CrossRefGoogle Scholar
  26. 26.
    Zhu, J, Deng, D, “Single-Crystalline α-Fe2O3 Void@frame Microframes for Rechargeable Batteries.” J. Mater. Chem. A, 4 4425 (2016)CrossRefGoogle Scholar
  27. 27.
    Smith, AML, Edwards, KAH, Dubbin, WE, Wright, K, “Dissolution of Jarosite [KFe3(SO4)2(OH)6] at pH 2 and 8: Insights from Batch Experiments and Computational Modelling.” Geochim. Cosmochim. Acta, 70 608 (2006)CrossRefGoogle Scholar
  28. 28.
    Li, X, Wang, CK, Yu, Z, Li, PY, Xie, TH, Zhang, YK, “Bacteria-Assisted Preparation of Nano α-Fe2O3 Red Pigment Powders from Waste Ferrous Sulfate.” J. Hazard. Mater., 317 563 (2016)CrossRefGoogle Scholar
  29. 29.
    Sugimoto, T, Waki, S, Itoh, H, Muramatsu, A, “Preparation of Monodispersed Platelet-Type Hematite from a Highly Condensed β-FeOOH Suspension.” Colloids Surf. A, 109 155 (1996)CrossRefGoogle Scholar

Copyright information

© American Coatings Association 2018

Authors and Affiliations

  • Xiang Li
    • 1
  • Yabo Wang
    • 1
  • Enjie Wei
    • 1
  • Yi Xie
    • 1
  • Yu Zeng
    • 1
  • Panyu Li
    • 1
  • Yongkui Zhang
    • 1
  1. 1.Department of Pharmaceutical and Biological Engineering, School of Chemical EngineeringSichuan UniversityChengduPeople’s Republic of China

Personalised recommendations