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Journal of Coatings Technology and Research

, Volume 14, Issue 6, pp 1369–1380 | Cite as

A facile and low-cost preparation of durable amphiphobic coatings with fluoride–silica@poly(methacrylic acid) hybrid nanocomposites

  • Zheng-Bai Zhao
  • Da-Ming Zhang
  • Li Tai
  • Peng-Fei Jiang
  • Yong JiangEmail author
Article

Abstract

Poor robustness, high cost and complicated preparation are the main barriers to the large-scale industrial application of amphiphobic coatings. A facile and low-cost method to fabricate durable amphiphobic coatings is reported in this work. The coatings were composed of top and bottom paints. The top paint was prepared by the F–Si@PMAA hybrid nanocomposites dispersion. The hybrid nanocomposites with dual structure were prepared via the co-condensation reaction of tetraethoxysilane (TEOS) and 1H,1H,2H,2H-Perfluorodecyl triethoxysilane (HDFTES) on the surface of the presynthesized PMAA nanoparticles in ethanol dispersion. The bottom one was a type of inexpensive car refinishing paint. The resulting coatings could be sprayed onto different substrates. All the coated substrates exhibited good amphiphobicity with superhydrophobicity with the water contact angle greater than 150°, water roll-off angle less than 4°, and high oleophobicity with the oil contact angle greater than 130°. Moreover, all of the prepared coatings exhibited great robustness after water jetting, sand abrasion, and knife scratching. This method can be an effective strategy for fabricating amphiphobic surfaces for practical industrial applications.

Keywords

Hybrid nanocomposite Durable Low-cost Amphiphobic Superhydrophobicity High oleophobicity 

Notes

Acknowledgments

This work was supported by the National Natural Science Foundation of China (NSFC) with Grant Number 21174029, the Industry Academia Cooperation Innovation Fund of Jiangsu Province with Grant Number BY2014127-07, and the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) with Grant Number 1107047002.

Conflict of interest

The authors declare no competing financial interest.

Supplementary material

11998_2017_9940_MOESM1_ESM.docx (30.4 mb)
Supplementary material 1 (DOCX 31118 kb)

Supplementary material 2 (MP4 3207 kb)

Supplementary material 3 (3gp 8057 kb)

Supplementary material 4 (MP4 10317 kb)

Supplementary material 5 (MP4 22008 kb)

References

  1. 1.
    Li, J, Xu, CC, Zhang, Y, Wang, RF, Zha, F, She, HD, “Robust Superhydrophobic Attapulgite Coated Polyurethane Sponge for Efficient Immiscible Oil/Water Mixture and Emulsion Separation.” J. Mater. Chem. A, 4 (40) 15546–15553 (2016)CrossRefGoogle Scholar
  2. 2.
    Li, J, Yan, L, Zhao, YZ, Zha, F, Wang, QT, Lei, ZQ, “One-Step Fabrication of Robust Fabrics with Both-Faced Superhydrophobicity for the Separation and Capture of Oil from Water.” Phys. Chem. Chem. Phys., 17 (9) 6451–6457 (2015)CrossRefGoogle Scholar
  3. 3.
    Li, J, Jing, ZJ, Zha, F, Yang, YX, Wang, QT, Lei, ZQ, “Facile Spray-Coating Process for the Fabrication of Tunable Adhesive Superhydrophobic Surfaces with Heterogeneous Chemical Compositions Used for Selective Transportation of Microdroplets with Different Volumes.” ACS Appl. Mater. Interfaces, 6 (11) 8868–8877 (2014)CrossRefGoogle Scholar
  4. 4.
    Li, J, Yan, L, Ouyang, QL, Zha, F, Jing, ZJ, Li, X, Lei, ZQ, “Facile Fabrication of Translucent Superamphiphobic Coating on Paper to Prevent Liquid Pollution.” Chem. Eng. J., 246 238–243 (2014)CrossRefGoogle Scholar
  5. 5.
    Ellinas, K, Tsougeni, K, Petrou, PS, Boulousis, G, Tsoukleris, D, Pavlatou, E, Tserepi, A, Kakabakos, SE, Gogolides, E, “Three-Dimensional Plasma Micro-Nanotextured Cyclo-Olefin-Polymer Surfaces for Biomolecule Immobilization and Environmentally Stable Superhydrophobic and Superoleophobic Behavior.” Chem. Eng. J., 300 394–403 (2016)CrossRefGoogle Scholar
  6. 6.
    Gurav, AB, Xu, QF, Latthe, SS, Vhatkar, RS, Liu, SH, Yoon, H, Yoon, SS, “Superhydrophobic Coatings Prepared from Methyl-Modified Silica Particles Using Simple Dip-Coating Method.” Ceram. Int., 41 (2) 3017–3023 (2015)CrossRefGoogle Scholar
  7. 7.
    Arbatan, T, Fang, XY, Shen, W, “Superhydrophobic and Oleophilic Calcium Carbonate Powder as a Selective Oil Sorbent with Potential Use in Oil Spill Clean-ups.” Chem. Eng. J., 166 (2) 787–791 (2011)CrossRefGoogle Scholar
  8. 8.
    Song, XY, Zhai, J, Wang, YL, Jiang, L, “Fabrication of Superhydrophobic Surfaces by Self-assembly and their Water-Adhesion Properties.” J. Phys. Chem. B, 109 (9) 4048–4052 (2005)CrossRefGoogle Scholar
  9. 9.
    Sengupta, A, Malik, SN, Bahadur, D, “Developing Superhydrophobic and Oleophobic Nanostructure by a Facile Chemical Transformation of Zirconium Hydroxide Surface.” Appl. Surf. Sci., 363 346–355 (2016)CrossRefGoogle Scholar
  10. 10.
    Siriviriyanun, A, Imae, T, “Anti-Fingerprint Properties of Non-fluorinated Organosiloxane Self-assembled Monolayer-Coated Glass Surfaces.” Chem. Eng. J., 246 254–259 (2014)CrossRefGoogle Scholar
  11. 11.
    Zhang, XX, Honkanen, M, Pore, V, Levanen, E, Mantyla, T, “Effect of Heat Treating Gel Films on the Formation of Superhydrophobic Boehmite Flaky Structures on Austenitic Stainless Steel.” Ceram. Int., 35 (4) 1559–1564 (2009)CrossRefGoogle Scholar
  12. 12.
    Li, H, Yu, SR, Han, XX, Liu, EY, Zhao, Y, “Fabrication of Superhydrophobic and Oleophobic Surface on Zinc Substrate by a Simple Method.” Colloids Surf. A Physicochem. Eng. Asp., 469 271–278 (2015)CrossRefGoogle Scholar
  13. 13.
    Li, H, Yu, SR, Han, XX, Zhao, Y, “A Stable Hierarchical Superhydrophobic Coating on Pipeline Steel Surface with Self-cleaning, Anticorrosion, and Anti-scaling Properties.” Colloids Surf. A Physicochem. Eng. Asp., 503 43–52 (2016)CrossRefGoogle Scholar
  14. 14.
    Xu, ZL, Miyazaki, K, Hori, T, “Fabrication of Polydopamine-Coated Superhydrophobic Fabrics for Oil/Water Separation and Self-cleaning.” Appl. Surf. Sci., 370 243–251 (2016)CrossRefGoogle Scholar
  15. 15.
    Brassard, JD, Sarkar, DK, Perron, J, Audibert-Hayet, A, Melot, D, “Nano-micro Structured Superhydrophobic Zinc Coating on Steel for Prevention of Corrosion and Ice Adhesion.” J. Colloid Interface Sci., 447 240–247 (2015)CrossRefGoogle Scholar
  16. 16.
    Yang, N, Li, JC, Bai, NN, Xu, L, Li, Q, “One Step Phase Separation Process to Fabricate Superhydrophobic PVC Films and Its Corrosion Prevention for AZ91D Magnesium Alloy.” Mater. Sci. Eng. B Adv. Funct. Solid-State Mater., 209 1–9 (2016)CrossRefGoogle Scholar
  17. 17.
    Zhu, XT, Zhang, ZZ, Xu, XH, Men, XH, Yang, J, Zhou, XY, Xue, QJ, “Rapid Control of Switchable Oil Wettability and Adhesion on the Copper Substrate.” Langmuir, 27 (23) 14508–14513 (2011)CrossRefGoogle Scholar
  18. 18.
    Antonini, C, Innocenti, M, Horn, T, Marengo, M, Amirfazli, A, “Understanding the Effect of Superhydrophobic Coatings on Energy Reduction in Anti-icing Systems.” Cold Reg. Sci. Technol., 67 (1–2) 58–67 (2011)CrossRefGoogle Scholar
  19. 19.
    Bixler, GD, Theiss, A, Bhushan, B, Lee, SC, “Anti-fouling Properties of Microstructured Surfaces Bio-inspired by Rice Leaves and Butterfly Wings.” J. Colloid Interface Sci., 419 114–133 (2014)CrossRefGoogle Scholar
  20. 20.
    Liu, ZJ, Wang, HY, Wang, EQ, Zhang, XG, Yuan, RX, Zhu, YJ, “Superhydrophobic Poly(vinylidene fluoride) Membranes with Controllable Structure and Tunable Wettability Prepared by One-step Electrospinning.” Polymer, 82 105–113 (2016)CrossRefGoogle Scholar
  21. 21.
    Chen, Y, Zhang, YB, Shi, L, Li, J, Xin, Y, Yang, TT, Guo, ZG, “Transparent Superhydrophobic/Superhydrophilic Coatings for Self-cleaning and Anti-fogging.” Appl. Phys. Lett., 101 (3) 4 (2012)Google Scholar
  22. 22.
    Shang, QQ, Zhou, YH, “Fabrication of Transparent Superhydrophobic Porous Silica Coating for Self-cleaning and Anti-fogging.” Ceram. Int., 42 (7) 8706–8712 (2016)CrossRefGoogle Scholar
  23. 23.
    Shen, LY, Wang, BL, Wang, JL, Fu, JH, Picart, C, Ji, J, “Asymmetric Free-standing Film with Multifunctional Anti-bacterial and Self-cleaning Properties.” ACS Appl. Mater. Interfaces, 4 (9) 4476–4483 (2012)CrossRefGoogle Scholar
  24. 24.
    Wang, ZL, Ou, JF, Wang, Y, Xue, MS, Wang, FJ, Pan, B, Li, CQ, Li, W, “Anti-bacterial Superhydrophobic Silver on Diverse Substrates Based on the Mussel-Inspired Polydopamine.” Surf. Coat. Technol., 280 378–383 (2015)CrossRefGoogle Scholar
  25. 25.
    Coclite, AM, Shi, YJ, Gleason, KK, “Grafted Crystalline Poly-Perfluoroacrylate Structures for Superhydrophobic and Oleophobic Functional Coatings.” Adv. Mater., 24 (33) 4534–4539 (2012)CrossRefGoogle Scholar
  26. 26.
    Ragesh, P, Ganesh, VA, Naira, SV, Nair, AS, “A Review on ‘Self-cleaning and Multifunctional Materials’.” J. Mater. Chem. A, 2 (36) 14773–14797 (2014)CrossRefGoogle Scholar
  27. 27.
    Mathkar, A, Narayanan, TN, Alemany, LB, Cox, P, Nguyen, P, Gao, GH, Chang, P, Romero-Aburto, R, Mani, SA, Ajayan, PM, “Synthesis of Fluorinated Graphene Oxide and Its Amphiphobic Properties.” Part. Part. Syst. Charact., 30 (3) 266–272 (2013)CrossRefGoogle Scholar
  28. 28.
    Raimondo, M, Blosi, M, Caldarelli, A, Guarini, G, Veronesi, F, “Wetting Behavior and Remarkable Durability of Amphiphobic Aluminum Alloys Surfaces in a Wide Range of Environmental Conditions.” Chem. Eng. J., 258 101–109 (2014)CrossRefGoogle Scholar
  29. 29.
    Xiong, DA, Liu, GJ, Zhang, JG, Duncan, S, “Bifunctional Core-Shell-Corona Particles for Amphiphobic Coatings.” Chem. Mater., 23 (11) 2810–2820 (2011)CrossRefGoogle Scholar
  30. 30.
    Deng, X, Mammen, L, Butt, HJ, Vollmer, D, “Candle Soot as a Template for a Transparent Robust Superamphiphobic Coating.” Science, 335 (6064) 67–70 (2012)CrossRefGoogle Scholar
  31. 31.
    Luo, ZK, Chen, PQ, Wang, F, Pang, Y, Xu, YH, Hong, YR, Zhao, X, “Preparation of Amphiphobic Coating by Combining Fluoroalkyl Silane with Nano-SiO2.” Phys. Status Solidi A Appl. Mater., 212 (2) 259–264 (2015)CrossRefGoogle Scholar
  32. 32.
    Lu, XM, Peng, YL, Ge, L, Lin, RJ, Zhu, ZH, Liu, SM, “Amphiphobic PVDF Composite Membranes for Anti-fouling Direct Contact Membrane Distillation.” J. Membr. Sci., 505 61–69 (2016)CrossRefGoogle Scholar
  33. 33.
    Farsinezhad, S, Waghmare, PR, Wiltshire, BD, Sharma, H, Amiri, S, Mitra, SK, Shankar, K, “Amphiphobic Surfaces from Functionalized TiO2 Nanotube Arrays.” RSC Adv., 4 (63) 33587–33598 (2014)CrossRefGoogle Scholar
  34. 34.
    Bai, F, Yang, XL, Li, R, Huang, B, Huang, WQ, “Monodisperse Hydrophilic Polymer Microspheres Having Carboxylic Acid Groups Prepared by Distillation Precipitation Polymerization.” Polymer, 47 (16) 5775–5784 (2006)CrossRefGoogle Scholar
  35. 35.
    Zhao, ZB, Zhang, DM, Meng, YF, Tai, L, Jiang, Y, “One-pot Fabrication of Fluoride–silica@silica Raspberry-like Nanoparticles for Superhydrophobic Coating.” Ceram. Int., 42 (13) 14601–14608 (2016)CrossRefGoogle Scholar
  36. 36.
    Lu, Y, Sathasivam, S, Song, JL, Crick, CR, Carmalt, CJ, Parkin, IP, “Robust Self-cleaning Surfaces that Function When Exposed to Either Air or Oil.” Science, 347 (6226) 1132–1135 (2015)CrossRefGoogle Scholar
  37. 37.
    Chen, BY, Qiu, JH, Sakai, E, Kanazawa, N, Liang, RL, Feng, HX, “Robust and Superhydrophobic Surface Modification by a “Paint Plus Adhesive” Method: Applications in Self-cleaning After Oil Contamination and Oil Water Separation.” ACS Appl. Mater. Interfaces, 8 (27) 17659–17667 (2016)CrossRefGoogle Scholar
  38. 38.
    Jung, YC, Bhushan, B, “Mechanically Durable Carbon Nanotube-Composite Hierarchical Structures with Superhydrophobicity, Self-cleaning, and Low-Drag.” ACS Nano, 3 (12) 4155–4163 (2009)CrossRefGoogle Scholar
  39. 39.
    Ge, DT, Yang, LL, Zhang, YF, Rahmawan, Y, Yang, S, “Transparent and Superamphiphobic Surfaces from One-Step Spray Coating of Stringed Silica Nanoparticle/Sol Solutions.” Part. Part. Syst. Charact., 31 (7) 763–770 (2014)CrossRefGoogle Scholar
  40. 40.
    Barthlott, W, Neinhuis, C, “Purity of the Sacred Lotus, or Escape from Contamination in Biological Surfaces.” Planta, 202 (1) 1–8 (1997)CrossRefGoogle Scholar
  41. 41.
    Koch, K, Barthlott, W, “Superhydrophobic and Superhydrophilic Plant Surfaces: An Inspiration for Biomimetic Materials.” Philos. Trans. R. Soc. A Math. Phys. Eng. Sci., 367 (1893) 1487–1509 (2009)CrossRefGoogle Scholar
  42. 42.
    Latthe, SS, Terashima, C, Nakata, K, Fujishima, A, “Superhydrophobic Surfaces Developed by Mimicking Hierarchical Surface Morphology of Lotus Leaf.” Molecules, 19 (4) 4256–4283 (2014)CrossRefGoogle Scholar

Copyright information

© American Coatings Association 2017

Authors and Affiliations

  • Zheng-Bai Zhao
    • 1
  • Da-Ming Zhang
    • 1
  • Li Tai
    • 1
  • Peng-Fei Jiang
    • 1
  • Yong Jiang
    • 1
    Email author
  1. 1.School of Chemistry and Chemical EngineeringSoutheast UniversityNanjingPeople’s Republic of China

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