Journal of Coatings Technology and Research

, Volume 14, Issue 6, pp 1369–1380 | Cite as

A facile and low-cost preparation of durable amphiphobic coatings with fluoride–silica@poly(methacrylic acid) hybrid nanocomposites

  • Zheng-Bai Zhao
  • Da-Ming Zhang
  • Li Tai
  • Peng-Fei Jiang
  • Yong JiangEmail author


Poor robustness, high cost and complicated preparation are the main barriers to the large-scale industrial application of amphiphobic coatings. A facile and low-cost method to fabricate durable amphiphobic coatings is reported in this work. The coatings were composed of top and bottom paints. The top paint was prepared by the F–Si@PMAA hybrid nanocomposites dispersion. The hybrid nanocomposites with dual structure were prepared via the co-condensation reaction of tetraethoxysilane (TEOS) and 1H,1H,2H,2H-Perfluorodecyl triethoxysilane (HDFTES) on the surface of the presynthesized PMAA nanoparticles in ethanol dispersion. The bottom one was a type of inexpensive car refinishing paint. The resulting coatings could be sprayed onto different substrates. All the coated substrates exhibited good amphiphobicity with superhydrophobicity with the water contact angle greater than 150°, water roll-off angle less than 4°, and high oleophobicity with the oil contact angle greater than 130°. Moreover, all of the prepared coatings exhibited great robustness after water jetting, sand abrasion, and knife scratching. This method can be an effective strategy for fabricating amphiphobic surfaces for practical industrial applications.


Hybrid nanocomposite Durable Low-cost Amphiphobic Superhydrophobicity High oleophobicity 



This work was supported by the National Natural Science Foundation of China (NSFC) with Grant Number 21174029, the Industry Academia Cooperation Innovation Fund of Jiangsu Province with Grant Number BY2014127-07, and the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) with Grant Number 1107047002.

Conflict of interest

The authors declare no competing financial interest.

Supplementary material

11998_2017_9940_MOESM1_ESM.docx (30.4 mb)
Supplementary material 1 (DOCX 31118 kb)

Supplementary material 2 (MP4 3207 kb)

Supplementary material 3 (3gp 8057 kb)

Supplementary material 4 (MP4 10317 kb)

Supplementary material 5 (MP4 22008 kb)


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Copyright information

© American Coatings Association 2017

Authors and Affiliations

  • Zheng-Bai Zhao
    • 1
  • Da-Ming Zhang
    • 1
  • Li Tai
    • 1
  • Peng-Fei Jiang
    • 1
  • Yong Jiang
    • 1
    Email author
  1. 1.School of Chemistry and Chemical EngineeringSoutheast UniversityNanjingPeople’s Republic of China

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