Inorganic precursor peroxides for antifouling coatings
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Modern antifouling coatings are generally based on cuprous oxide (Cu2O) and organic biocides as active ingredients. Cu2O is prone to bioaccumulation, and should therefore be replaced by more environmentally benign compounds when technically possible. However, cuprous oxide does not only provide antifouling properties, it is also a vital ingredient for the antifouling coating to obtain its polishing and leaching mechanism. In this paper, peroxides of strontium, calcium, magnesium, and zinc are tested as pigments in antifouling coatings. The peroxides react with seawater to create hydrogen peroxide and highly seawater-soluble ions of the metal. The goals have been to establish the antifouling potency of an antifouling coating that releases hydrogen peroxide as biocide, and to investigate the potential use of peroxides as water-soluble polishing and leaching pigments. The investigations have shown that it is possible to identify particulates that, when applied as pigments in antifouling coatings, will provide polishing and leaching rates comparable to those of Cu2O-based coatings. Furthermore, the combination of polishing and hydrogen peroxide leaching by a coating based on zinc peroxide in a suitable binder matrix provides antifouling properties exceeding those of a similar coating based entirely on zinc oxide.
KeywordsPigment Biofouling Hydrogen peroxide Polishing
This work is funded by the Danish Ministry of Science. It is part of the CHEC Research Center at the Department of Chemical and Biochemical Engineering, funded among others by the Technical University of Denmark, the Danish Technical Research Council, the European Union, the Nordic Energy Research, Dong Energy A/S, Vattenfall A.B., F L Smidth A/S, J.C. Hempel Foundation, and Public Service Obligation funds from Energinet.dk and the Danish Energy Research program. The authors wish to thank the Institute of Marine Research (IMR), Tjärnö, at the University of Gothenburg for supplying barnacle cyprids. Also thanks to chemical engineer, Ajish John, for his good work and thorough reporting.
- 3.Minoru, K, Shunkai, M, Katsumi, K, “Antifouling Composition.” Japanese Patent 01-213372, 1988Google Scholar
- 4.Minuro, K, Shunkai, M, Katsumi, K, “Coatings Containing Non-Metallic Antifouling Agent Releasable Compounds.” Japanese Patent Application 64-61404, 1989Google Scholar
- 8.Morris, RS, Walsh, IV, “Zinc Oxide Photoactive Antifoulant Material.” US Patent 5,916,947, 1996Google Scholar
- 9.Steiner, N., Eul, W., “Peroxides and peroxide compounds. Inorganic peroxides,” Kirk-Othmer Encyclopedia of chemical technology, 18, 1–35 (2001).Google Scholar
- 10.Ikuta, S, Ichikawa, S, Wakao, Y, Nishimura, K, Yasunaga, T, “Inorganic Peroxides for Heat Exchanger Biofouling Control.” Jt. ASME/IEEE Power Generation Conference, Philadelphia, Pennsylvania, September 1988Google Scholar
- 15.Mathyarasu, J., Marutiamutiu, S., Muralidharan, S., Meenakshisundaram, R., Rengaswamy, N. S., “Evaluation of peroxide based biocides for inhibition and biocidal efficiencies,” Bulletin of Electrochemistry, 13, 289–293 (1997).Google Scholar
- 17.Wicks, ZW, “Coatings.” Kirk-Othmer Encyclopedia Chem. Technol., 7 77–150 (2002)Google Scholar
- 19.Rittschof, D, Clare, AS, Gerhart, DJ, Mary, SA, Bonaventura, J, “Barnacle In Vitro Assays for Biologically Active Substances: Toxicity and Settlement Inhibition Assays Using Mass Cultured Balanus Amphitrite Darwin.” Biofouling, 6(2), 115–122 (1992)Google Scholar
- 20.Kiil, S, Weinell, CE, Yebra, DM, Dam-Johansen, K, “Marine Biofouling Protection: Design of Controlled Release Antifouling Paints.” In: Ng, KM, Gani, R, Dam-Johansen, K (eds.) Chemical Product Design; Towards a Perspective Through Case Studies, 23IDBN-13: 978-0-444-52217-7, Part II (7), Elsevier (2006)Google Scholar
- 21.Eul, W, Moeller, A, Steiner, N, “Hydrogen Peroxide.” Kirk-Othmer Encyclopedia of Chem. Technol., 1–53 (2001)Google Scholar