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Palladium and tantalum aluminide coatings for high-temperature oxidation resistance of titanium alloy IMI 834

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Abstract

The present article explains the efforts made in developing new protective coatings based on palladium, tantalum, and aluminum with considerably improved oxidation resistance for effective protection of titanium alloy IMI 834. Systematic characterization was carried out on as-prepared as well as oxidized coatings and these results are presented. The performance of new coatings was evaluated by generating weight-gain data as a function of time followed by detailed characterization in order to confirm the ability of the coatings to prevent oxidation and alpha-case formation. The results showed that tantalum aluminide and simple aluminide coatings exhibit improved oxidation resistance when compared to palladium aluminide. Finally, the advantages of developed new coatings and the necessity of their use in modern gas turbine engines that allow the alloy to be used safely at high temperatures, which in turn would enhance the efficiency of gas-turbine engine-compressor sections, will be stressed.

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References

  1. Williams, JC, “The Development of Advanced Gas Turbines: The Technical and Economic Development.” In: Cputsouradis, D et al (eds.) Materials for Advanced Power Engineering, p. 1831. Kluwer Academic, The Netherlands (1994)

  2. I Gurrappa, AK Gogia, Oxidation Behavior of Titanium Alloy IMI 834 at Elevated Temperatures, Proceedings of the 5th National Convention on Corrosion, New Delhi, India, NACE International India Section, November (1999), pp. 210–219

    Google Scholar 

  3. I Gurrappa (2002) On the Degradation Mechanism of Titanium Aalloy IMI 834 in Oxidizing Atmospheres at Elevated Temperatures, Corr. Prev. & Control, 49, 79

    CAS  Google Scholar 

  4. I Gurrappa (2003) Mechanism of Degradation of Ttitanium Aalloy IMI 834 and Its Protection Under Hot Corrosion Conditions, Oxid. Met., 59, 321

    Article  CAS  Google Scholar 

  5. Z Yao, Z Jiang, F Wang, G Hao (2007) Oxidation Behavior of Ceramic Coatings on Ti-6Al-4V by Micro-Plasma Oxidation, J. Mater. Process. Tech., 190, 117

    Article  CAS  Google Scholar 

  6. H Zhou, F Li, B He, J Wang, B Sun (2007) Wang and B. Sun, Air Plasma Sprayed Thermal Barrier Coatings on Titanium Alloy Substrates, Surf. Coat. Tech., 202, 7360

    Article  Google Scholar 

  7. Riviere, JP, Pichon, L, Drouet, M, Poquillon, D, Galdikas, A, “Silicon Based Coatings Deposited by Dynamic Ion Mixing for Oxidation Protection of a Ti6242 Aalloy.” Surf. Coat. Tech., 201 8343 (2007)

  8. R Siab, G Bonnet, JM Brossard, J Balmain, JF Dinhut (2007) Effect of An Electrodeposited Yttrium Containing Thin Film on the High Temperature Oxidation Behavior of TA6V alloy, Appl. Surf. Sci., 253, 3425

    Article  ADS  CAS  Google Scholar 

  9. I Gurrappa, D Manova, JW Gerlach, S Mandl, B Rauchenbach (2006) Effect of an Electrodeposited Yttrium Containing Thin Film on the High Temperature Oxidation Behavior of TA6V Alloy, J. Alloys. Comp., 426, 375

    Article  CAS  Google Scholar 

  10. M Froehlich, R Braun, C Leyens (2006) Oxidation Resistant Coatings in Combination with Thermal Barrier Coatings on γ–TiAl Alloys for High Temperature Applications, Surf. Coat. Tech., 201, 3911

    Article  CAS  Google Scholar 

  11. H P Xiong, W Mao, WL Ma, YH Xie, Y Feng, H Yuan, XH Li (2006) Liquid-Phase Aluminizing and Siliconizing at the Surface of a Ti60 Alloy and Improvement in Oxidation Resistance, Mater. Sci.Eng., A433, 108

    CAS  Google Scholar 

  12. H Li, C Costil, V Barnier, R Oltra, O Heintz, C Coddet (2006) Surface Modifications Induced by Nanosecond Pulsed Nd:YAG Laser Irradiation of Metallic Substrates, Surf. Coat. Tech., 201, 1383

    Article  CAS  Google Scholar 

  13. Fox-Rabinovich GS, Wilkinson DS, Veldhuis SC, Dosboneva GK, Weatherly GC (2006) Oxidation Resistant Ti–Al–Cr Alloy for Protective Coating Applications, Intermetallics, 14, 189. doi:10.1016/j.intermet.2005.05.011

    Article  CAS  Google Scholar 

  14. I Gurrappa, D Manova, JW Gerlach, S Mandl, B Rauchenbach (2006) Influence of Nitrogen Implantation on the High Temperature Oxidation of Titanium-Based Alloys, Surf. Coat. Tech., 201, 3536

    Article  CAS  Google Scholar 

  15. HN Lee, ZM Park, MH Oh, KY Kim, DM Wee (1999) Oxidation Behavior and Mechanical Properties of Yttrium-Doped L12 (Al,Cr)3 Ti Coating on TiAl Alloys, Script Met., 41, 1073

    Article  CAS  Google Scholar 

  16. I Gurrappa (2001) Platinum Aluminide Coatings for Oxidation Resistance of Titanium Alloys, Platinum Metals Rev., 45, 124

    CAS  Google Scholar 

  17. I Gurrappa (2001) Effect of Aluminizing on the Oxidation Behavior of the Titanium Alloy IMI 834, Oxid. Metals, 56, 73

    Article  CAS  Google Scholar 

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Acknowledgments

The principal author (I. Gurrappa) is grateful to the European Commission for providing financial assistance for his stay at Northumbria University, United Kingdom. The authors would like to thank Prof. Alistair Sambell, Dean, School of Computing, Engineering and Information Sciences, Northumbria University, for his keen interest in this project, support, and encouragement. The principal author would like to thank Prof. P. Rama Rao, ARCI, Dr. D. Banerjee, Chief Controller (DRDO), and Dr. G. Malakondaiah, Director, DMRL, Hyderabad, for their constant support and encouragement.

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Gurrappa, I., Wilson, A. & Datta, P.K. Palladium and tantalum aluminide coatings for high-temperature oxidation resistance of titanium alloy IMI 834. J Coat Technol Res 6, 257–268 (2009). https://doi.org/10.1007/s11998-008-9113-9

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