Journal of Coatings Technology and Research

, Volume 4, Issue 4, pp 505–510 | Cite as

Photopolymers for rapid prototyping

  • R. Liska
  • M. Schuster
  • R. Inführ
  • C. Turecek
  • C. Fritscher
  • B. Seidl
  • V. Schmidt
  • L. Kuna
  • A. Haase
  • F. Varga
  • H. Lichtenegger
  • J. Stampfl
Brief Communication

Abstract

Rapid prototyping by means of stereolithography using different types of photopolymers has gained increasing interest because cellular structures can be built at a high resolution with sub-μm feature sizes. Structures made with digital light processing and microstereolithography and rapid prototyping based on two-photon absorption photopolymerization techniques are presented. Soluble photopolymers were developed to substitute crosslinked photopolymers as mold materials and to extend the variety of materials which can be cast. With these molds, the processing of ‘bio-inspired’ ceramic composites with a controlled architecture from a macroscopic scale down to the nanometer range is possible. Another example is the development of biophotopolymers that are based on commercially available reactive diluents and modified gelatin for the fabrication of cellular bone replacement materials. Biocompatibility was investigated by seeding with osteoblast-like cells.

Keywords

Photopolymers Rapid prototyping Biophotopolymers Digital light processing Microstereolithography Two-photon polymerization 

Notes

Acknowledgments

UDMA was provided by Ivoclar Vivadent AG, and photoinitiators were from Ciba Specialty Chemicals. The financial support was provided by the ‘Austrian Nano Initiative’ under contract No. N-703 and it and the TU innovative project ‘3D-Microfab’ are kindly acknowledged. H. Lichtenegger thanks the Austrian Science Fund (FWF) for their financial support under contract No. T190. R. Liska thanks the FWF for financial support (P18623-N17).

References

  1. 1.
    Hutmacher DW, Scaffold Design and Fabrication Technologies for Engineering Tissues—State-of-the-Art and Future Perspectives, J. Biomater. Sci.–Polym. Ed. 12, (1), 107–124, 2001CrossRefGoogle Scholar
  2. 2.
    Xiong Z, Y Yan, R Zhang, L Sun, Fabrication of Porous Poly(l-Lactic Acid) Scaffolds for Bone Tissue Engineering via Precise Extrusion, Scripta Materialia 45, 773–779, 2001CrossRefGoogle Scholar
  3. 3.
    Stampfl J, A Wöß, O Kolednik, P Fratzl, ‚Object Reconstruction and Object Construction: Applications in Materials Science, Recent Res. Dev. Appl. Phys. 5, 89–106, 2002Google Scholar
  4. 4.
    Lam CXF, XM Mo, SH Teoh, DW Hutmacher, Scaffold Development Using 3D Printing with Starch Powder, Mater. Sci. Eng., C20, 49–56, 2002Google Scholar
  5. 5.
    Leukers B, H Gulkan, S Irsen, S Milz, C Tille, M Schieker, H Seitz, Hydroxyapatite Scaffolds for Bone Tissue Engineering Made By 3D Printing, J. Mater. Sci.: Mater. Med. 16, (12), 1121–1124, 2005CrossRefGoogle Scholar
  6. 6.
    Bertsch A, S Zissi, JY Jezequel, S Corbel, JC Andre, Micro-Stereophotolithography Using a Liquid Crystal Display as Dynamic Mask-Generator, Microsyst. Technol., 3, (2), 42–47, 1997CrossRefGoogle Scholar
  7. 7.
    Stampfl, J, Wöß, A, Fratzl, P, Seidler, S, “Rapid Prototyping of Ceramic and Polymer Cellular Materials.” Proc. from the 2nd European Medical and Biological Engineering Conference (EMBEC), 172–3, Wien, 4th to 8th December 2002Google Scholar
  8. 8.
    Dufaud O, S Corbel, Stereolithography of PZT Ceramic Suspensions, Rapid Prototyp. J. 8, (2), 83–90, 2002CrossRefGoogle Scholar
  9. 9.
    Chu T-MG, DG Orton, SJ Hollister, SE Feinberg, JW Halloran, Mechanical and In Vivo Performance of Hydroxyapatite Implants with Controlled Architecture, Biomaterials, 23, 1283–1293, 2002CrossRefGoogle Scholar
  10. 10.
    Davis KA, JA Burdick, KS Anseth, Photoinitiated Cross-Linked Degradable Copolymer Networks for Tissue Engineering Applications, Biomaterials, 24, 2485–2495, 2003CrossRefGoogle Scholar
  11. 11.
    Liska R, B Seidl, 1,5-Diphenyl-1,4-Diyn-3-One: A Highly Efficient Photoinitiator, J. Polym. Sci. Part A: Polym. Chem., 43, 101–111, 2005CrossRefGoogle Scholar
  12. 12.
    Temenoff JS, AG Mikos, Injectable Biodegradable Materials for Orthopaedic Tissue Engineering, Biomaterials, 21, 2405–2412, 2000CrossRefGoogle Scholar
  13. 13.
    M Schuster, R Inführ, C Turecek, J Stampfl, F Varga, R Lisk, Photopolymers for Rapid Prototyping of Soluble Mould Materials and Moulding of Cellular Biomaterials, Chem. Monthly 137, 843–853, 2006CrossRefGoogle Scholar
  14. 14.
    Brandhuber, D, Hüsing, N, Raab, C, Torma, V, Peterlik, H, “Cellular Mesoscopically Organised Silica Monoliths with Tailored Surface Chemistry by One-Step Drying/Extraction/Surface Modification Processes.” J. Mater. Chem., 15, 1801–1806, (advance article), (2005)Google Scholar

Copyright information

© FSCT and OCCA 2007

Authors and Affiliations

  • R. Liska
    • 1
  • M. Schuster
    • 1
  • R. Inführ
    • 2
  • C. Turecek
    • 3
  • C. Fritscher
    • 2
  • B. Seidl
    • 1
  • V. Schmidt
    • 4
  • L. Kuna
    • 4
  • A. Haase
    • 4
  • F. Varga
    • 3
  • H. Lichtenegger
    • 2
  • J. Stampfl
    • 2
  1. 1.Institute of Applied Synthetic ChemistryVienna University of TechnologyViennaAustria
  2. 2.Institute of Materials Science and TechnologyVienna University of TechnologyViennaAustria
  3. 3.Ludwig Boltzmann Institute of OsteologyHanusch-KrankenhausViennaAustria
  4. 4.Institute of Nanostructured Materials and PhotonicsJoanneum ResearchWeizAustria

Personalised recommendations