High Performance of Asymmetric Alumina Hollow Fiber Membranes for the Clarification of Genipap (Genipa americana L.) Fruit Extract
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Membrane filtration processes represent a suitable alternative for fruit juice treatment, but the applied membrane should present high stability and permeability. Here, we propose the development and application of ceramic asymmetric hollow fiber membranes for genipap extract clarification. Genipap is an exotic fruit from Central and South America with considerable concentration of phenolic and iridoid compounds. The dual-layer ceramic hollow fiber membrane was fabricated by a single-step co-extrusion and co-sintering process. The developed hollow fibers presented the desired asymmetric structure, with an inner finger-like region that guaranteed a suitable permeate flux (191 L h−1 m−2 at 1 bar), while the outer sponge-like layer was responsible for solid retentions and for the membrane mechanical resistance. Reductions in turbidity, total polyphenol content, and genipin concentration were of 52, 17, and 4%, respectively. Mathematical modeling of the experimental flux decay showed that pore blocking was the main fouling mechanism during filtrations of genipap extract through the asymmetric hollow fibers. The presence of microchannels with larger pore size in the inner surface of the fiber probably mitigated cake formation. The increase in the transmembrane pressure from 1 to 2 bar did not improve the permeation flux through the membrane since the fouling layer resistance was considerably higher at 2 bar than at 1 bar. Thus, asymmetric ceramic hollow fibers are suggested for juice fruit clarification with improved permeate flux and clarification degree.
KeywordsMembrane Asymmetric ceramic hollow fiber Genipap
We acknowledge financial support from FAPEMIG (Fundação de Amparo à Pesquisa do Estado de Minas Gerais), CAPES (Coordenação de Aperfeiçoamento de Pessoal de Nível Superior), and CNPq (Conselho Nacional de Desenvolvimento Científico e Tecnológico).
- Hermia, J. (1982). Constant pressure blocking filtration laws—application to power-law non-Newtonian fluids. Transactions. Institution of Chemical Engineers, 60(3), 183–187.Google Scholar
- Hubadillah, S. K., Othman, M. H. D., Matsuura, T., Rahman, M. A., Jaafar, J., Ismail, A. F., & Amin, S. Z. M. (2018). Green silica-based ceramic hollow fiber membrane for seawater desalination via direct contact membrane distillation. Separation and Purification Technology, 205, 22–31.CrossRefGoogle Scholar
- Jeon, S., Karkhanechi, H., Fang, L.-F., Cheng, L., Ono, T., Nakamura, R., & Matsuyama, H. (2018). Novel preparation and fundamental characterization of polyamide 6 self-supporting hollow fiber membranes via thermally induced phase separation (TIPS). Journal of Membrane Science, 546(Supplement C), 1–14.CrossRefGoogle Scholar
- Kumar, B., Smita, K., Cumbal, L., Camacho, J., Hernández-Gallegos, E., de Guadalupe Chávez-López, M., Grijalva, M., & Andrade, K. (2016). One pot phytosynthesis of gold nanoparticles using Genipa americana fruit extract and its biological applications. Materials Science and Engineering: C, 62, 725–731.CrossRefGoogle Scholar
- Omena, C. M. B., Valentim, I. B., Guedes, G. S., Rabelo, L. A., Mano, C. M., Bechara, E. J. H., Sawaya, A. C. H. F., Trevisan, M. T. S., da Costa, J. G., Ferreira, R. C. S., Sant'Ana, A. E. G., & Goulart, M. O. F. (2012). Antioxidant, anti-acetylcholinesterase and cytotoxic activities of ethanol extracts of peel, pulp and seeds of exotic Brazilian fruits: Antioxidant, anti-acetylcholinesterase and cytotoxic activities in fruits. Food Research International, 49(1), 334–344.CrossRefGoogle Scholar
- Ramos-de-la-Pena, A. M., Renard, C. M. G. C., Montanez, J. C., de la Luz Reyes-Vega, M., & Carlos Contreras-Esquivel, J. (2015). Ultrafiltration for genipin recovery technologies after ultrasonic treatment of genipap fruit. Biocatalysis and Agricultural Biotechnology, 4(1), 11–16.CrossRefGoogle Scholar
- Ribeiro, L. F., Ribani, R. H., Francisco, T. M. G., Soares, A. A., Pontarolo, R., & Haminiuk, C. W. I. (2015). Profile of bioactive compounds from grape pomace (Vitis vinifera and Vitis labrusca) by spectrophotometric, chromatographic and spectral analyses. Journal of Chromatography B-Analytical Technologies in the Biomedical and Life Sciences, 1007, 72–80.CrossRefGoogle Scholar
- Singleton, V. L. (1985). Citation classic—Colorimetry of total phenolics with phosphomolybdic-phosphotungstic acid reagents. Current Contents/Agriculture Biology & Environmental Sciences, 48, 18.Google Scholar