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JOM

, Volume 71, Issue 9, pp 3277–3284 | Cite as

Preparation and Characterization of LiSb(OH)6 and LiSbF6 for Lithium-Ion Batteries

  • Weifeng Liu
  • Zanlang Tang
  • Duchao ZhangEmail author
  • Lin Chen
  • Tianzu Yang
Technical Article
  • 15 Downloads

Abstract

In this article, the methods of lithium salt and potassium salt were used to synthesize LiSb(OH)6. Meanwhile, LiSbF6 was also prepared by the methods of neutralized dissolution and hexafluoroantimonic acid. The relative contents of Li, Sb, and F in LiSb(OH)6 and LiSbF6 were determined, and the results showed these values were extremely similar to the theoretical values. The phases of the products were detected by x-ray diffraction, and the results indicated they were single-phase products with good crystallinity. The morphologies of the products were characterized by scanning electron microscope, which revealed the LiSb(OH)6 crystals were hexagonal layered structures. The infrared spectra of the LiSbF6 crystals proved the presence of SbF6 in the crystals. Moreover, the result of the thermal stability test indicated that the initial decomposition temperature of LiSbF6 was 367.64°C. Therefore, these novel methods can be used as a reference to effectively improve the traditional processes for LiSb(OH)6 and LiSbF6 preparation.

Notes

Acknowledgements

The authors acknowledge financial support from the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 51404296) and the Postdoctoral Science Foundation of China (Grant No. 2016M602427).

References

  1. 1.
    B. Scrosati and J. Garche, J. Power Sour. 195, 2419 (2010).CrossRefGoogle Scholar
  2. 2.
    Y. Gong, Y.J. Yu, K. Huang, J.X. Hu, and C.D. Li, J. Clean. Prod. 170, 915 (2018).CrossRefGoogle Scholar
  3. 3.
    K. Xu, Chem. Rev. 104, 4303 (2004).CrossRefGoogle Scholar
  4. 4.
    G. Moumouzias, G. Ritzoulis, D. Siapkas, and D. Terzidis, J. Power Sour. 122, 57 (2003).CrossRefGoogle Scholar
  5. 5.
    A. Subramania, R. Sathiyamoorthi, T. Vasudevan, and R. Gangadharan, Ionics 12, 327 (2006).CrossRefGoogle Scholar
  6. 6.
    E.W. Lawless, C.J.W. Wiegand, Y. Mizumoto, and C. Weis, Inorg. Chem. 10, 1084 (1971).CrossRefGoogle Scholar
  7. 7.
    C. Nanjundiah, J.L. Goldman, L.A. Dominey, and V.R. Koch, Cheminform. 20, 2914 (1989).CrossRefGoogle Scholar
  8. 8.
    J.W. Liu, X.H. Li, Z.X. Wang, H.J. Guo, W.J. Peng, Y.H. Zhang, and Q.Y. Hu, Trans. Nonferrous Met. Soc. China 20, 344 (2010).CrossRefGoogle Scholar
  9. 9.
    X. Wang, E. Yasukawa, and S. Mori, Electrochim. Acta 45, 2677 (2000).CrossRefGoogle Scholar
  10. 10.
    J.H. Burns, Acta Cryst. 15, 1098 (1962).CrossRefGoogle Scholar
  11. 11.
    G.M. Begun and A.C. Rutenberg, Inorg. Chem. 6, 2212 (1967).CrossRefGoogle Scholar
  12. 12.
    P.C. Barbosa, L.C. Rodrigues, M. Manuela, and M.J. Smith, ECS Trans. 19, 25 (2009).Google Scholar
  13. 13.
    M.M. Silva, P. Barbosa, A. Evans, and M.J. Smith, Solid State Sci. 8, 1318 (2006).CrossRefGoogle Scholar
  14. 14.
    L.C. Rodrigues, M. Fernandes, V.D.Z. Bermudez, M.M. Silva, and M.J. Smith, Solid State Ion. 226, 7 (2012).CrossRefGoogle Scholar
  15. 15.
    V. Seneviratne, R. Frech, and J.E. Furneaux, Electrochim. Acta 48, 2221 (2003).CrossRefGoogle Scholar
  16. 16.
    V. Seneviratne, R. Frech, J.E. Furneaux, and M. Khan, J. Phys. Chem. B 108, 8124 (2004).CrossRefGoogle Scholar
  17. 17.
    S.S. York, M. Buckner, and R. Frech, Macromolecules 37, 994 (2004).CrossRefGoogle Scholar
  18. 18.
    H. Mizoguchi, N.S. Bhuvanesh, Y.I. Kim, S. Ohara, and P.M. Woodward, Inorg. Chem. 53, 10570 (2014).CrossRefGoogle Scholar
  19. 19.
    O. Yamamoto, S. Li, and T. Sasamoto, J. Mater. Synth. Process. 6, 203 (1998).CrossRefGoogle Scholar
  20. 20.
    M. Kundu, S. Mahanty, and R.N. Basu, Mater. Lett. 65, 1105 (2011).CrossRefGoogle Scholar

Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  • Weifeng Liu
    • 1
  • Zanlang Tang
    • 1
  • Duchao Zhang
    • 1
    Email author
  • Lin Chen
    • 1
  • Tianzu Yang
    • 1
  1. 1.School of Metallurgy and EnvironmentCentral South UniversityChangshaPeople’s Republic of China

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