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JOM

, Volume 71, Issue 12, pp 4639–4646 | Cite as

Evaluation of Maghemite-Rich Iron Oxide Composite Prepared from Magnetite as Adsorbent for Gold from Chloride Solution

  • April Rose Malagum Calderon
  • Richard Diaz AlorroEmail author
  • Bogale Tadesse
  • Kyoungkeun Yoo
  • Carlito Baltazar Tabelin
Rare Metal Recovery from Secondary Resources
  • 93 Downloads

Abstract

The capacity and effectiveness of a composite magnetic iron oxide, consisting mainly of maghemite \( (\gamma {\text{Fe}}_{2} {\text{O}}_{3} ) \), prepared by oxidation of synthetic magnetite at 350°C have been evaluated. X-ray diffraction analysis of the synthesized product indicated an iron oxide with 44%, 33%, and 23% of maghemite, hematite (Fe2O3), and magnetite (Fe3O4), respectively. The produced composite material was used in this study as adsorbent to recover gold from chloride solution. The effects of different process parameters, such as solution pH, contact time, chloride ion concentration, and initial Au concentration, on the recovery of Au were studied. Almost all Au in solution (99.78%) was recovered at pH of about 6.5 after 24 h of contact time. The maximum Au uptake of about 11.5 µmol/g was obtained at initial Au concentration of 3.5 × 10−4 mol/L. No significant difference in Au uptake was observed upon increasing the contact time to 48 h. High chloride concentration was found to be detrimental to Au recovery. These results indicate that the prepared maghemite-rich iron oxide composite is more effective than synthetic magnetite reported in previous studies for recovery of Au from chloride solution.

Notes

Acknowledgements

The authors wish to acknowledge the R&D Center for Valuable Recycling (Global-Top R&BD Program), Ministry of Environment, Republic of Korea (under Project No. 2016002250004) for funding this research.

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Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  1. 1.Western Australian School of Mines: Minerals, Energy and Chemical EngineeringCurtin UniversityKalgoorlieAustralia
  2. 2.Department of Energy and Resources EngineeringKorea Maritime and Ocean University (KMOU)BusanRepublic of Korea
  3. 3.School of Minerals and Energy Resources EngineeringThe University of New South WalesSydneyAustralia

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