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Korean Journal of Chemical Engineering

, Volume 25, Issue 4, pp 808–811 | Cite as

Biological synthesis of bimetallic Au/Ag nanoparticles using Persimmon (Diopyros kaki) leaf extract

  • Jae Yong Song
  • Beom Soo KimEmail author
Biotechnology Short Communication

Abstract

Persimmon (Diopyros kaki) leaf extract was used for the synthesis of bimetallic Au/Ag nanoparticles. Competitive reduction of Au3+ and Ag+ ions present simultaneously in solution during exposure to Persimmon leaf extract leads to the formation of bimetallic Au/Ag nanoparticles. UV-visible spectroscopy was monitored as a function of reaction time to follow the formation of Au/Ag nanoparticles. The synthesized bimetallic Au/Ag nanoparticles were characterized with energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). SEM images showed that large Au/Ag particles of 50–500 nm were formed with some cubic structure, while pure Ag particles obtained by reduction of only Ag+ ion were smaller with diameter of 15–90 nm and predominantly spherical. The atomic Ag contents of the bimetallic Au/Ag nanoparticles from EDS and XPS analysis were 36 and 71 wt%, respectively, suggesting that bimetallic Au core/Ag shell structure was formed by competitive reduction of Au3+ and Ag+ ions with Persimmon leaf extract.

Key words

Biological Synthesis Nanoparticles Plant Extract Diopyros kaki Bimetallic Gold/Silver 

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Copyright information

© Springer 2008

Authors and Affiliations

  1. 1.Department of Chemical EngineeringChungbuk National UniversityCheongju, ChungbukKorea

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