Korean Journal of Chemical Engineering

, Volume 25, Issue 4, pp 675–680 | Cite as

One-step synthesis of methylmethacrylate from methacrolein over Keggin-type heteropoly compounds

Catalysis, Reaction Engineering, Industrial Chemistry

Abstract

One-step synthesis of methylmethacrylate (MMA) using heteropoly compounds (HPCs) as catalysts was demonstrated by feeding a mixture of methacrolein (MAL), air, water, nitrogen and MeOH (methanol). The HPCs with different counter-ions, such as H1.7Cs1.5Cu0.25As0.1PMo11VO40 (CsPMo11VO40), H1.7La0.7Cu0.25As0.1PMo11VO40 (LaPMo11VO40) and H1.7K1.5Cu0.25As0.1PMo11VO40 (KPMo11VO40), were studied in oxidation of MAL, esterification of methacrylic acid (MAA) and one-step synthesis of MMA from MAL, respectively. The selectivity of MAA was up to 45.7% and MMA was 44.6% with 93.3% MAL conversion over CsPMo11VO40.

Key words

Methylmethacrylate Methacrolein HPCs Counter Ions 

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Copyright information

© Springer 2008

Authors and Affiliations

  1. 1.State Key Laboratory Chemical Resource EngineeringBeijing University of Chemical TechnologyBeijingChina

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