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Melt miscibility and solid-state properties of metallocene LLDPE blends with HDPE: Influence of MM of LLDPE

  • Tayyab Hameed
  • Ibnelwaleed A. Hussein
Article

Abstract

The influence of relative molecular mass (MM) of LLDPE on the rheological, thermal and mechanical properties of two sets of m-LLDPE/HDPE blends of low and high branch content (BC) was studied. Blends of m-LLDPE with linear HDPE reveal no influence of MM (60–100 kg/mol) on melt miscibility at low BC (about 20 branches/1 000 C). However, at high BC levels (about 40 branches/1 000 C), MM affects the melt miscibility of m-LLDPE/HDPE blends. The DSC results suggest that compatibility in the solid state is independent of MM and BC. For all blends studied, the HDPE-rich blends are found to contain single crystal populations, suggesting high degree of cocrystallization, whereas, m-LLDPE rich phase shows separate crystallization. Mechanical properties of these blends are found to be a strong function of blend compatibility and the specific properties of the blend components. In general, the high BC pairs show poor mechanical properties.

Key words

molecular mass metallocene LLDPE miscibility rheological property 

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References

  1. [1]
    UTRACKI L A. Polymer Alloys and Blends; Thermodynamics and Rheology[M]. New York: Hanser, 1989.Google Scholar
  2. [2]
    HUSSSEIN I A, WILLIAMS M C. Polym Eng Sci, 2001, 41: 696.CrossRefGoogle Scholar
  3. [3]
    LA MANTIA F P, VALENZA A, ACIERNO D. Eur Polym J, 1986, 22(8): 647.CrossRefGoogle Scholar
  4. [4]
    HILL M J, MORGAN R L, BARHAM P. J Polymer, 1997, 38: 3003.CrossRefGoogle Scholar
  5. [5]
    ALAMO R G, GRAESSLEY W W, KRISHNAMOORTI R, et al. Macromolecules, 1997, 30: 561.CrossRefGoogle Scholar
  6. [6]
    TANEM B S, STORI A. Polymer, 2001, 42: 5389.CrossRefGoogle Scholar
  7. [7]
    HUSSEIN I A. Macromolecules, 2003, 36: 2024.CrossRefGoogle Scholar
  8. [8]
    HUSSEIN I A. Polym Int, 2004, 53: 1327.CrossRefGoogle Scholar
  9. [9]
    HUSSEIN I A. Proceedings of the 20th Meeting of the Polymer Processing Society, Akron, OH, June 20–24, 2004.Google Scholar
  10. [10]
    CHUANG C I, HAN C D. J Appl Polym Sci, 1994, 29: 2205.CrossRefGoogle Scholar
  11. [11]
    BINGHAM E C. Fluidity and Elasticity[M]. New York: McGraw-Hill, 1922: 86.Google Scholar
  12. [12]
    LIN C C. Polym J (Tokyo), 1979, 11: 185–192.CrossRefGoogle Scholar
  13. [13]
    BOUSMINA M, PALIERNE J F, UTRACKI L A. Polym Eng Sci, 19.Google Scholar
  14. [14]
    ABU-SHARKH B F, HUSSEIN I A. Polymer, 2002, 43: 6333.CrossRefGoogle Scholar
  15. [15]
    ARNAL M L, SANCHEZ J J, MULLER A J. Polymer, 2001: 6877.CrossRefGoogle Scholar

Copyright information

© Central South University Press, Sole distributor outside Mainland China: Springer 2007

Authors and Affiliations

  • Tayyab Hameed
    • 1
  • Ibnelwaleed A. Hussein
    • 2
  1. 1.Department of Chemical EngineeringKing Fahd University of Petroleum & MineralsDhahranSaudi Arabia
  2. 2.Center for Refining & Petrochemicals, Research InstituteKing Fahd University of Petroleum & MineralsDhahranSaudi Arabia

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