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Journal of Central South University of Technology

, Volume 13, Issue 6, pp 618–623 | Cite as

Synthesis of Ni-Zn ferrite and its microstructure and magnetic properties

  • Yang Zheng-hui  (阳征会)Email author
  • Gong Zhu-qing  (龚竹青)
  • Li Hong-xu  (李宏煦)
  • Ma Yu-tian  (马玉天)
  • Yang Yu-Fang  (杨余芳)
Article

Abstract

Nanometer Ni0.5Zn0.5Fe2O4 powders with spinel phase were prepared by the hydrothermal method using purified FeSO4 solution from sodium jarosite’s slag as materials. The results show that the spinel phase of Ni0.5Zn0.5Fe2O4 powders begins to form at a relatively low temperature (130 °C) and a shorter holding time (1 h) when pH=8. The crystallization kinetics equation at 200 °C is ln[-ln(1−x)] = −0.78+0.95ln t. The growth activation energy of Ni0.5Zn0.5Fe2O4 grains is 41.6 kJ/moL in hydrothermal synthesis process. With the increase of sintering temperature, the density and diameter shrinkage of ferrite circulus increase, whereas its pores decrease. The results of magnetic measurements show that saturation magnetic flux density Bs increases and the coercivity Hc decreases with the increase of their sintering temperature. Magnetic parameters of all the investigated samples satisfy the character demand of high Bs, low Br and low Hc of soft magnetic ferrite materials.

Key words

sodium jarosite hydrothermal synthesis Ni-Zn ferrite nanoparticle 

CLC number

TG31 

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Copyright information

© Published by: Central South University Press, Sole distributor outside Mainland China: Springer 2006

Authors and Affiliations

  • Yang Zheng-hui  (阳征会)
    • 1
    Email author
  • Gong Zhu-qing  (龚竹青)
    • 1
  • Li Hong-xu  (李宏煦)
    • 2
  • Ma Yu-tian  (马玉天)
    • 1
  • Yang Yu-Fang  (杨余芳)
    • 1
  1. 1.School of Metallurgical Science and EngineeringCentral South UniversityChangshaChina
  2. 2.School of Metallurgical and Ecological EngineeringBeijing University of Science and TechnologyBeijingChina

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