Journal of Surfactants and Detergents

, Volume 1, Issue 3, pp 399–402 | Cite as

Colloidal flocculation of micellar solutions of anionic surfactants

  • P. Paton
  • F. I. Talens-AlessonEmail author


Micellar solutions of anionic surfactants usually precipitate in the presence of cations, following a mechanism by which initially cations bind themselves to the micellar surface until saturation is achieved. At higher cation concentrations, unbound cations precipitate with surfactant monomers. In a few cases cations, and especially Al3+, cause surfactant micelles to flocculate. These flocs have properties as adsorbents of acidic organic compounds, which might be used in water treatment processes. Both α-olefinsulfonates C14−C16, and laurylsulfate micellar solutions are fast flocculation colloidal systems in the presence of Al3+.

Key Words

Aluminum AOS flocculation laurylsulfate light scattering micellar z-potential 


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Copyright information

© AOCS Press 1998

Authors and Affiliations

  1. 1.TALENCO Consulting08902 Hospitalet de Llobregat(Barcelona)Spain

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