Journal of Surfactants and Detergents

, Volume 1, Issue 2, pp 253–261

Oxygen bleaching systems in domestic laundry

  • Neal J. Milne
Review

Abstract

The oxidative bleaching process plays a key role in removing unwanted stains from laundry. This review covers methods of generation of active oxygen bleaching species, their activation and application. In addition, the requirements for commercially acceptable oxygen bleach products are discussed.

Key words

Activator bleaching hydrogen peroxide laundry oxidative peracid perborate percarbonate TAED 

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References

  1. 1.
    Van Ee, J.H., and M.P. Bollier, World Patent 9602623 (1996).Google Scholar
  2. 2.
    Thoen, J.K.A.C., R. Labeque, P.W.M. Goethals, and J.P. Johnston, World Patent 9315174 (1993).Google Scholar
  3. 3.
    Croud, V.B., S. Scarborough, and S.J. Tompsett, World Patent 9601311 (1996).Google Scholar
  4. 4.
    Day, M., World Patent 9745518 (1997).Google Scholar
  5. 5.
    Dannacher, J., and W. Schlenker, Book Pap. Int. Conf. Exhib. AATCC, 111–121 (1995).Google Scholar
  6. 6.
    Thompson, K.M., W.P. Griffith, and M. Spiro, Mechanism of Bleaching by Peroxides, J. Chem. Soc. Faraday Trans. 89:4035–4043 (1993).CrossRefGoogle Scholar
  7. 7.
    Davies, D.M., and M.E. Deary, A Convenient Preparation of Aqueous Methyl Hydroperoxide and a Comparison of Its Reactivity Towards Triacetylethylenediamine with That of Other Nucleophiles, J. Chem. Soc. Perkin 2: 559–562 (1992).Google Scholar
  8. 8.
    Davies, D.M., and M.E. Deary, Kinetics of the Hydrolysis and Perhydrolysis of Tetraacetylethylenediamine, a Peroxide Bleach Activatior, J. Chem. Soc. Perkin Trans.: 1549–1552 (1991).Google Scholar
  9. 9.
    Bolsman, T.A.B.M., R. Kok, and A.D. Vreugdenhil, Chemistry of Long-Chain Peroxy Acids Under Laundry Conditions, J. Am. Oil Chem. Soc. 65: 1211–1218 (1988).Google Scholar
  10. 10.
    Willey, A.D., M.E. Burns, and R.T. Hartshorn, World Patent 9428104 (1994).Google Scholar
  11. 11.
    Hodge, S.R., and A. Pearce, World Patent 8907639 (1989).Google Scholar
  12. 12.
    Willey, A.D., G.S. Miracle, K.L. Kott, and G.M. Bailley, World Patent 960915 (1996).Google Scholar
  13. 13.
    Bailley, G.M., F.F. Hardy, and N. Guedira, World Patent 9529160 (1995).Google Scholar
  14. 14.
    Milne, N.J., and J.M. Watkins, World Patent 9604244 (1996).Google Scholar
  15. 15.
    Del Grosso, M., and H. Offermanns, World Patent 9630482 (1996).Google Scholar
  16. 16.
    Nollet, A.J., J. Maijer, and J.W. Overkamp European Patent 202698 (1986).Google Scholar
  17. 17.
    Zielske, A.G., European Patent 267048 (1987).Google Scholar
  18. 18.
    Coles, B., J.D. Crowther, and E. Haque, World Patent 9514759 (1995).Google Scholar
  19. 19.
    Dankowski, M., M. Del Grosso, and A. Dorfer, European Patent 698661 (1996).Google Scholar
  20. 20.
    Burns, M.E., K.L. Kott, A.D. Willey, and G.S. Miracle, World Patent 9606913 (1996)Google Scholar
  21. 21.
    Reinhardt, G., and M. Loffler, New Reactive Bleach Activators, Tenside Surfactants Deterg. 34:404–409 (1997).Google Scholar
  22. 22.
    Woods, W., U.S. Patent 3532634 (1970).Google Scholar
  23. 23.
    Finch, T.D., and R.J. Wilde, European Patent 141470 (1984).Google Scholar
  24. 24.
    Van Kralingen, C.G., R.J. Martens, M.E. Rerek, T. Swarthoff, and M.R.P. Van Vliet, European Patent 392592 (1990).Google Scholar
  25. 25.
    Karpusiewicz, W.M., and E.J. McCallion, European Patent 224952 (1986).Google Scholar
  26. 26.
    Gregory, M.F., European Patent 384503 (1990).Google Scholar
  27. 27.
    Johnston, J.P., and J.R. Tate, U.S. Patent 4077768 (1978).Google Scholar
  28. 28.
    Favre, T.C.F., R. Hage, K. Helm-Rademaker, H. Kock, R.J. Martens, T. Swarthoff, and M.R.P., Van Vliet, European Patent 458397 (1991).Google Scholar
  29. 29.
    Truth Behind the Soap Wars Hype, Marketing (7 July):14–15 (1994).Google Scholar
  30. 30.
    Feringa, B.L., M. Lubben, R.M. Hermant, and R.S. Twisker, World Patent 9534628 (1995).Google Scholar
  31. 31.
    Kirk, O., and S.E. Gotfredsen, World Patent 8909813 (1989).Google Scholar
  32. 32.
    Lui, D.K., and A.C. Convents, World Patent 9533040 (1995).Google Scholar
  33. 33.
    Scialla, S., and A.J. Pretty, World Patent 9527774 (1995).Google Scholar
  34. 34.
    Burns, M.E., and F.E. Hardy, European Patent 170386 (1985).Google Scholar
  35. 35.
    Dyroff, D.R., D.P. Getman, and J.K. Glascock, European Patent 334427 (1989).Google Scholar
  36. 36.
    Hutchins, J.P., D.V. Julian, and M.E. Burns, German Patent 2737865 (1978).Google Scholar

Copyright information

© AOCS Press 1998

Authors and Affiliations

  • Neal J. Milne
    • 1
  1. 1.Warwick International LimitedHolywellNorth Wales, UK

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