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Frontiers in Energy

, Volume 13, Issue 1, pp 9–15 | Cite as

Cathodes with MnO2 catalysts for metal fuel battery

  • Songbo Wei
  • He LiuEmail author
  • Ran Wei
  • Lin Chen
Research Article
  • 11 Downloads

Abstract

A series of cathodes with MnO2 catalysts of metal fuel battery were prepared. The catalyst slurry was treated by ultrasonic dispersion under the ultrasonic time of 20 min, 40 min and 60 min. The cathodes were also dried with the temperature of 90°C, 120°C and 150°C. Besides, the microstructures of the cathodes and discharging performance were investigated. The results indicated that the ultrasonic time and drying temperature had a remarkable influence on the electric current densities, but had little effect on the open-circuit voltage. The effects of oxygen on the current density and voltage of cathode were also studied, and it was found that the method of blowing oxygen to cathode could increase the current density of the metal fuel battery.

Keywords

metal fuel battery cathode current density ultrasonic dispersion oxygen supply 

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References

  1. 1.
    Liu Y, Sun Q, Li W, Adair K R, Li J, Sun X. A comprehensive review on recent progress in aluminum air batteries. Green Energy & Environment, 2017, 2(3): 246–277CrossRefGoogle Scholar
  2. 2.
    Pollet B G, Staffell I, Shang J L. Current status of hybrid, battery and fuel cell electric vehicles: from electrochemistry to market prospects. Electrochimica Acta, 2012, 84: 235–249CrossRefGoogle Scholar
  3. 3.
    Dunn B, Kamath H, Tarascon J M. Electrical energy storage for the grid: a battery of choices. Science, 2011, 334(6058): 928–935CrossRefGoogle Scholar
  4. 4.
    Li Q, Bjerrum N J. Aluminum as anode for energy storage and conversion: a review. Journal of Power Sources, 2002, 110(1): 1–10CrossRefGoogle Scholar
  5. 5.
    Bruce P G, Freunberger S A, Hardwick L J, Tarascon J M. Li-O2 and Li-S batteries with high energy storage. Nature Materials, 2012, 11(1): 19–29CrossRefGoogle Scholar
  6. 6.
    Haneda T, Ono Y, Ikegami T, Akisawa A. Technological assessment of residential fuel cells using hydrogen supply systems for fuel cell vehicles. International Journal of Hydrogen Energy, 2017, 42(42): 26377–26388CrossRefGoogle Scholar
  7. 7.
    Eriksson E L V, Gray E M. Optimization and integration of hybrid renewable energy hydrogen fuel cell energy systems––a critical review. Applied Energy, 2017, 202: 348–364CrossRefGoogle Scholar
  8. 8.
    Wu G. Current challenge and perspective of PGM-free cathode catalysts for PEM fuel cells. Frontiers in Energy, 2017, 11(3): 286–298CrossRefGoogle Scholar
  9. 9.
    Moghaddam R B, Shahgaldi S, Li X. A facile synthesis of high activity cube-like Pt/carbon composites for fuel cell application. Frontiers in Energy, 2017, 11(3): 245–253CrossRefGoogle Scholar
  10. 10.
    Zhang C, Shen X, Pan Y, Peng Z. A review of Pt-based electrocatalysts for oxygen reduction reaction. Frontiers in Energy, 2017, 11(3): 268–285CrossRefGoogle Scholar
  11. 11.
    Rahman M A, Wang X, Wen C. High energy density metal-air batteries: a review. Journal of the Electrochemical Society, 2013, 160(10): A1759–A1771Google Scholar
  12. 12.
    Cheng F, Chen J. Metal-air batteries: from oxygen reduction electrochemistry to cathode catalysts. Chemical Society Reviews, 2012, 41(6): 2172–2192CrossRefGoogle Scholar
  13. 13.
    Danner T, Eswara S, Schulz V P, Latz A. Characterization of gas diffusion electrodes for metal-air batteries. Journal of Power Sources, 2016, 324: 646–656CrossRefGoogle Scholar
  14. 14.
    Mokhtar M, Talib M Z M, Majlan E H, Tasirin S M, Ramli W M F W, Daud W R W, Sahari J. Recent developments in materials for aluminum–air batteries: a review. Journal of Industrial and Engineering Chemistry, 2015, 32: 1–20CrossRefGoogle Scholar
  15. 15.
    Liu Y, Sun Q, Li W, Adair K R, Li J, Sun X. A comprehensive review on recent progress in aluminum air batteries. Green Energy & Environment, 2017, 2(3): 246–277CrossRefGoogle Scholar
  16. 16.
    Liu K, Peng Z, Wang H, Ren Y, Liu D, Li J, Tang Y, Zhang N. Fe3C@Fe/N doped graphene-like carbon sheets as a highly efficient catalyst in al-air batteries. Journal of the Electrochemical Society, 2017, 164(6): F475–F483Google Scholar
  17. 17.
    Wang X, Sebastian P J, Smit MA, Yang H, Gamboa S A. Studies on the oxygen reduction catalyst for zinc–air battery electrode. Journal of Power Sources, 2003, 124(1): 278–284CrossRefGoogle Scholar
  18. 18.
    Mori R. Electrochemical properties of a rechargeable aluminum–air battery with a metal–organic framework as air cathode material. RSC Advances, 2017, 7(11): 6389–6395CrossRefGoogle Scholar
  19. 19.
    Lima F H B, Calegaro M L, Ticianelli E A. Electrocatalytic activity of manganese oxides prepared by thermal decomposition for oxygen reduction. Electrochimica Acta, 2007, 52(11): 3732–3738CrossRefGoogle Scholar
  20. 20.
    Cheng F, Su Y, Liang J, Tao Z, Chen J. MnO2-based nanostructures as catalysts for electrochemical oxygen reduction in alkaline media. Chemistry of Materials, 2010, 22(3): 898–905CrossRefGoogle Scholar
  21. 21.
    Byon H R, Suntivich J, Shao-Horn Y. Graphene-based non-noblenetalcatalysts for oxygen reduction reaction in acid. Chemistry of Materials, 2011, 23(15): 3421–3428CrossRefGoogle Scholar
  22. 22.
    Yu L. Preparation of PTFE microporous fiber with catalytic capability. Dissertation for the Master’s Degree. Hangzhou: Zhejiang Sci-Tech University, 2009 (in Chinese)Google Scholar
  23. 23.
    Yang W, Li Y, Li B. Influence of ultrasonic pretreatment on modification effect of nano-sized titanium dioxide. Inorganic Chemicals Industry, 2008, 40(8): 27–29Google Scholar
  24. 24.
    Wang Y, Zeng X, Liu H, Song S. Effect of preparation conditions of catalyst in on the electrochemical properties of Pt/C catalyst. Chinese Journal of Catalysis, 2011, 32(1): 184–188Google Scholar
  25. 25.
    Cui C. Research and preparation of air electrode for zinc-air battery. Dissertation for the Master’s Degree. Harbin: Harbin Institute of Technology, 2013 (in Chinese)Google Scholar
  26. 26.
    Wang X, Sebastian P J, Smit MA, Yang H, Gamboa S A. Studies on the oxygen reduction catalyst for zinc–air battery electrode. Journal of Power Sources, 2003, 124(1): 278–284CrossRefGoogle Scholar
  27. 27.
    Yan B. Preparation and characterization of air cathode for aluminum-air battery. Dissertation for the Master’s Degree. Harbin: Harbin Institute of Technology, 2010 (in Chinese)Google Scholar

Copyright information

© Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.PetroChina Research Institute of Petroleum Exploration and DevelopmentBeijingChina

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