Frontiers of Materials Science

, Volume 10, Issue 1, pp 23–30 | Cite as

Synthesis, characterization and photoactivity of bi-crystalline mesoporous TiO2

  • Dongthanh Nguyen
  • Wei Wang
  • Haibo Long
  • Hongqiang Ru
Research Article


Mesoporous titania (meso-TiO2) has received extensive attention owing to its versatile potential applications. This paper reports a low-temperature templating approach for the fabrication of meso-TiO2 using the peroxo titanic acid (PTA) sol as precursor and Pluronic P123 as nonionic template. The TGA, XRD, N2 sorption, FE-SEM and HRTEM were used to characterize the obtained samples. The results showed that meso-TiO2 with high surface area up to 163 m2·g–1 and large pore volume of 0.65 cm3·g–1 can be obtained. The mesopore sizes can be varied between 13 and 20 nm via this synthesis approach. The amount of P123 and the calcination conditions were found to have great influence on the mesoporous and crystalline structures of meso-TiO2. The photocatalytic activity testing clearly shows that the high surface area and bi-crystallinity phases of meso-TiO2 play important roles in enhancing photocatalytic properties of meso-TiO2 in photo-decomposing Rhodamine B in water.


surfactant templating mesopore bi-crystallinity titania 


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  1. [1]
    Boettcher S W, Fan J, Tsung C K, et al. Harnessing the sol–gel process for the assembly of non-silicate mesostructured oxide materials. Accounts of Chemical Research, 2007, 40(9): 784–792CrossRefGoogle Scholar
  2. [2]
    Li W, Wu Z, Wang J, et al. A perspective on mesoporous TiO2 materials. Chemistry of Materials, 2014, 26(1): 287–298CrossRefGoogle Scholar
  3. [3]
    Zhang R, Elzatahry A A, Al-Deyab S S, et al. Mesoporous titania: From synthesis to application. Nano Today, 2012, 7(4): 344–366CrossRefGoogle Scholar
  4. [4]
    Pan J H, Dou H, Xiong Z, et al. Porous photocatalysts for advanced water purifications. Journal of Materials Chemistry, 2010, 20(22): 4512–4528CrossRefGoogle Scholar
  5. [5]
    Oveisi H, Suzuki N, Beitollahi A, et al. Aerosol-assisted fabrication of mesoporous titania spheres with crystallized anatase structures and investigation of their photocatalitic properties. Journal of Sol-Gel Science and Technology, 2010, 56(2): 212–218CrossRefGoogle Scholar
  6. [6]
    Samiee L, Beitollahi A, Vinu A. Effect of calcination atmosphere on the structure and photocatalytic properties of titania mesoporous powder. Research on Chemical Intermediates, 2012, 38(7): 1467–1482CrossRefGoogle Scholar
  7. [7]
    Shamaila S, Sajjad A K L, Chen F, et al. Mesoporous titania with high crystallinity during synthesis by dual template system as an efficient photocatalyst. Catalysis Today, 2011, 175(1): 568–575CrossRefGoogle Scholar
  8. [8]
    Renuka N K, Praveen A K, Aravindakshan K K. Synthesis and characterisation of mesoporous anatase TiO2 with highly crystalline framework. Materials Letters, 2013, 91: 118–120CrossRefGoogle Scholar
  9. [9]
    Chang Y S, Lee Y C, Yuhara J, et al. Effect of water on the formation of nanostructured mesoporous titania. Current Applied Physics, 2011, 11(3): 486–491CrossRefGoogle Scholar
  10. [10]
    Chu S, Luo L L, Yang J C, et al. Low-temperature synthesis of mesoporous TiO2 photocatalyst with self-cleaning strategy to remove organic templates. Applied Surface Science, 2012, 258 (24): 9664–9667CrossRefGoogle Scholar
  11. [11]
    Xu J H, Dai W L, Li J X, et al. Novel core–shell structured mesoporous titania microspheres: Preparation, characterization and excellent photocatalytic activity in phenol abatement. Journal of Photochemistry and Photobiology A: Chemistry, 2008, 195(2–3): 284–294CrossRefGoogle Scholar
  12. [12]
    Mohamed M M, Bayoumy W A, Khairy M, et al. Structural features and photocatalytic behavior of titania and titania supported vanadia synthesized by polyol functionalized materials. Microporous and Mesoporous Materials, 2008, 109(1–3): 445–457CrossRefGoogle Scholar
  13. [13]
    Dong Q, Su H L, Zhang D, et al. Synthesis of hierarchical mesoporous titania with interwoven networks by eggshell membrane directed sol–gel technique. Microporous and Mesoporous Materials, 2007, 98(1-3): 344–351CrossRefGoogle Scholar
  14. [14]
    Chen L, Yao B D, Cao Y, et al. Synthesis of well-ordered mesoporous titania with tunable phase content and high photoactivity. Journal of Physical Chemistry C, 2007, 111(32): 11849–11853CrossRefGoogle Scholar
  15. [15]
    Tian C X, Yang Y, Pu H. Effect of calcination temperature on porous titania prepared from industrial titanyl sulfate solution. Applied Surface Science, 2011, 257(20): 8391–8395CrossRefGoogle Scholar
  16. [16]
    Baiju K V, Periyat P, Shajesh P, et al. Mesoporous gadolinium doped titania photocatalyst through an aqueous sol–gel method. Journal of Alloys and Compounds, 2010, 505(1): 194–200CrossRefGoogle Scholar
  17. [17]
    Shibata H, Mihara H, Mukai T, et al. Preparation and formation mechanism of mesoporous titania particles having crystalline wall. Chemistry of Materials, 2006, 18(9): 2256–2260CrossRefGoogle Scholar
  18. [18]
    Tian C X, Zhang Z, Hou J, et al. Surfactant/co-polymer template hydrothermal synthesis of thermally stable, mesoporous TiO2 from TiOSO4. Materials Letters, 2008, 62(1): 77–80CrossRefGoogle Scholar
  19. [19]
    Shibata H, Ogura T, Mukai T, et al. Direct synthesis of mesoporous titania particles having a crystalline wall. Journal of the American Chemical Society, 2005, 127(47): 16396–16397CrossRefGoogle Scholar
  20. [20]
    Song H, Chen T, Sun Y, et al. Controlled synthesis of porous flower-like TiO2 nanostructure with enhanced photocatalytic activity. Ceramics International, 2014, 40(7): 11015–11022CrossRefGoogle Scholar
  21. [21]
    Tang H, Zhang D, Tang G G, et al. Low temperature synthesis and photocatalytic properties of mesoporous TiO2 nanospheres. Journal of Alloys and Compounds, 2014, 591: 52–57CrossRefGoogle Scholar
  22. [22]
    Ge L, Xu M X. Fabrication and characterization of TiO2 photocatalytic thin film prepared from peroxo titanic acid sol. Journal of Sol-Gel Science and Technology, 2007, 43(1): 1–7CrossRefGoogle Scholar
  23. [23]
    Lee C K, Kim D K, Lee J H, et al. Preparation and characterization of peroxo titanic acid solution using TiCl3. Journal of Sol-Gel Science and Technology, 2004, 31(1–3): 67–72CrossRefGoogle Scholar
  24. [24]
    Kim G H, Lee C G, Kim I. Properties of TiO2 film prepared from titanium tetrachloride. Metals and Materials International, 2004, 10(5): 423–427CrossRefGoogle Scholar
  25. [25]
    Sasirekha N, Rajesh B, Chen Y W. Synthesis of TiO2 sol in a neutral solution using TiCl4 as a precursor and H2O2 as an oxidizing agent. Thin Solid Films, 2009, 518(1): 43–48CrossRefGoogle Scholar
  26. [26]
    Liu Y J, Aizawa M, Wang Z M, et al. Comparative examination of titania nanocrystals synthesized by peroxo titanic acid approach from different precursors. Journal of Colloid and Interface Science, 2008, 322(2): 497–504CrossRefGoogle Scholar
  27. [27]
    Zakharova G S, Andreikov E I. Effect of the precursor heat treatment procedure on the properties of titania photocatalysts. Inorganic Materials, 2012, 48(7): 727–731CrossRefGoogle Scholar
  28. [28]
    Wang W, Nguyen D T, Long H B, et al. High temperature and water-based evaporation-induced self-assembly approach for facile and rapid synthesis of nanocrystalline mesoporous TiO2. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2014, 2(38): 15912–15920CrossRefGoogle Scholar
  29. [29]
    Wan Y, Zhao D. On the controllable soft-templating approach to mesoporous silicates. Chemical Reviews, 2007, 107(7): 2821–2860CrossRefGoogle Scholar
  30. [30]
    Wan Y, Shi Y, Zhao D. Designed synthesis of mesoporous solids via nonionic-surfactant-templating approach. Chemical Communications, 2007, (9): 897–926CrossRefGoogle Scholar
  31. [31]
    Wang W, Qi H, Long H, et al. A simple ternary non-ionic templating system for preparation of complex hierarchically mesomesoporous silicas with 3D interconnected large mesopores. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2014, 2(15): 5363–5370CrossRefGoogle Scholar
  32. [32]
    Wang W, Shan W J, Ru H Q, et al. Short-time synthesis of SBA- 15s with large mesopores via partitioned cooperative selfassembly process based on sodium silicate. Journal of Sol-Gel Science and Technology, 2012, 64(1): 200–208CrossRefGoogle Scholar
  33. [33]
    Zhang H, Banfield J F. Understanding polymorphic phase transformation behavior during growth of nanocrystalline aggregates: Insights from TiO2. The Journal of Physical Chemistry B, 2000, 104(15): 3481–3487CrossRefGoogle Scholar
  34. [34]
    Wanka G, Hoffmann H, Ulbricht W. Phase diagrams and aggregation behavior of poly(oxyethylene)-poly(oxypropylene)- poly(oxyethylene) triblock copolymers in aqueous solutions. Macromolecules, 1994, 27(15): 4145–4159CrossRefGoogle Scholar
  35. [35]
    Yamada S, Wang Z, Mouri E, et al. Crystallization of titania ultrafine particles from peroxotitanic acid in aqueous solution in the present of polymer and incorporation into poly(methyl methacylate) via dispersion in organic solvent. Colloid & Polymer Science, 2009, 287(2): 139–146CrossRefGoogle Scholar
  36. [36]
    Bacsa R R, Kiwi J. Effect of rutile phase on the photocatalytic properties of nanocrystalline titania during the degradation of p-coumaric acid. Applied Catalysis B: Environmental, 1998, 16(1): 19–29CrossRefGoogle Scholar
  37. [37]
    Bakardjieva S, Šubrt J, Štengl V, et al. Photoactivity of anatase-rutile TiO2 nanocrystalline mixtures obtained by heat treatment of homogeneously precipitated anatase. Applied Catalysis B: Environmental, 2005, 58(3–4): 193–202CrossRefGoogle Scholar
  38. [38]
    Ohno T, Tokieda K, Higashida S, et al. Synergism between rutile and anatase TiO2 particles in photocatalytic oxidation of naphthalene. Applied Catalysis A, 2003, 244(2): 383–391CrossRefGoogle Scholar
  39. [39]
    Yan M, Chen F, Zhang J, et al. Preparation of controllable crystalline titania and study on the photocatalytic properties. The Journal of Physical Chemistry B, 2005, 109(18): 8673–8678CrossRefGoogle Scholar

Copyright information

© Higher Education Press and Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  1. 1.Key Laboratory for Anisotropy and Texture of Materials of Ministry of Education (ATM)Northeastern UniversityShenyangChina
  2. 2.School of Materials and MetallurgyNortheastern UniversityShenyangChina

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