Journal of Phase Equilibria and Diffusion

, Volume 37, Issue 3, pp 269–276 | Cite as

Interdiffusion and Atomic Mobility Studies in Ni-Rich fcc Ni-Co-Al Alloys

Article

Abstract

The ternary interdiffusion coefficients in fcc Ni-Co-Al alloys at 1373 K were determined using Whittle and Green method together with electronic-probe microanalysis. With the help of DICTRA software, the experimental diffusion coefficients were critically assessed to obtain the atomic mobilities of Ni, Co and Al in fcc Ni-Co-Al alloys. Comprehensive comparisons between calculated and experimental diffusion coefficients showed that the experimental data could be well reproduced by the atomic mobilities obtained in the present work. The developed diffusion mobilities were further validated by the calculation of the concentration profiles and diffusion paths in diffusion couples.

Keywords

atomic mobility DICTRA diffusion couple interdiffusion coefficients Whittle and Green method 

Notes

Acknowledgment

This work thanks the support from the Industry-university research project of Aviation Industry Corporation of China (No. CXY2014XD27), the Fundamental Research Funds for the Central Universities (No. 20720140511), Ministry of Science and Technology of China (Grant No. 2014DFA53040) and the National Natural Science Foundation of China (No. 51201145, and No. 51301146).

References

  1. 1.
    R.C. Reed, The Superalloys: Fundamentals and Applications, Cambridge University Press, Cambridge, 2006CrossRefGoogle Scholar
  2. 2.
    C.T. Sims, N.S. Stoloff, and W.C. Hagel, Superalloys II, Wiley, New York, 1987Google Scholar
  3. 3.
    T.M. Pollock and S. Tin, Nickel-Based Superalloys for Advanced Turbine Engines: Chemistry, Microstructure and Properties, J. Propul. Power, 2006, 22, p 361-374CrossRefGoogle Scholar
  4. 4.
    S. Walston, A. Cetel, R. MacKay, K. O’hara, D. Duhl, and R. Dreshfield, Joint Development of a Fourth Generation Single Crystal Superalloy, Superalloys, 2004, 2004, p 15-24Google Scholar
  5. 5.
    M.V. Nathal and L.J. Ebert, The Influence of Cobalt, Tantalum, and Tungsten on the Microstructure of Single Crystal Nickel-Base Superalloys, Metall. Trans. A, 1985, 16, p 1849-1862CrossRefGoogle Scholar
  6. 6.
    E. Mabruri, S. Sakurai, Y. Murata, T. Koyama, and M. Morinaga, Interdiffusion in Ni-Co-Re and Ni-Co-Ru Systems, Mater. Trans., 2007, 48, p 2718-2723CrossRefGoogle Scholar
  7. 7.
    X.J. Liu, J.Y. Lin, Y. Lu, Y.H. Guo, and C.P. Wang, Assessment of the Atomic Mobility for the fcc Phase of Ni-Co-X (X = Re and Ru) System, Calphad, 2014, 45, p 138-144CrossRefGoogle Scholar
  8. 8.
    J. Chen, Y. Liu, G. Sheng, F. Lei, and Z. Kang, Atomic Mobilities, Interdiffusivities and Their Related Diffusional Behaviors in fcc Co-Cr-Ni Alloys, J. Alloy. Compd., 2014, 621, p 428-433CrossRefGoogle Scholar
  9. 9.
    K. Cheng, D. Liu, L. Zhang, Y. Du, S. Liu, and C. Tang, Interdiffusion and Atomic Mobility Studies in Ni-rich fcc Ni-Al-Mn Alloys, J. Alloy. Compd., 2013, 579, p 124-131CrossRefGoogle Scholar
  10. 10.
    M. Hattori, N. Goto, Y. Murata, T. Koyama, and M. Morinaga, Diffusion of Refractory Elements in Ni-Al-X (X: Re, W) Ternary Alloys, Mater. Trans., 2005, 46, p 163-166CrossRefGoogle Scholar
  11. 11.
    E. Mabruri, M. Hattori, K. Hasuike, T. Kunieda, Y. Murata, and M. Morinaga, Al and Re Interdiffusion in the γ-Phase of Ni-Al-Re System, Mater. Trans., 2006, 47, p 1408-1411CrossRefGoogle Scholar
  12. 12.
    J.O. Andersson, T. Helander, L. Höglund, P. Shi, and B. Sundman, Thermo-Calc & DICTRA, Computational Tools for Materials Science, Calphad, 2002, 26, p 273-312CrossRefGoogle Scholar
  13. 13.
    A. Borgenstam, L. Höglund, J. Ågren, and A. Engström, DICTRA, a Tool for Simulation of Diffusional Transformations in Alloys, JPE, 2000, 21, p 269-280CrossRefGoogle Scholar
  14. 14.
    J. Kirkaldy, Diffusion in Multicomponent Metallic Systems, Can. J. Phys., 1957, 35, p 435-440ADSCrossRefGoogle Scholar
  15. 15.
    J. Morral, Chemical Diffusivities and Their Hidden Concentration Units, Journal of Phase Equilibria and Diffusion, 2014, 35, p 581-586CrossRefGoogle Scholar
  16. 16.
    D. Whittle and A. Green, The Measurement of Diffusion Coefficients in Ternary Systems, Scr. Metall., 1974, 8, p 883-884CrossRefGoogle Scholar
  17. 17.
    J. Ågren, Numerical Treatment of Diffusional Reactions in Multicomponent Alloys, J. Phys. Chem. Solids, 1982, 43, p 385-391ADSCrossRefGoogle Scholar
  18. 18.
    J. Ågren, Diffusion in Phases with Several Components and Sublattices, J. Phys. Chem. Solids, 1982, 43, p 421-430ADSCrossRefGoogle Scholar
  19. 19.
    J. Andersson, L. Höglund, B. Jönsson, J. Ågren, and G. Purdy, Fundamentals and Applications of Ternary Diffusion, Pergamon Press, New York, 1990, p 153-163CrossRefGoogle Scholar
  20. 20.
    J.O. Andersson and J. Agren, Models for Numerical Treatment of Multicomponent Diffusion in Simple Phases, J. Appl. Phys., 1992, 72, p 1350-1355ADSCrossRefGoogle Scholar
  21. 21.
    B. Jönsson, Ferromagnetic Ordering and Diffusion of Carbon and Nitrogen in bcc Cr-Fe-Ni Alloys, Zeitschrift für Metallkunde, 1994, 85, p 498-501Google Scholar
  22. 22.
    B. Jönsson, Assessment of the Mobility of Carbon in fcc C-Cr-Fe-Ni Alloys, Zeitschrift für Metallkunde, 1994, 85, p 502-509Google Scholar
  23. 23.
    B. Jönsson, On Ferromagnetic Ordering and Lattice Diffusion: A Simple Model, Zeitschrift für Metallkunde, 1992, 83, p 349-355Google Scholar
  24. 24.
    O. Redlich and A. Kister, Algebraic Representation of Thermodynamic Properties and the Classification of Solutions, Ind. Eng. Chem., 1948, 40, p 345-348CrossRefGoogle Scholar
  25. 25.
    M. Hillert, Empirical Methods of Predicting and Representing Thermodynamic Properties of Ternary Solution Phases, Calphad, 1980, 4, p 1-12CrossRefGoogle Scholar
  26. 26.
    J. Kirkaldy, D. Weichert, and Z.U. Haq, Diffusion in Multicomponent Metallic Systems: VI. Some Thermodynamic Properties of the D Matrix and the Corresponding Solutions of the Diffusion Equations, Can. J. Phys., 1963, 41, p 2166-2173ADSCrossRefGoogle Scholar
  27. 27.
    J. Zhu, M. Titus, and T. Pollock, Experimental Investigation and Thermodynamic Modeling of the Co-Rich Region in the Co-Al-Ni-W Quaternary System, J. Phase Equilib. Diffus., 2014, 35, p 595-611CrossRefGoogle Scholar
  28. 28.
    L. Zhang, Y. Du, Q. Chen, I. Steinbach, and B. Huang, Atomic Mobilities and Diffusivities in the fcc, L12 and B2 Phases of the Ni-Al System, Int. J. Mater. Res., 2010, 101, p 1461-1475CrossRefGoogle Scholar
  29. 29.
    Y.-W. Cui, B. Tang, R. Kato, R. Kainuma, and K. Ishida, Interdiffusion and atomic mobility for face-centered-cubic Co-Al alloys, Metall. Mater. Trans. A, 2011, 42, p 2542-2546CrossRefGoogle Scholar
  30. 30.
    C.E. Campbell, W.J. Boettinger, and U.R. Kattner, Development of a Diffusion Mobility Database for Ni-Base Superalloys, Acta Mater., 2002, 50, p 775-792CrossRefGoogle Scholar
  31. 31.
    B. Jansson, Evaluation of parameters in thermochemical models using different types of experimental data simultaneously (PARROT), Stockholm Materials Research Center: TRITA-MAC-0234, (1984).Google Scholar
  32. 32.
    Y.H. Sohn and M.A. Dayananda, A Double-Serpentine Diffusion Path for a Ternary Diffusion Couple, Acta Mater., 2000, 48, p 1427-1433CrossRefGoogle Scholar

Copyright information

© ASM International 2016

Authors and Affiliations

  1. 1.Department of Materials Science and Engineering, Fujian Key Laboratory of Materials Genome, College of MaterialsXiamen UniversityXiamenPeople’s Republic of China
  2. 2.Department of AeronauticsXiamen UniversityXiamenPeople’s Republic of China

Personalised recommendations