Journal of Failure Analysis and Prevention

, Volume 10, Issue 1, pp 3–7 | Cite as

TEM Study of Lizardite-1T Particles in Toluene Solvent

Feature

Abstract

Micrometer sized particles of lizardite-1T phase are observed in toluene solvent. Phase identification is carried out by selected-area electron diffraction experiment and simulation. TEM study shows that the particles are in flake forms with the (001) preferred orientation. Energy-dispersive X-ray spectra reveal some particles containing Mg and Si, and others containing Al and Si. Structural deterioration of the lizardite-1T phase occurs under relative higher dose of electron beams. The results of this characterization of lizardite-1T particles show the importance of beam-induced deterioration and emphasize the potential importance of such deterioration in the characterization of nano scale systems.

Keywords

Characterization Electron microscopy Microstructure Lizardite-1T 

References

  1. 1.
    Parikh, A.N., Schivley, M.A., Koo, E., Seshadri, K., Aurentz, D., Mueller, K., Allara, D.L.: n-Alkylsiloxanes: from single monolayers to layered crystals. The formation of crystalline polymers from the hydrolysis of n-octadecyltrichlorosilane. J. Am. Chem. Soc. 119, 3135–3143 (1997)CrossRefGoogle Scholar
  2. 2.
    Shimojima, A., Wu, C.W., Kuroda, K.: Structure and properties of multilayered siloxane–organic hybrid films prepared using long-chain organotrialkoxysilanes containing C=C double bonds. J. Mater. Chem 17, 658–663 (2007)CrossRefGoogle Scholar
  3. 3.
    Rucklidge, J.C., Zussman, J.: The crystal structure of the serpentine mineral, lizardite Mg3Si2O5(OH)4. Acta Cryst 19, 381–389 (1965)CrossRefGoogle Scholar
  4. 4.
    Mellini, M.: The crystal structure of lizardite 1T: hydrogen bonds and polytypism. Am. Mineral. 67, 587–598 (1982)Google Scholar
  5. 5.
    Mellini, M., Zanazzi, P.F.: Crystal structures of lizardite-1T and lizardite-2H1 from Coli, Italy. Am. Mineral. 72, 943–948 (1987)Google Scholar
  6. 6.
    Guggenheim, S., Zhan, W.-D.: Effect of temperaturoe on the structures of lizardite-1T and liardite-2H1. Can. Mineral. 36, 1587–1594 (1998)Google Scholar
  7. 7.
    Zhukhlistov, A.P., Zvyagin, B.B.: Crystal structure of lizardite 1T from electron diffractometry data. Cryst. Rep. 43, 950–955 (1998)Google Scholar
  8. 8.
    Li, X.Z.: JECP/ED—A computer program for simulation of selected-area and precession electron diffraction patterns. J. Appl. Cryst. 36, 956 (2003)CrossRefGoogle Scholar
  9. 9.
    ICSD: Inorganic Crystal Structure Database. Fachinformationszentrum Karlsruhe, Germany (2008)Google Scholar

Copyright information

© ASM International 2009

Authors and Affiliations

  1. 1.Department of Engineering MechanicsUniversity of NebraskaLincolnUSA
  2. 2.Nebraska Center for Materials and NanoscienceUniversity of NebraskaLincolnUSA
  3. 3.Dalian University of TechnologyLiaoningPeople’s Republic of China

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