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Journal of Thermal Spray Technology

, Volume 28, Issue 1–2, pp 265–272 | Cite as

Characterizations of Composite Titanium Nitride Coatings Deposited by Very Low-Pressure Plasma Spraying

  • Xiujuan FanEmail author
  • Geoffrey Darut
  • Marie-Pierre Planche
  • Xiaohua Feng
  • Hanlin Liao
  • Ghislain Montavon
Peer Reviewed
  • 48 Downloads

Abstract

In this study, composite titanium nitride coating deposition by reactive spraying was carried under a controlled low-pressure (150 pa) atmosphere with a F4-VB low-power plasma gun. Pure titanium powder is injected into the plasma, and a reactive gas (N2) is added on the substrate surface to generate nitriding reactions. The experiments were carried out at different radial distances of the plasma plume. Morphologies of the coating present quite dense binary structure deposited by molten, vapors particles. As measured by means of x-ray diffraction, the coatings composition is modified with an evolution of TiN0.3, Ti2N and TiN phase crystalline phases along radial distance of the plume. The nitride phases (Ti2N, TiN) contents of the coating show a linear relationship with the micro-hardness of the coating. Micro-hardness of VLPPS-processed composite titanium coatings reaches 1071HV0.03.

Keywords

morphology and phase composition micro-hardness titanium nitride very low-pressure plasma spraying 

Notes

Acknowledgments

The authors are grateful to the financial supports by the China Scholarship Council (CSC-No. 201504490061) and Marie Curie [Grant No. FP7-IPACT-268696(EU)].

References

  1. 1.
    A.P. Serro, C. Completo, R. Colaço, F. dos Santos, C. Lobato da Silva, J.M.S. Cabral, H. Araújo, E. Pires, and B. Saramago, A Comparative Study of Titanium Nitrides, TiN, TiNbN and TiCN, as Coatings for Biomedical Applications, Surf. Coat. Technol., 2009, 203, p 3701-3707CrossRefGoogle Scholar
  2. 2.
    B. Subramanian, C.V. Muraleedharan, R. Ananthakumar, and M. Jayachandran, A Comparative Study of Titanium Nitride (TiN), Titanium Oxy Nitride (TiON) and Titanium Aluminum Nitride (TiAlN), as Surface Coatings for Bio Implants, Surf. Coat. Technol., 2011, 205, p 5014-5020CrossRefGoogle Scholar
  3. 3.
    B. Tian, W. Yue, C. Wang, and J. Liu, A Comparative Study of Titanium Nitride (TiN), Titanium Oxy Nitride (TiON) and Titanium Aluminum Nitride (TiAlN), as Surface Coatings for Bio Implants, Surf. Coat. Technol., 2011, 205, p 5014-5020CrossRefGoogle Scholar
  4. 4.
    A. Bahri, N. Guermazi, K. Elleuch, and M. Ürgen, Tribological Performance of TiN Coatings Deposited on 304L Stainless Steel Used for Olive-Oil Extraction, Wear, 2015, 342, p 77-84CrossRefGoogle Scholar
  5. 5.
    X. Shi, L. Xu, M. Munar, and K. Ishikawa, Hydrothermal Treatment for TiN as Abrasion Resistant Dental Implant Coating and Its Fibroblast Response, Mater. Sci. Eng. C, 2015, 49, p 1-6CrossRefGoogle Scholar
  6. 6.
    B. Elsener, A. Rota, and H. Böhni, Impedance Study on the Corrosion of PVD and CVD Titanium Nitride Coating, Mater. Sci. Forum, 1989, 44-45, p 29-38CrossRefGoogle Scholar
  7. 7.
    F. Lang and Z. Yu, The Corrosion Resistance and Wear Resistance of Thick TiN Coatings Deposited by Arc Ion Plating, Surf. Coat. Technol., 2001, 145(1-3), p 80-87CrossRefGoogle Scholar
  8. 8.
    L. Xiao, D. Yan, J. He, L. Zhu, Y. Dong, J. Zhang, and X. Li, Nanostructured TiN Coating Prepared by Reactive Plasma Spraying in Atmosphere, Appl. Surf. Sci., 2007, 253(18), p 7535-7539CrossRefGoogle Scholar
  9. 9.
    V. Serban, R. Rosu, A. Bucur, and D. Pascu, Deposition of Titanium Nitride Layers by Electric Arc-Reactive Plasma Spraying Method, Appl. Surf. Sci., 2013, 265, p 245-249CrossRefGoogle Scholar
  10. 10.
    K. Niessen and M. Gindrat, Plasma Spray-PVD: A New Thermal Spray Process to Deposit Out of the Vapor Phase, J. Therm. Spray Technol., 2011, 20(4), p 736-743CrossRefGoogle Scholar
  11. 11.
    M.F. Smith, A.C. Hall, J.D. Fleetwood, and P. Meyer, Very Low-Pressure Plasma Spray—A Review of an Emerging Technology in the Thermal Spray Community, Coatings, 2011, 1(2), p 117-132CrossRefGoogle Scholar
  12. 12.
    X. Fan, G. Darut, M. Planche, H. Liao, and G. Montavon, Formation Mechanisms of In-situ Al Based Intermetallic Coatings Manufactured by Very-Low Pressure Plasma Spraying, Surf. Coat. Technol., 2018, 334, p 300-304CrossRefGoogle Scholar
  13. 13.
    L. Zhu, N. Zhang, B. Zhang, R. Bolot, and H. Liao, Synthesis and Microstructure Observation of Titanium Carbon Nitride Nanostructured Coatings Using Reactive Plasma Spraying in Atmosphere, Appl. Surf. Sci., 2011, 257, p 8722-8727CrossRefGoogle Scholar
  14. 14.
    C. Pierlot, L. Pawlowski, M. Bigan, and P. Chagnon, Design of Experiments in Thermal Spraying: A Review, Surf. Coat. Technol., 2008, 202, p 4483-4490CrossRefGoogle Scholar
  15. 15.
    X. Lin, Y. Zeng, X. Zhou, and C. Ding, Microstructure of Alumina-3wt.% Titania Coatings by Plasma Spraying with Nanostructured Powders, Mater. Sci. Eng. A, 2003, 357, p 228-234CrossRefGoogle Scholar
  16. 16.
    Y. Zhu, C. Deng, K. Yukimura, and T. Xiao, Deposition and Characterization of Nanostructured WC-Co Coating, Ceram. Int., 2001, 27, p 669-674CrossRefGoogle Scholar
  17. 17.
    S. Cirolini, J.H. Harding, and G. Jacucci, Computer Simulation of Plasma Sprayed Coatings, Surf. Coat. Technol., 1991, 48(2), p 137-145CrossRefGoogle Scholar
  18. 18.
    G.M. Ingo, S. Kaciulis, A. Mezzi, T. Valente, F. Casadei, and G. Gusmano, Characterization of Composite Titanium Nitride Coatings Prepared by Reactive Plasma Spraying, Electrochem. Acta, 2005, 50(23), p 4531-4537CrossRefGoogle Scholar
  19. 19.
    X. Fan et al, Characterization of Ti Coatings Deposited by Very Low-Pressure Plasma Spraying. In: Proc 8th RIPT2017, Limoges, France (2017)Google Scholar

Copyright information

© ASM International 2018

Authors and Affiliations

  • Xiujuan Fan
    • 1
    Email author
  • Geoffrey Darut
    • 1
  • Marie-Pierre Planche
    • 1
  • Xiaohua Feng
    • 2
  • Hanlin Liao
    • 1
  • Ghislain Montavon
    • 1
  1. 1.ICB, UMR 6303, CNRSUniv. Bourgogne Franche-Comté, UTBMBelfortFrance
  2. 2.Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingboPeople’s Republic of China

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