Journal of Thermal Spray Technology

, Volume 21, Issue 1, pp 16–22 | Cite as

SiC Coatings for Carbon/Carbon Composites Fabricated by Vacuum Plasma Spraying Technology

Peer-Reviewed

Abstract

SiC coatings for carbon/carbon (C/C) composites have been prepared by the combination process of vacuum plasma spraying technology and heat treatment. The SiC coatings were formed by the reaction of C/C substrates with as-sprayed silicon coatings deposited by vacuum plasma spraying. The preparation temperature and the thickness of original silicon coatings have great influence on the microstructure and the thickness of the synthesized SiC coatings. The results indicated that a continuous and dense SiC coating has been produced on the surface of C/C substrates. The SiC coatings prepared at 2073 K with the silicon coatings of 230 μm thickness, exhibited a low mass loss of 2.56% in the plasma jet with temperature about 2473 K and duration of 420 s in atmosphere. The present results implied that vacuum plasma spraying technology combined with heat treatment was an acceptable method for synthesis of protective SiC coatings for C/C composites.

Keywords

C/C composites heat treatment plasma spraying technology SiC coatings 

Notes

Acknowledgments

This work was jointly supported by Innovative Foundation of Shanghai University, Shanghai Leading Academic Discipline Project under grant s30107, and the Key Laboratory of Inorganic Coating Materials, Chinese Academy of Sciences. The National Natural Science Foundation of China under grant 51102267, Shanghai Science and Technology R&D Fund under grant 11ZR1442100.

References

  1. 1.
    E. Fitzer, The Future of Carbon-Carbon Composites, Carbon, 1987, 25, p 163-190CrossRefGoogle Scholar
  2. 2.
    J.E. Sheehan, Oxidation Protection for Carbon Fiber Composites, Carbon, 1989, 29, p 709-715CrossRefGoogle Scholar
  3. 3.
    C.A.A. Cairo, M.L.A. Graca, C.R.M. Silva, and J.C. Bressiani, Functionally Gradient Ceramic Coating for Carbon-Carbon Antioxidation Protection, J. Eur. Ceram. Soc., 2001, 21, p 325-329CrossRefGoogle Scholar
  4. 4.
    J.F. Huang, M. Liu, B. Wang, L.Y. Cao, C.K. Xia, and J.P. Wu, SiCn/SiC Oxidation Protective Coating for Carbon/Carbon Composites, Carbon, 2009, 47, p 1198-1201CrossRefGoogle Scholar
  5. 5.
    R. Mevrel, C. Duret, and R. Pichoir, Pack Cementation Processes, Mater. Sci. Technol., 1986, 2, p 201-206Google Scholar
  6. 6.
    K. Kobayashi, K. Madea, H. Sano, and Y. Uchiyama, Formation and Oxidation Resistance of the Coating Formed on Carbon Material Composed of B4C-SiC Powders, Carbon, 1995, 33, p 397-403CrossRefGoogle Scholar
  7. 7.
    J. Li, R.Y. Luo, Y.P. Chen, Q. Xiang, C. Lin, P. Ding, N. An, and J.W. Cheng, Oxidation Behavior and Kinetics of SiC/Alumina-Borosilicate Coating for Carbon-Carbon Composites, Appl. Surf. Sci., 2008, 255, p 1967-1974CrossRefGoogle Scholar
  8. 8.
    T. Aokia, H. Hatta, T. Hitomi, H. Fukuda, and I. Shiota, SiC/C Multi-Layered Coating Contributing to the Antioxidation of C/C Composites and the Suppression of Through-Thickness Cracks in the Layer, Carbon, 2001, 39, p 1477-1483CrossRefGoogle Scholar
  9. 9.
    C. Bartulia, T. Valente, and M. Tului, Plasma Spray Deposition and High Temperature Characterization of ZrB2-SiC Protective Coatings, Surf. Coat. Technol., 2002, 155, p 260-273CrossRefGoogle Scholar
  10. 10.
    M. Tului, G. Marino, and T. Valente, Plasma Spray Deposition of Ultra High Temperature Ceramics, Surf. Coat. Technol., 2006, 201, p 2103-2108CrossRefGoogle Scholar
  11. 11.
    Y. Niu, X. Liu, X. Zheng, H. Ji, and C. Ding, Microstructure and Properties Characterization of Silicon Coatings Prepared by Vacuum Plasma Spraying Technology, J. Therm. Spray Technol., 2009, 18, p 427-434CrossRefGoogle Scholar
  12. 12.
    C. Isola, M. Salvo, M. Ferraris, and M.A. Montorsi, Joining of Surface Modified Carbon/Carbon Composites Using Barium-Aluminium-Borosilicate Glass, J. Eur. Ceram. Soc., 1998, 18, p 1017CrossRefGoogle Scholar
  13. 13.
    G. Kumar and K. Narayan Prabhu, Review of Non-Reactive and Reactive Wetting of Liquids on Surfaces, Adv. Colloid Interface Sci., 2007, 133, p 61-89CrossRefGoogle Scholar
  14. 14.
    S.F. Tang, J.Y. Deng, S.J. Wang, and W.C. Liu, Comparison of Thermal and Ablation Behaviors of C/SiC Composites and C/ZrB2-SiC Composites, Corros. Sci., 2009, 51, p 54-61CrossRefGoogle Scholar
  15. 15.
    J.C. Margiotta, D. Zhang, and D.C. Nagle, Microstructural Evolution During Silicon Carbide (SiC) Formation by Liquid Silicon Infiltration Using Optical Microscopy, Int. J. Refract. Met. Hard Mater., 2010, 28, p 191-197CrossRefGoogle Scholar
  16. 16.
    J. Han, P. Hu, X. Zhang, S. Meng, and W. Han, Oxidation-Resistant ZrB2-SiC Composites at 2200 °C, Compos. Sci. Technol., 2008, 68, p 799-806CrossRefGoogle Scholar
  17. 17.
    J.F. Huang, X.R. Zeng, H.J. Li, X.B. Xiong, and Y.W. Fu, Influence of the Preparation Temperature on the Phase, Microstructure and Anti-Oxidation Property of a SiC Coating for C/C Composites, Carbon, 2004, 42, p 1517-1521CrossRefGoogle Scholar
  18. 18.
    C. Tang and J. Guan, Improvement in Oxidation Resistance of the Nuclear Graphite by Reaction-Coated SiC Coating, J. Nucl. Mater., 1995, 224, p 103-108CrossRefGoogle Scholar
  19. 19.
    Y.R. Niu, X.B. Zheng, C.X. Ding, H. Li, C. Hu, M.S. Ren, and J.L. Sun, Microstructure Characteristics of Silicon Carbide Coatings Fabricated on C/C Composites by Plasma Spraying Technology, Ceram. Int., 2011, 37, p 1675-1680CrossRefGoogle Scholar
  20. 20.
    N.S. Jacobson, D.J. Roth, R.W. Rauser, J.D. Cawley, and D.M. Curry, Oxidation Through Coating Cracks of SiC-Protected Carbon/Carbon, Surf. Coat. Technol., 2008, 203, p 372-383CrossRefGoogle Scholar
  21. 21.
    Q.G. Fu, H.J. Li, Y.J. Wang, K.Z. Li, and H. Wu, A Si-SiC Oxidation Protective Coating for Carbon/Carbon Composites Prepared by a Two-Step Pack Cementation, Ceram. Int., 2009, 35, p 2525-2529CrossRefGoogle Scholar

Copyright information

© ASM International 2011

Authors and Affiliations

  1. 1.School of Material Science and EngineeringShanghai UniversityShanghaiChina
  2. 2.Key Laboratory of Inorganic Coating MaterialsShanghai Institute of Ceramics, Chinese Academy of SciencesShanghaiChina

Personalised recommendations