In this work, an Al/CuO energetic film with a porous hollow structure was obtained by electrophoretic deposition (EPD) from an aqueous solution at low field strengths of 20 V cm−2 instead of from organic solvents. CuO porous hollow microspheres (PHMSs) were prepared by a one-step hydrothermal method. The shape of the CuO PHMSs was very uniform at the macroscale with a size of 5 μm. To codeposit the species during the EPD process, the nano-Al particles and CuO PHMSs were modified with acrylic acid and citric acid, respectively. The nano-Al particles were deposited on the surface or in the interior of the CuO PHMSs by an electrical field and formed Al/CuO PHMS composites. The chemical composition, morphology, heat release and combustion of the as-prepared composite coating films were analyzed by XRD, FESEM, FT-IR, EDS, TG-DSC and with a high-speed camera. The heat release of the Al/CuO porous thermite reached 3804 J/g with excellent combustion performance due to the novel microstructure and appropriate modifications.
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C. Rossi, Two Decades of Research on Nano-Energetic Materials, Propellants Explos. Pyrotech., 2014, 39, p 323–327
P. Sarkar and P.S. Nicholson, Electrophoretic Deposition(EPD): Mechanisms, Kinetics, and Application to Ceramics, J. Am. Ceram. Soc., 1996, 79, p 1987–2002
K. Wu, P. Imin, Y.C. Sun, X. Pang, A. Adronov, and I. Zhitomirsky, Electrophoretic Deposition of Composite Films from Solutions of Conjugated Polymers and Their Supramolecular Complexes with Carbon Nanotubes, Mater. Lett., 2012, 67, p 248–251
S. Santhanagopalan, A. Balram, and D.D. Meng, Scalable High-Power Redox Capacitors with Aligned Nano Forests of Crystalline MnO2 Nanorods by High Voltage Electrophoretic Deposition, ACS Nano, 2013, 3, p 2114–2125
L.V. Kovalev, M.V. Yarmolich, M.L. Petrova, J. Ustarroz, H.A. Terryn, N.A. Kalanda, and M.L. Zheludkevich, Double Perovskite Sr2FeMoO6 Films Prepared by Electrophoretic Deposition, ACS Appl. Mater. Interfaces, 2014, 6, p 19201–19206
Y.S. Liu, K.Y. Shi, and I. Zhitomirsky, Azopolymer Triggered Electrophoretic Deposition of MnO2-Carbon Nanotube Composites and Polypyrrole Coated Carbon Nanotubes for Supercapacitors, J. Mater. Chem. A, 2015, 3, p 16486–16494
K.T. Sullivan, M.A. Worsley, J.D. Kuntz, and A.E. Gash, Electrophoretic Deposition of Binary Energetic Composites, Combust. Flame, 2012, 159, p 2210–2218
H.S. Maharana, S. Lakra, and S.P. Basu, Electrophoretic Deposition of Cu-SiO2 Coatings by DC and Pulsed DC for Enhanced Surface-Mechanical Properties, J. Mater. Eng. Perform., 2016, 25, p 327–337
K.Y. Hui, M. Dao, Y. Han, and L.F. Cheng, Strengthening of C/SiC Composites by Electrophoretic Deposition of CNTs on a SiC Coating, J. Mater. Eng. Perform., 2018, 27, p 5762–5768
D.X. Zhou, G. Jian, Y.X. Hu, Y.N. Zheng, S.P. Gong, and H. Liu, Electrophoretic Deposition of Multiferroic BaTiO3/CoFe2O4 Bilayer Films, Mater. Chem. Phys., 2011, 127, p 316–321
Z.M. Al-Rashidy, M.M. Farag, N.A. Abdel Ghany, A.M. Ibrahim, and W. Abdel-Fattah, Aqueous Electrophoretic Deposition and Corrosion Protection of Borate Glass Coatings on 316L Stainless Steel for Hard Tissue Fixation, Surf. Interfaces, 2017, 7, p 125–133
A. Hajizadeh, M. Aliofkhazraei, M. Hasanpoor, and E. Mohammadi, Comparison of Electrophoretic Deposition Kinetics of Graphene Oxide Nanosheets in Organic and Aqueous Solutions, Ceram. Int., 2018, 44, p 10951–10960
S. Yokoyama, I. Suzuki, K. Motomiya, H. Takahashi, and K. Tohji, Aqueous Electrophoretic Deposition of Citric-Acid-Stabilized Copper Nanoparticles, Colloids Surf. A, 2018, 545, p 93–100
T.R. Sippel, S.F. Son, and L.J. Groven, Altering Reactivity of Aluminum with Selective Inclusion of Polytetrafluoroethylene through Mechanical Activation, Propellants Explos. Pyrotech., 2013, 38, p 286–295
K.W. Watson, M.L. Pantoya, and V.I. Levitas, Fast Reactions with Nano- and Micrometer Aluminum: A Study on Oxidation vs. Fluorination, Combust. Flame, 2008, 155, p 619–634
K.S. Kappagantula, C. Farley, M.L. Pantoya, and J. Horn, Tuning Energetic Material Reactivity Using Surface Functionalization of Aluminum Fuels, J. Phys. Chem. C, 2012, 116, p 24469–24475
R.J. Jouet, A. Warren, D.M. Rosenberg, V.J. Bellito, K. Park, and M. Zachariah, Surface Passivation of Bare Aluminum Nanoparticles Using Perfluoroalkyl Carboxylic Acids, Chem. Mater., 2005, 17, p 2987–2996
S. Valliappan, J. Swiatkiewicz, and J. Puszynski, Reactivity of Aluminum Nanopowders with Melt Oxides, Powder Technol., 2005, 156, p 164–169
J. Wang, A. Hu, and J. Persic, Thermal Stability and Reaction Properties of Passivated Al/CuO Nano-Thermite, J. Phys. Chem. Solids, 2011, 72, p 620–625
E. Weil, Fire-Protective and Flame-Retardant Coatings—A State of the Art Review, J. Fire Sci., 2011, 29, p 259–296
J. Xu, X. Yao, W.Y. Wei, Z.M. Wang, and R.B. Yu, Multi-shelled Copper Oxide Hollow Spheres and Their Gas Sensing Properties, Mater. Res. Bull., 2017, 87, p 214–218
C. Zhang, L.W. Yin, L.Y. Zhang, Y.X. Qi, and N. Lun, Preparation and Photocatalytic Activity of Hollow ZnO and ZnO-CuO Composite Spheres, Mater. Lett., 2012, 67, p 303–307
M.M. Ahmadpour, A. Mosavi, N. Alharbi, and N.E. Gorji, Modeling the Time-Dependent Characteristics of Perovskite Solar Cells, Sol. Energy, 2018, 170, p 969–973
B. Mtiller, M. Shalid, and G. Kinet, Nitro-and Aminophenols as Corrosion Inhibitors for Aluminium and Zinc Pigments, Corros. Sci., 1999, 41, p 1323–1331
B. Müller, Polymeric Corrosion Inhibitors for Aluminium Pigment, React. Funct. Polym., 1999, 39, p 165–177
G.B. Sun, L.N. Sun, and H. Wen, From Layered Double Hydroxide to Spinel Nanostructure: Facile Synthesis and Characterization of Nanoplatelets and Nanorods, J. Phys. Chem. B, 2006, 110, p 13375–13380
M.H. Looi, S.T. Lee, and S.B. Abd-Hamid, Use of CA in Synthesizing a Highly Dispersed Copper Catalyst for Selective Hydrogenolysis, Chin. J. Catal., 2008, 29, p 566–570
Y.K. Cho, K.Y. Jung, H. Lee, and S. Heo, Synthesis and Characterization of C/Cu Core-Shell Particles by Hydrogen-Free Spray Pyrolysis Assisted with CA and Sucrose, Mater. Res. Bull., 2013, 9, p 3424–3430
M.M. Tunesi, R.A. Soomro, and R. Ozturk, CuO Nanostructures for Highly Sensitive Shape Dependent Electrocatalytic Oxidation of N-acetyl-l-cysteine, J. Electroanal. Chem., 2016, 15, p 40–47
A.C. Pierre and K. Ma, Sedimentat Ion Behaviour of Kaolinite and Montmorillonite Mixed with Iron Additives, as a Function of Their Zeta Potential, Mat. Sci., 1997, 32, p 2937–2947
D.A. Mahrouqi, J. Vinogradov, and M.D. Jackson, Zeta Potential of Artificial and Natural Calcite in Aqueous Solution, Adv. Colloid Interface, 2017, 240, p 60–76
K.L. Zhang, C. Rossia, and G.A.A. Rodriguez, Development of a Nano-Al/CuO Based Energetic Material on Silicon Substrate, Appl. Phys. Lett., 2007, 91, p p113117
S. Nigam, K.C. Barick, and D. Badahur, Development of Citrate-Stabilized Fe2O3 Nanoparticles: Conjugation and Release of Doxorubicin for Therapeutic Application, J. Magn. Magn. Mater., 2011, 323, p 237–243
This work was funded by the National Natural Science Foundation of China (Nos. 21905032 and 61271059), the Natural Science Foundation Project of Chongqing (No. 2010BB4246), the Science and Technology Development Project of Chongqing (No. CSTC2012ggyyjs90007) and Chongqing Graduate Scientific Research Innovation Project (No. CXB14220).
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Yin, Y., Li, X. Electrophoretic Deposition and Characterization of an Al/CuO Energetic Film with a Porous Hollow Microsphere Structure. J. of Materi Eng and Perform (2020). https://doi.org/10.1007/s11665-020-04631-1
- CuO porous hollow microsphere
- electrophoretic deposition (EPD)
- surface modification