High-Temperature Tribological Performance of Vacuum Hot-Pressed NiCr Matrix Composite Containing SrAl12O19

  • Feng LiuEmail author
  • Le Feng
  • Hongdou Liu
  • Wenwen Zhao


The tribological properties of NiCr-30 wt.% Al2O3 (denoted by NC30A) composite with 4 wt.% SrCO3 were investigated at different testing temperatures. The results indicated that the formation of SrAl12O19, which was derived from the solid-state reaction between SrO and Al2O3 in the sintering process had an impact on the friction coefficient and wear rate of NC30A composite. In the temperature range from 200 to 800 °C, the tribofilm containing SrAl12O19 and oxides (NiO, Cr2O3 and NiCr2O4) led to a decrease in the friction coefficient, while the detachment of Al2O3 grains and the oxidation of Ni on the worn surface endowed the sintered composite with a slightly higher wear rate.


elevated temperature SrAl12O19 tribological properties wear mechanism 



The authors acknowledge the financial supports by the National Natural Science Foundation of China (Grant No. 51505378) and the Natural Science Basic Research Plan in Shaanxi Province of China (Program No. 2017JM5101).


  1. 1.
    X. Feng, C. Lu, J. Jia, J. Xue, Q. Wang, Y. Sun, W. Wang, and G. Yi, High Temperature Tribological Behaviors and Wear Mechanisms of NiAl-NbC-Ag Composites Formed by In Situ Decomposition of AgNbO3, Tribol Int., 2020, 141, p 105898CrossRefGoogle Scholar
  2. 2.
    M. Kotkowiak, A. Piasecki, and M. Kulka, The Influence of Solid Lubricant on Tribological Properties of Sintered Ni-20%CaF2 Composite Material, Ceram. Int., 2019, 45, p 17103–17113CrossRefGoogle Scholar
  3. 3.
    T.R. Prabhu, M. Arivarasu, Y. Chodancar, N. Arivazhagan, G. Sumanth, and R.K. Mishra, Tribological Behaviour of Graphite-Reinforced FeNiCrCuMo High-Entropy Alloy Self-Lubricating Composites for Aircraft Braking Energy Applications, Tribol. Lett., 2019, 67, p 78CrossRefGoogle Scholar
  4. 4.
    K.P. Furlan, J.D.B. de Mello, and A.N. Klein, Self-Lubricating Composites Containing MoS2: A Review, Tribol. Int., 2018, 120, p 280–298CrossRefGoogle Scholar
  5. 5.
    Q. Bi, S. Zhu, W. Liu, High Temperature Self-Lubricating Materials, Tribology in Engineering, H. Pihtili, Ed., InTech, Rijeka, 2013, pp Ch. 07Google Scholar
  6. 6.
    S. Cao, J. Zhou, L. Wang, Y. Yu, and B. Xin, Microstructure, Mechanical and Tribological Property of Multi-components Synergistic Self-Lubricating NiCoCrAl Matrix Composite, Tribol. Int., 2019, 131, p 508–519CrossRefGoogle Scholar
  7. 7.
    F. Liu, G.W. Yi, W.Z. Wang, Y. Shan, and J.H. Jia, Tribological Properties of NiCr-Al2O3 Cermet-Based Composites with Addition of Multiple-Lubricants at Elevated Temperatures, Tribol. Int., 2013, 67, p 164–173CrossRefGoogle Scholar
  8. 8.
    H. Heshmat, P. Hryniewicz, J.F. Walton Ii, J.P. Willis, S. Jahanmir, and C. DellaCorte, Low-Friction Wear-Resistant Coatings for High-Temperature Foil Bearings, Tribol. Int., 2005, 38, p 1059–1075CrossRefGoogle Scholar
  9. 9.
    J.L. Li, D.S. Xiong, and M.F. Huo, Friction and Wear Properties of Ni-Cr-W-Al-Ti-MoS2 at Elevated Temperatures and Self-Consumption Phenomena, Wear, 2008, 265, p 566–575CrossRefGoogle Scholar
  10. 10.
    J.L. Li and D.S. Xiong, Tribological Properties of Nickel-Based Self-Lubricating Composite at Elevated Temperature and Counterface Material Selection, Wear, 2008, 265, p 533–539CrossRefGoogle Scholar
  11. 11.
    A.A. Voevodin, C. Muratore, and S.M. Aouadi, Hard Coatings with High Temperature Adaptive Lubrication and Contact Thermal Management: Review, Surf. Coat. Technol., 2014, 257, p 247–265CrossRefGoogle Scholar
  12. 12.
    S.M. Aouadi, H. Gao, A. Martini, T.W. Scharf, and C. Muratore, Lubricious Oxide Coatings for Extreme Temperature Applications: A Review, Surf. Coat. Technol., 2014, 257, p 266–277CrossRefGoogle Scholar
  13. 13.
    F. Li, J. Cheng, Z. Qiao, J. Ma, S. Zhu, L. Fu, J. Yang, and W. Liu, A Nickel-Alloy-Based High-Temperature Self-Lubricating Composite with Simultaneously Superior Lubricity and High Strength, Tribol. Lett., 2013, 49, p 573–577CrossRefGoogle Scholar
  14. 14.
    C.H. Ding, C.H. Liu, Z.M. Yang, Y.P. Wang, Z.B. Sun, and L. Yu, Effect of Size Refinement and Distribution of Lubricants on Friction Coefficient of High Temperature Self-Lubricating Composites, Compos. Sci. Technol., 2010, 70, p 1000–1005CrossRefGoogle Scholar
  15. 15.
    R.K.S. Gautam, U.S. Rao, and R. Tyagi, High Temperature Tribological Properties of Ni-Based Self-Lubricating Coatings Deposited by Atmospheric Plasma Spray, Surf. Coat. Technol., 2019, 372, p 390–398CrossRefGoogle Scholar
  16. 16.
    T. Zhang, C. Huang, H. Lan, L. Du, and W. Zhang, Tribological Properties and Lubrication Mechanisms of a Ag–Mo Composite, Lubr. Sci., 2016, 28, p 141–156CrossRefGoogle Scholar
  17. 17.
    H. Zhong, X. Feng, J. Jia, and G. Yi, Tribological Characteristics and Wear Mechanisms of NiMoAl Composite Coatings in Reversible Temperature Cycles from RT to 900 °C, Tribol. Int., 2017, 114, p 48–56CrossRefGoogle Scholar
  18. 18.
    J. Wang, Y. Shan, H. Guo, B. Li, W. Wang, and J. Jia, Friction and Wear Characteristics of Hot-Pressed NiCr–Mo/MoO3/Ag Self-Lubrication Composites at Elevated Temperatures up to 900° C, Tribol. Lett., 2015, 59, p 48CrossRefGoogle Scholar
  19. 19.
    A.V. Bondarev, P.V. Kiryukhantsev-Korneev, D.A. Sidorenko, and D.V. Shtansky, A New Insight into Hard Low Friction MoCN–Ag Coatings Intended for Applications in Wide Temperature Range, Mater. Des., 2016, 93, p 63–72CrossRefGoogle Scholar
  20. 20.
    Z. Xu, Q. Zhang, and W. Zhai, Tribological Properties of TiAl Matrix Self-Lubricating Composites Incorporated with Tungsten Disulfide and Zinc Oxide, RSC Adv., 2015, 5, p 45044–45052CrossRefGoogle Scholar
  21. 21.
    S. Zhu, Q. Bi, J. Yang, and W. Liu, Ni3Al Matrix Composite with Lubricious Tungstate at High Temperatures, Tribol. Lett., 2012, 45, p 251–255CrossRefGoogle Scholar
  22. 22.
    D. Stone, J. Liu, D.P. Singh, C. Muratore, A.A. Voevodin, S. Mishra, C. Rebholz, Q. Ge, and S.M. Aouadi, Layered Atomic Structures of Double Oxides for Low Shear Strength at High Temperatures, Scr. Mater., 2010, 62, p 735–738CrossRefGoogle Scholar
  23. 23.
    S. Zhu, H. Tan, J. Cheng, Y. Yu, Z. Qiao, and J. Yang, Nickel Aluminum Matrix Solid-Lubricating Composite Lubricated by Silver and Silver Vanadate Formed by Tribochemistry at Elevated Temperature, J. Tribol., 2019, 141, p 031302CrossRefGoogle Scholar
  24. 24.
    S.M. Aouadi, D.P. Singh, D.S. Stone, K. Polychronopoulou, F. Nahif, C. Rebholz, C. Muratore, and A.A. Voevodin, Adaptive VN/Ag Nanocomposite Coatings with Lubricious Behavior from 25 to 1000° C, Acta Mater., 2010, 58, p 5326–5331CrossRefGoogle Scholar
  25. 25.
    H. Guo, M. Han, W. Chen, C. Lu, B. Li, W. Wang, and J. Jia, Microstructure and Properties of VN/Ag Composite Films with Various Silver Content, Vacuum, 2017, 137, p 97–103CrossRefGoogle Scholar
  26. 26.
    B. Xin, Y. Yu, J. Zhou, L. Wang, S. Ren, and Z. Li, Effect of Silver Vanadate on the Lubricating Properties of NiCrAlY Laser Cladding Coating at Elevated Temperatures, Surf. Coat. Technol., 2016, 307, p 136–145CrossRefGoogle Scholar
  27. 27.
    J. Li, J. Wang, A. Kumar, H. Li, and D. Xiong, High Temperatures Tribological Properties of Ta-Ag Films Deposited at Various Working Pressures and Sputtering Powers, Surf. Coat. Technol., 2018, 349, p 186–197CrossRefGoogle Scholar
  28. 28.
    D.S. Stone, H. Gao, C. Chantharangsi, C. Paksunchai, M. Bischof, A. Martini, and S.M. Aouadi, Reconstruction Mechanisms of Tantalum Oxide Coatings with Low Concentrations of Silver for High Temperature Tribological Applications, Appl. Phys. Lett. (USA), 2014, 105, p 191607CrossRefGoogle Scholar
  29. 29.
    H. Gao, A. Otero-de-la-Roza, S.M. Aouadi, A. Martini, and E.R. Johnson, Chemical Basis of the Tribological Properties of AgTaO3 Crystal Surfaces, J. Phys. Chem. C, 2014, 118, p 17577–17584CrossRefGoogle Scholar
  30. 30.
    D.S. Stone, H. Gao, C. Chantharangsi, C. Paksunchai, M. Bischof, D. Jaeger, A. Martini, T.W. Scharf, and S.M. Aouadi, Load-Dependent High Temperature Tribological Properties of Silver Tantalate Coatings, Surf. Coat. Technol., 2014, 244, p 37–44CrossRefGoogle Scholar
  31. 31.
    D.S. Stone, S. Harbin, H. Mohseni, J.E. Mogonye, T.W. Scharf, C. Muratore, A.A. Voevodin, A. Martini, and S.M. Aouadi, Lubricious Silver Tantalate Films for Extreme Temperature Applications, Surf. Coat. Technol., 2013, 217, p 140–146CrossRefGoogle Scholar
  32. 32.
    F. Liu and J.H. Jia, Tribological Properties and Wear Mechanisms of NiCr-Al2O3-SrSO4-Ag Self-Lubricating Composites at Elevated Temperatures, Tribol. Lett., 2013, 49, p 281–290CrossRefGoogle Scholar
  33. 33.
    F. Liu, G. Yi, W. Wang, Y. Shan, and J. Jia, The Influence of SrSO4 on the Tribological Properties of NiCr-Al2O3 Cermet at Elevated Temperatures, Ceram. Int., 2014, 40, p 2799–2807CrossRefGoogle Scholar
  34. 34.
    F. Liu, Y. Zhou, X. Zhang, W. Cao, and J. Jia, Tribological Properties of NiCr-ZrO2(Y2O3)-SrSO4 Composites at Elevated Temperatures, Ceram. Int., 2016, 42, p 12981–12987CrossRefGoogle Scholar
  35. 35.
    Y. Xu, W. Peng, S. Wang, X. Xiang, and P. Lu, Synthesis of SrAl12O19 via Citric Acid Precursor, Mater. Sci. Eng. B, 2005, 123, p 139–142CrossRefGoogle Scholar
  36. 36.
    M. Bukhtiyarova, A. Ivanova, E. Slavinskaya, P. Kuznetsov, L. Plyasova, O. Stonkus, V. Rogov, V. Kaichev, and A. Noskov, Steam Reforming of Methane over Ni-Substituted Sr Hexaaluminates, Catal. Sustai. Energy, 2012, 1, p 11–21Google Scholar
  37. 37.
    Z. Xu, M. Zhen, Y. Bi, and K. Zhen, Carbon Dioxide Reforming of Methane to Synthesis Gas over Hexaaluminate ANiAl11O19-delta (A = Ca, Sr, Ba and La) Catalysts, Catal. Lett., 2000, 64, p 157–161CrossRefGoogle Scholar
  38. 38.
    V. Malinovschi, A. Marin, D. Negrea, V. Andrei, E. Coaca, C.N. Mihailescu, and C.P. Lungu, Characterization of Al2O3/ZrO2 Composite Coatings Deposited on Zr-2.5Nb Alloy by Plasma Electrolytic Oxidation, Appl. Surf. Sci., 2018, 451, p 169–179CrossRefGoogle Scholar
  39. 39.
    J. Chastain, Handbook of X-ray Photoelectron Spectroscopy, Perkin-Elmer Corporation, Eden Prairie, 1992Google Scholar

Copyright information

© ASM International 2020

Authors and Affiliations

  1. 1.School of Materials Science and EngineeringXi’an Shiyou UniversityXi’anPeople’s Republic of China

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