Dry Sliding Wear Behavior and Mechanism of a Hot-Dip Aluminized Steel as a Function of Sliding Velocity

  • Yubiao Yang
  • Benguo Zhang
  • Wei Jiang
  • Shuqi WangEmail author


Fe-Al intermetallic coatings were prepared on AISI 1045 steel by hot-dip aluminizing and subsequent high-temperature diffusion. The dry sliding wear tests were performed for the aluminized steel with various substrate hardnesses in the velocity range of 0.75-4 m/s on a pin-on-disk configuration. The dry sliding wear behavior and mechanisms of the aluminized steel under various velocities were explored. It was found that the wear rate decreased substantially with an increase in sliding velocity from 0.75 to 1.5 and then slightly varied in the velocity range of 1.5-4 m/s. The wear behavior and mechanisms of the aluminized steel were noticed to be closely related with tribo-layers. As tribo-layers contained more oxides with Fe2O3, the wear resistance of the aluminized steel was markedly improved because of their protective function. The substrate hardness also changed the wear behavior of the aluminized steel by affecting the stability of tribo-layers because the substrate hardness was inversely proportional to the thermal stability of the substrate structure. Under a low velocity of 0.75 m/s, adhesive wear and abrasive wear prevailed owing to the metal-on-metal contact, resulting in a higher wear rate. At 1.5-4 m/s, mild oxidative wear prevailed due to the stable existence of tribo-oxides layers. However, at 1.5 and 4 m/s for the substrate hardness of 45 HRC, the wear rate was slightly increased because the protection of tribo-layers was weakened by a double-layered structure or more cracks in tribo-layers and coatings.


dry sliding hot-dip aluminized steel tribo-layer wear behavior wear mechanism 



The authors were grateful for the support from National Natural Science Foundation of China (No. 51071078), Prospective Joint Research Project of Jiangsu Province (No. BY2016072-04) and Natural Science Foundation of Jiangsu (No. BK20150429).


  1. 1.
    J.P. Tu and M.S. Liu, Wet Abrasive Wear of Ordered Fe3Al Alloys, Wear, 1997, 209, p 31–36CrossRefGoogle Scholar
  2. 2.
    S.M. Zhu, X.S. Guan, K. Shibata, and K. Iwasaki, Microstructure and Mechanical and Tribological Properties of High Carbon Fe3Al and FeAl Intermetallic Alloys, Mater. Trans., 2002, 43, p 36–41CrossRefGoogle Scholar
  3. 3.
    C.J. Li, H.T. Wang, G.J. Yang, and C.G. Bao, Characterization of High-Temperature Abrasive Wear of Cold-Sprayed FeAl Intermetallic Compound Coating, J. Therm. Spray Technol., 2011, 20, p 227–233CrossRefGoogle Scholar
  4. 4.
    N. Cinca, S. Cygan, C. Senderowski, L. Jaworska, S. Dosta, I.G. Cano, and J. Guilemany, Sliding Wear Behavior of Fe-Al Coatings at High Temperatures, Coatings, 2018, 8, p 268CrossRefGoogle Scholar
  5. 5.
    I.I. Danzo, K. Verbeken, and Y. Houbaert, Microstructure of Hot Dip Coated Fe-Si Steels, Thin Solid Films, 2011, 520, p 1638–1644CrossRefGoogle Scholar
  6. 6.
    B. Xu, Z. Zhu, S. Ma, W. Zhang, and W. Liu, Sliding Wear Behavior of Fe-Al and Fe-Al/WC Coatings Prepared by High Velocity Arc Spraying, Wear, 2004, 257, p 1089–1095CrossRefGoogle Scholar
  7. 7.
    C. Shen, Z. Pan, Y. Ma, D. Cuiuri, and H. Li, Fabrication of Iron-Rich Fe-Al Intermetallics Using the Wire-Arc Additive Manufacturing Process, Addit. Manuf., 2015, 7, p 20–26CrossRefGoogle Scholar
  8. 8.
    N. Cinca and J.M. Guilemany, Thermal Spraying of Transition Metal Aluminides: An Overview, Intermetallics, 2012, 24, p 60–72CrossRefGoogle Scholar
  9. 9.
    B. Bax, M. Schäfer, C. Pauly, and F. Mücklich, Coating and Prototyping of Single-Phase Iron Aluminide by Laser Cladding, Surf. Coat. Technol., 2013, 235, p 773–777CrossRefGoogle Scholar
  10. 10.
    F. Pougoum, J. Qian, M. Laberge, L. Martinu, J. Klemberg-Sapieha, Z. Zhou, and R. Schulz, Investigation of Fe3Al-Based PVD/HVOF Duplex Coatings to Protect Stainless Steel from Sliding Wear Against Alumina, Surf. Coat. Technol., 2018, 350, p 699–711CrossRefGoogle Scholar
  11. 11.
    Q.Y. Zhang, Y. Zhou, J.Q. Liu, K.M. Chen, J.G. Mo, X.H. Cui, and S.Q. Wang, Comparative Research on Dry Sliding Wear of Hot-Dip Aluminized and Uncoated AISI, H13 Steel, Wear, 2015, 344, p 22–31CrossRefGoogle Scholar
  12. 12.
    X. Zhang, J. Ma, L. Fu, S. Zhu, F. Li, J. Yang, and W. Liu, High Temperature Wear Resistance of Fe-28Al-5Cr Alloy and Its Composites Reinforced by TiC, Tribol. Int., 2013, 61, p 48–55CrossRefGoogle Scholar
  13. 13.
    C.T. Liu, E.P. George, P.J. Maziasz, and J.H. Schneibel, Recent Advances in B2 Iron Aluminide Alloys: Deformation, Fracture and Alloy Design, Mater. Sci. Eng. A, 1998, 258, p 84–98CrossRefGoogle Scholar
  14. 14.
    J. Yang, P. La, W. Liu, and Q. Xue, Tribological Properties of FeAl intermetallics Under Dry Sliding, Wear, 2004, 257, p 104–109CrossRefGoogle Scholar
  15. 15.
    J. Wang, J. Xing, L. Cao, W. Su, and Y. Gao, Dry Sliding Wear Behavior of Fe3Al Alloys Prepared by Mechanical Alloying and Plasma Activated Sintering, Wear, 2010, 268, p 473–480CrossRefGoogle Scholar
  16. 16.
    S.Q. Wang, M.X. Wei, and Y.T. Zhao, Effects of the Tribo-Oxide and Matrix on Dry Sliding Wear Characteristics and Mechanisms of a Cast Steel, Wear, 2010, 269, p 424–434CrossRefGoogle Scholar
  17. 17.
    M.X. Wei, S.Q. Wang, L. Wang, X.H. Cui, and K.M. Chen, Effect of Tempering Conditions on Wear Resistance in Various Wear Mechanisms of H13 Steel, Tribol. Int., 2011, 44(7), p 898–905CrossRefGoogle Scholar
  18. 18.
    M.X. Wei, K.M. Chen, S.Q. Wang, and X.H. Cui, Analysis for Wear Behaviors of Oxidative Wear, Tribol. Lett., 2011, 42, p 1–7CrossRefGoogle Scholar
  19. 19.
    S.Q. Wang, M.X. Wei, F. Wang, X.H. Cui, and K.M. Chen, Effect of Morphology of Oxide Scale on Oxidation Wear in Hot Working Die Steels, Mater. Sci. Eng., 2009, 505A, p 20–26CrossRefGoogle Scholar
  20. 20.
    M.X. Wei, S.Q. Wang, Y.T. Zhao, and F. Wang, Effects of the Ambient Temperature and Load on the Wear Performances and Mechanisms of H13 Steel, Metall. Mater. Trans. A, 2011, 42, p 3106–3114CrossRefGoogle Scholar
  21. 21.
    Q.Y. Zhang, K.M. Chen, L. Wang, X.H. Cui, and S.Q. Wang, Characteristics of Oxidative Wear and Oxidative Mild Wear, Tribol. Int., 2013, 61, p 214–223CrossRefGoogle Scholar
  22. 22.
    X.H. Cui, S.Q. Wang, F. Wang, and K.M. Chen, Research on Oxidation Wear Mechanism of the Cast Steels, Wear, 2008, 265, p 468–476CrossRefGoogle Scholar
  23. 23.
    Y. Wang, T. Lei, and J. Liu, Tribo-Metallographic Behavior of High Carbon Steels in Dry Sliding: III. Dynamic Microstructural Changes and Wear, Wear, 1999, 231, p 20–37CrossRefGoogle Scholar
  24. 24.
    K.M. Lee and A.A. Polycarpou, Wear of Conventional Pearlitic and Improved Bainitic Rail Steels, Wear, 2005, 259, p 391–399CrossRefGoogle Scholar
  25. 25.
    M. Godet, The Third-Body Approach: A Mechanical View of Wear, Wear, 1984, 100, p 437–452CrossRefGoogle Scholar
  26. 26.
    Z. Baccouch, R. Mnif, R. Elleuch, and C. Richard, The Effect of Tribolayers on the Behavior Friction of X40CrMoV5/Fe360B Steel Couple in an Open Sliding Contact, J. Mater. Res., 2017, 3, p 1–7Google Scholar
  27. 27.
    M. Alemani, S. Gialanella, G. Straffelini, R. Ciudin, U. Olofsson, G. Perricone, and I. Metinoz, Dry Sliding of a Low Steel Friction Material Against Cast Iron at Different Loads: Characterization of the Friction Layer and Wear Debris, Wear, 2017, 376, p 1450–1459CrossRefGoogle Scholar
  28. 28.
    S.K. Rhee, M.G. Jacko, and P.H.S. Tsang, Wear Debris Compaction and Friction Film Formation of Polymer Composites, Wear, 1989, 133, p 23–38CrossRefGoogle Scholar
  29. 29.
    T.F.J. Quinn, J.L. Sullivan, and D.M. Rowson, Origins and Development of Oxidational Wear at Low Ambient Temperatures, Wear, 1984, 94, p 175–191CrossRefGoogle Scholar
  30. 30.
    J.E. Wilson, F.H. Stott, and G.C. Wood, The Development of Wear-Protective Oxides and Their Influence on Sliding Friction, Proc. R. Soc. Lond. A, 1980, 369, p 557–574CrossRefGoogle Scholar
  31. 31.
    A. Pauschitz, M. Roy, and F. Franek, On the Chemical Composition of the Layers Formed During Sliding of Metallic Alloys at High Temperature, Tribologia, 2003, 2, p 127–143Google Scholar
  32. 32.
    A. Pauschitz, M. Roy, and F. Franek, Mechanisms of Sliding Wear of Metals and Alloys at Elevated Temperatures, Tribol. Int., 2008, 41, p 584–602CrossRefGoogle Scholar
  33. 33.
    V. Leskovšek, B. Šuštaršič, and G. Jutriša, The Influence of Austenitizing and Tempering Temperature on the Hardness and Fracture Toughness of Hot-Worked H11 Tool Steel, J. Mater. Process. Technol., 2006, 178, p 328–334CrossRefGoogle Scholar

Copyright information

© ASM International 2019

Authors and Affiliations

  • Yubiao Yang
    • 1
  • Benguo Zhang
    • 2
  • Wei Jiang
    • 1
  • Shuqi Wang
    • 1
    Email author
  1. 1.School of Material Science and EngineeringJiangsu UniversityZhenjiangChina
  2. 2.School of Mechanical EngineeringYancheng Institute of TechnologyYanchengChina

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