Skip to main content

Advertisement

Log in

Densification, Microstructural Evolution, Mechanical Properties and Oxidation Study of CrB2 + EuB6 Composite

  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

This paper reports the results of investigation on densification, microstructural evolution, mechanical properties and oxidation study of CrB2 + EuB6 composite. CrB2 + EuB6 (10 and 20 wt.%) composites have been fabricated by hot pressing at a temperature of 1700 °C and 35 MPa pressure. The hardness and flexural strength were measured in the range of 21.25-24.48 GPa and 171-199 MPa, respectively. The fracture toughness increased from 3.3 to 4.01 MPa m1/2 by the addition of 20% EuB6. Microstructural evolution revealed the uniform distribution of EuB6 and absence of any reaction product. Fracture surface analysis confirmed the presence of transgranular mode of fracture. Oxidation study at 1200 °C revealed that the developed composites have good oxidation resistance and followed the parabolic rate of oxidation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  1. M.L. Bauccio, ASM Engineered Materials Reference Book, ASM International, Russell Township, 1994

    Google Scholar 

  2. J.K. Sonber, T.S.R.Ch. Murthy, C. Subramanian, S. Kumar, R.K. Fotedar, and A.K. Suri, Investigation on Synthesis, Pressureless Sintering and Hot Pressing of Chromium Diboride, Int. J. Refract. Met. Hard Mater., 2009, 27, p 912–918

    Article  Google Scholar 

  3. L.R. Jordan, A.J. Betts, K.L. Dahm, P.A. Dearnley, and G.A. Wright, Corrosion and Passivation Mechanism of Chromium Diboride Coatings on Stainless Steel, Corros. Sci., 2005, 47, p 1085–1096

    Article  Google Scholar 

  4. S. Marka, A.K. Menaka, and M.G.Krishna Ganguli, Effect of Substrate and Film Thickness on the Growth, Structure, Mechanical and Optical Properties of Chromium Diboride Thin Films, Surf. Coat. Technol., 2012, 209, p 23–31

    Article  Google Scholar 

  5. M. Jha, S. Marka, M.G. Krishna, and A.K. Ganguli, Multifunctional Nanocrystalline Chromium Boride Thin Films, Mater. Lett., 2012, 73, p 220–222

    Article  Google Scholar 

  6. N. Nedfors, D. Primetzhofer, L.P. Wang, J. Lu, L. Hultman, and U. Jansson, Characterization of Magnetron Sputtered Cr-B and Cr-B-C Thin Films for Electrical Contact Application, Surf. Coat. Technol., 2015, 266, p 167–176

    Article  Google Scholar 

  7. A.L. Ivanovskii, Mechanical and Electronic Properties of Diborides of Transition 3d-5d, Metals From First Principles: Toward Search of Novel Ultra-Incompressible and Superhard Materials, Prog. Mater Sci., 2012, 57, p 184–228

    Article  Google Scholar 

  8. X.L. Cui, Y.Y. Wu, T. Gao, and X.F. Liu, Influence of Preparation Temperature on Morphology Evolution and Growth Mechanism of CrB2 in Al-Cr-B alloys, Mater. Lett., 2014, 118, p 176–179

    Article  Google Scholar 

  9. K.L. Dahm, L.R. Jordan, J. Haase, and P.A. Dearnley, Magnetron Sputter Deposition of Chromium Diboride Coatings, Surf. Coat. Technol., 1998, 108–109, p 413–418

    Article  Google Scholar 

  10. P.A. Dearnley, M. Schellewald, and K.L. Dahm, Characterization and Wear Response of Metal Boride Coated WC-Co, Wear, 2005, 259, p 861–869

    Article  Google Scholar 

  11. X. Cui, Y. Wu, T. Gao, C. Li, N. Jinfeng, and X. Liu, In Situ CrB2 and Its Effect on the Mechanical Properties of A390 Alloy, Mater. Charact., 2013, 86, p 296–302

    Article  Google Scholar 

  12. T.S.R.Ch. Murthy, J.K. Sonber, C. Subramanian, R.K. Fotedar, M.R. Gonal, and A.K. Suri, Effect of CrB2 Addition on Densification, Properties and Oxidation Resistance of TiB2, Int. J. Refract. Met. Hard Mater., 2009, 27, p 976–984

    Article  Google Scholar 

  13. R.D. Bedse, J.K. Sonber, K. Sairam, T.S.R.Ch. Murthy, and R.C. Hubli, Processing and Characterization of CrB2 Based Novel Composites, High Temp. Mater. Process. (London), 2015, 34(7), p 683–687

    Google Scholar 

  14. V. Reddy, J.K. Sonber, K. Sairam, T.S.R.Ch. Murthy, S. Kumar, G.V.S. Nageswara Rao, T. Srinivasa Rao, and J.K. Chakravartty, Densification and Mechanical Properties of CrB2 + MoSi2 Based Novel Composites, Ceram. Int., 2015, 41, p 7611–7617

    Article  Google Scholar 

  15. K. Iizumi, D. Maezava, T. Sasaki, and K. Kudaka, Reactive Sintering of CrB2 Via Mechanochemical Processing of Chromium and Boron Powders, J. Jpn. Soc. Powder Powder Metall., 2000, 47(1), p 3–8

    Article  Google Scholar 

  16. J.K. Sonber, T.S.R.Ch. Murthy, K. Sairam, A. Nagraj, R.D. Bedse, K. Singh, S. Majumdar, and V. Kain, Development and Tribological Properties of SiC Fibre Reinforced CrB2 Composite, J. Aust. Ceram. Soc., 2017, https://doi.org/10.1007/s41779-017-0039-5

    Google Scholar 

  17. B. Mahesh, K. Sairam, J.K. Sonber, T.S.R.Ch. Murthy, G.V.S. Nageswara Rao, T. Srinivasa Rao, and J.K. Chakravartty, Sinterability Studies of Monolithic Chromium Diboride (CrB2) by Spark Plasma Sintering, Int. J. Refract. Met. Hard Mater., 2015, 51, p 110–117

    Article  Google Scholar 

  18. K. Sairam, J.K. Sonber, T.S.R.Ch. Murthy, A.K. Sahu, R.D. Bedse, and J.K. Chakravartty, Pressureless Sintering of Chromium Diboride Using Spark Plasma Sintering Facility, Int. J. Refract. Met. Hard Mater., 2016, 58, p 165–171

    Article  Google Scholar 

  19. T.S.R.Ch. Murthy, J.K. Sonber, B. Vishwanadh, A. Nagaraj, K. Sairam, R.D. Bedse, and J.K. Chakravartty, Densification, Characterization and Oxidation Studies of Novel TiB2 + EuB6 Compounds, J. Alloy. Compd., 2016, 670, p 85–95

    Article  Google Scholar 

  20. J.K. Sonber, T.S.R.Ch. Murthy, C. Subramanian, R.C. Hubli, and A.K. Suri, Effect of EuB6 Addition on Densification and Properties of ZrB2, Int. J. Refract. Met. Hard Mater., 2012, 35, p 96–101

    Article  Google Scholar 

  21. T.S.R.Ch. Murthy, J.K. Sonber, C. Subramanian, R.C. Hubli, N. Krishnamurthy, and A.K. Suri, Densification and Oxidation Behavior of a Novel TiB2-MoSi2-CrB2 Composite, Int. J. Refract. Met. Hard Mater., 2013, 36, p 243–253

    Article  Google Scholar 

  22. S. Okada, K. Kudou, K. Iizumi, K. Kudaka, I. Higashi, and T. Lundstrom, Single-Crystal Growth and Properties of CrB, Cr3B4, Cr2B3 and CrB2 From High-Temperature Aluminum Solutions, J. Crystal Growth, 1996, 166, p 429–435

    Article  Google Scholar 

  23. J. Ma, Y. Gu, L. Shi, L. Chen, Z. Yang, and Y. Qian, Reduction-Boronation Route to Chromium Boride (CrB) Nanorods, Chem. Phys. Lett., 2003, 381, p 194–198

    Article  Google Scholar 

  24. L. Qin, X. Zhang, Y. Liang, E. Zhang, H. Gao, and Z. Zhang, Preparation and Characterization of Nanocrystalline Chromium Boride, J. Mater. Sci., 2006, 41, p 7617–7619

    Article  Google Scholar 

  25. M.L. Emiliani, Characterization and Oxidation Resistance of Hot Pressed Chromium Diboride, Mater. Sci. Eng. A, 1993, 172, p 111–124

    Article  Google Scholar 

  26. J.K. Sonber, T.S.R.Ch. Murthy, C. Subramanian, R.C. Hubli, and A.K. Suri, Synthesis, Densification and Characterization of EuB6, Int. J. Refract. Met. Hard Mater., 2013, 38, p 67–72

    Article  Google Scholar 

  27. G.R. Anstis, P. Chantikul, B.R. Lawn, and D.B. Marshall, A Critical Evaluation of Indentation Techniques for Measuring Fracture Toughness: I, Direct Crack Measurements, J. Am. Ceram. Soc., 1981, 64, p 533–538

    Article  Google Scholar 

  28. J. Xu, X. Chen, Y. Zhao, C. Zou, Q. Ding, and J. Jian, Self-Catalyst Growth of EuB6 Nanowires and Nanotubes, J. Cryst. Growth, 2007, 303(2), p 466–471

    Article  Google Scholar 

  29. J.K. Sonber, T.S.R.Ch. Murthy, K. Sairam, and V. Kain, Sintering and Oxidation of GdB4 Synthesized by B4C Reduction Method, J. Korean Ceram. Soc., 2017, 54(2), p 121–127

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to J. K. Sonber.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Raju, K., Sonber, J.K., Murthy, T.S.R.C. et al. Densification, Microstructural Evolution, Mechanical Properties and Oxidation Study of CrB2 + EuB6 Composite. J. of Materi Eng and Perform 27, 2457–2465 (2018). https://doi.org/10.1007/s11665-018-3354-2

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-018-3354-2

Keywords

Navigation