Journal of Materials Engineering and Performance

, Volume 25, Issue 4, pp 1515–1525 | Cite as

NiFe2O4 Spinel Protection Coating for High-Temperature Solid Oxide Fuel Cell Interconnect Application

  • Reza Irankhah
  • Babak Raissi
  • Amir Maghsoudipour
  • Abdullah Irankhah
  • Sasan Ghashghai
Article

Abstract

In the present study, Ni-Fe spinel powder was synthesized via a solid state reaction. In the next step, the electrophoretic deposition (EPD) method was used to apply the NiFe2O4 spinel, as an oxidation-resistant layer, on a commercially available stainless steel (SUS 430) in a potential range of 100 to 300 V. Microscopic studies of the deposited layers showed that crack-free NiFe2O4 films were obtained at 100 V. The coated and uncoated samples were then pre-sintered in air and 5% H2 bal Ar atmospheres at 900 °C for 3 h followed by cyclic oxidation at 800 °C for 500 h. The investigation of the oxidation resistance of the samples using Energy Dispersive Spectroscopy (EDS) revealed that the NiFe2O4 coating acted as an effective barrier against chromium migration into the coating. The oxidation resistance of 5% H2 bal Ar pre-sintered sample was enhanced with an oxidation rate constant (K P) of 8.9 × 10−15 g2 cm−4 s−1.

Keywords

cyclic oxidation electrophoretic deposition NiFe2O4 Spinel SOFC interconnect solid state reaction 

Notes

Acknowledgments

This study has been carried out under the financial support of Iran Renewable Energy Organization.

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Copyright information

© ASM International 2016

Authors and Affiliations

  • Reza Irankhah
    • 1
  • Babak Raissi
    • 1
  • Amir Maghsoudipour
    • 1
  • Abdullah Irankhah
    • 2
  • Sasan Ghashghai
    • 1
  1. 1.Department of CeramicMaterials and Energy Research CenterTehranIran
  2. 2.Hydrogen and Fuel Cell Research Lab, Chemical Engineering DepartmentUniversity of KashanKashanIran

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