Journal of Materials Engineering and Performance

, Volume 25, Issue 1, pp 116–129 | Cite as

Study on the Tribological Behaviors of Different PEEK Composite Coatings for Use as Artificial Cervical Disk Materials

  • Jian Song
  • Zhenhua Liao
  • Song Wang
  • Yuhong Liu
  • Weiqiang Liu
  • Rajnesh Tyagi
Article

Abstract

Poly(ether-ether-ketone) (PEEK) is a type of biomaterial which may be used for modifying the surface of materials used in implants. Hence, in the present investigation, the potentiality of PEEK and its composites coatings has been explored for improving the friction and wear behavior of the Ti6Al4V to be used for cervical disks. The structural characteristics, micro-hardness, friction, and wear characteristics of PEEK/Al2O3 and PEEK/SiO2 composite coatings have been investigated and compared with pure PEEK coating and bare titanium alloy sample. According to the XRD analysis results, these coated samples were mainly orthorhombic crystalline form. The contact angle values of PEEK and its composite coatings were higher, while micro-hardness values of these samples decreased significantly. The thickness values of the three coated samples were all above 70 μm on average. The average friction coefficients with a counterface of ZrO2 ball decreased significantly, especially under NCS (newborn calf serum) lubricated condition. After comprehensive evaluation, the PEEK/Al2O3 coating demonstrated optimum tribological properties and could be applied as bearing materials for artificial cervical disk.

Keywords

artificial cervical disk PEEK coating titanium alloy (Ti6Al4V) tribology 

Notes

Acknowledgment

This project was supported by the China Postdoctoral Science Foundation (Grant No. 2015M580735) and the Economy, Trade and Information Commission of Shenzhen Municipality (Grant No. SMJKPT20140417010001). The work is also financially supported by the National Natural Science Foundation of China (Grant No. 51522504). We are grateful to Chun ZHAO, president of Beijing Sino-Rich Material Technology Co., Ltd, for his kindly help of the PEEK composite coatings preparation for us.

Conflict of Interest

We declare that we have no conflict of interest.

References

  1. 1.
    M. Niinomi, M. Nakai, and J. Hieda, Development of New Metallic Alloys for Biomedical Applications, Acta Biomater., 2012, 8, p 3888–3903CrossRefGoogle Scholar
  2. 2.
    T.M. Grupp, H. Meisel, J.A. Cotton, J. Schwiesau et al., Alternative Bearing Materials for Intervertebral Disc Arthroplasty, Biomaterials, 2010, 31, p 523–531CrossRefGoogle Scholar
  3. 3.
    C. Zhang, Y. Liu, S. Wen, and S. Wang, Poly(vinylphosphonic acid) (PVPA) on Titanium Alloy Acting as Effective Cartilage-Like Superlubricity Coatings, Acs Appl. Mater. Inter., 2014, 6(20), p 17571–17578CrossRefGoogle Scholar
  4. 4.
    S. Wang, Z. Liao, Y. Liu, and W. Liu, Different Tribological Behaviors of Titanium Alloys Modified by Thermal Oxidation and Spraying Diamond Like Carbon, Surf. Coat. Technol., 2014, 252, p 64–73CrossRefGoogle Scholar
  5. 5.
    M.P. Ananth and R. Ramesh, Reciprocating Sliding Wear Performance of Hard Coating on Modified Titanium Alloy Surfaces, Tribol. Trans., 2015, 58, p 169–176CrossRefGoogle Scholar
  6. 6.
    M.P. Ananth and R. Ramesh, Tribological Improvement of Titanium Alloy Surfaces Through Texturing and TiAlN Coating, Surf. Eng., 2014, 30, p 758–762CrossRefGoogle Scholar
  7. 7.
    X. Guan, Z. Lu, and L. Wang, Achieving High Tribological Performance of Graphite-Like Carbon Coatings on Ti6Al4V in Aqueous Environments by Gradient Interface Design, Tribol. Lett., 2011, 44, p 315–325CrossRefGoogle Scholar
  8. 8.
    Q. Wang, F. Zhou, Z. Zhou, Y. Yang et al., Influence of Ti Content on the Structure and Tribological Properties of Ti-DLC Coatings in Water Lubrication, Diam. Relat. Mater., 2012, 25, p 163–175CrossRefGoogle Scholar
  9. 9.
    X. Feng and Y. Xia, Tribological Properties of Ti-Doped DLC Coatings Under Ionic Liquids Lubricated Conditions, Appl. Surf. Sci., 2012, 258, p 2433–2438CrossRefGoogle Scholar
  10. 10.
    Z. Yang, D. Wu, and M. Liu, Electroless Ni-P-PTFE Composite Coatings on Titanium Alloy and Their Tribological Properties, Adv. Mater. Res., 2011, 291–294, p 12–17CrossRefGoogle Scholar
  11. 11.
    B. Panjwani, N. Satyanarayana, and S.K. Sinha, Tribological Characterization of a Biocompatible Thin Film of UHMWPE on Ti6Al4V and the Effects of PFPE as Top Lubricating Layer, J. Mech. Behav. Biomed., 2011, 4, p 953–960CrossRefGoogle Scholar
  12. 12.
    Y. Luo, S. Ge, Z. Jin, and J. Fisher, Effect of Surface Modification on Surface Properties and Tribological Behaviours of Titanium Alloys, Proc. Inst. Mech. Eng. Part J, 2009, 223, p 311–316CrossRefGoogle Scholar
  13. 13.
    S.H. Modi, K.B. Dikovics, H. Gevgilili, G. Mago et al., Nanocomposites of Poly(ether ether ketone) with Carbon Nanofibers: Effects of Dispersion and Thermo-oxidative Degradation on Development of Linear Viscoelasticity and Crystallinity, Polymer, 2010, 51, p 5236–5244CrossRefGoogle Scholar
  14. 14.
    F. Rose and R. Oreffo, Bone Tissue Engineering: Hope vs Hype, Biochem. Biophys. Res. Comunn., 2002, 292, p 1–7CrossRefGoogle Scholar
  15. 15.
    H. Zhou, V.K. Goel, and S.B. Bhaduri, A Fast Route to Modify Biopolymer Surface: A Study on Polyetheretherketone (PEEK), Mater. Lett., 2014, 125, p 96–98CrossRefGoogle Scholar
  16. 16.
    O.E. Pohler, Unalloyed Titanium for Implants in Bone Surgery, Injury, 2000, 31, p D7–D13CrossRefGoogle Scholar
  17. 17.
    E.E. Nunez, S.M. Yeo, K. Polychronopoulou, and A.A. Polycarpou, Tribological Study of High Bearing Blended Polymer-Based Coatings for Air-Conditioning and Refrigeration Compressors, Surf. Coat. Technol., 2011, 205, p 2994–3005CrossRefGoogle Scholar
  18. 18.
    S. Wang, Z. Liao, Y. Liu, and W. Liu, Influence of Thermal Oxidation Temperature on the Microstructural and Tribological Behavior of Ti6A14V Alloy, Surf. Coat. Technol., 2014, 240, p 470–477CrossRefGoogle Scholar
  19. 19.
    X. Hou, C.X. Shan, and K. Choy, Microstructures and Tribological Properties of PEEK-Based Nanocomposite Coatings Incorporating Inorganic Fullerene-Like Nanoparticles, Surf. Coat. Technol., 2008, 202, p 2287–2291CrossRefGoogle Scholar
  20. 20.
    L. Yan, J. Wang, X. Han, Y. Ren et al., Enhanced Microwave Absorption of Fe Nanoflakes After Coating with SiO2 Nanoshell, Nanotechnology, 2010, 21, p 95708CrossRefGoogle Scholar
  21. 21.
    C.K. Akkan, M.E. Hammadeh, A. May, H. Park et al., Surface Topography and Wetting Modifications of PEEK for Implant Applications, Laser Med. Sci., 2014, 29, p 1633–1639CrossRefGoogle Scholar
  22. 22.
    C. Matschegewski, S. Staehlke, R. Loeffler, R. Lange et al., Cell Architecture–Cell Function Dependencies on Titanium Arrays with Regular Geometry, Biomaterials, 2010, 31, p 5729–5740CrossRefGoogle Scholar
  23. 23.
    P.R. Pandey and S. Roy, Is it Possible to Change Wettability of Hydrophilic Surface by Changing Its Roughness, J. Phys. Chem. Lett., 2013, 4, p 3692–3697CrossRefGoogle Scholar
  24. 24.
    C.N. Elias, Y. Oshida, J.H.C. Lima, and C.A. Muller, Relationship Between Surface Properties (Roughness, Wettability and Morphology) of Titanium and Dental Implant Removal Torque, J. Mech. Behav. Biomed., 2008, 1, p 234–242CrossRefGoogle Scholar
  25. 25.
    G. Zhang, H. Liao, H. Yu, V. Ji et al., Correlation of Crystallization Behavior and Mechanical Properties of Thermal Sprayed PEEK Coating, Surf. Coat. Technol., 2006, 200, p 6690–6695CrossRefGoogle Scholar
  26. 26.
    R. Xu, J. Wang, L. He, and Z. Guo, Study on the Characteristics of Ni–W–P Composite Coatings Containing Nano-SiO2 and Nano-CeO2 Particles, Surf. Coat. Technol., 2008, 202, p 1574–1579CrossRefGoogle Scholar
  27. 27.
    T. Palathai, J. Tharajak, and N. Sombatsompop, Hardness, Adhesion Index and Microstructure of PEEK Coating on Al or Fe Substrate by LVOF Flame Spray, Mater. Sci. Eng. A, 2008, 485, p 66–73CrossRefGoogle Scholar
  28. 28.
    G. Zhang, H. Yu, C. Zhang, H. Liao, and C. Coddet, Temperature Dependence of the Tribological Mechanisms of Amorphous PEEK (Polyetheretherketone) Under Dry Sliding Conditions, Acta Mater., 2008, 56, p 2182–2190CrossRefGoogle Scholar
  29. 29.
    S.R. Ge, Q.L. Wang, D.K. Zhang, H. Zhu et al., Friction and Wear Behavior of Nitrogen Ion Implanted UHMWPE Against ZrO2 Ceramic, Wear, 2003, 255, p 1069–1075CrossRefGoogle Scholar
  30. 30.
    C.L. Brockett, G. John, S. Williams, Z. Jin et al., Wear of Ceramic-on-Carbon Fiber-Reinforced Poly-ether Ether Ketone Hip Replacements, J. Biomed. Mater. Res. B, 2012, 100B, p 1459–1465CrossRefGoogle Scholar
  31. 31.
    S.C. Scholes and A. Unsworth, Pitch-Based Carbon-Fibre-Reinforced Poly(ether-ether-ketone) OPTIMA (R) Assessed as a Bearing Material in a Mobile Bearing Unicondylar Knee Joint, Proc. Inst. Mech. Eng. Part H, 2009, 223, p 13–25CrossRefGoogle Scholar
  32. 32.
    X. Huang, P. Jiang, and T. Tanaka, A Review of Dielectric Polymer Composites with High Thermal Conductivity, IEEE Ind. Electron. Mag., 2011, 27, p 8–16CrossRefGoogle Scholar
  33. 33.
    G. Zhang, H. Liao, H. Li, C. Mateus et al., On Dry Sliding Friction and Wear Behaviour of PEEK and PEEK/SiC-Composite Coatings, Wear, 2006, 260, p 594–600CrossRefGoogle Scholar
  34. 34.
    M. De Buck, M. Gouwy, P. Proost, S. Struyf, and J. Van Damme, Identification and Characterization of MIP-1α/CCL3 Isoform 2 from Bovine Serum as a Potent Monocyte/Dendritic Cell Chemoattractant, Biochem. Pharmacol., 2013, 85, p 789–797CrossRefGoogle Scholar
  35. 35.
    J. Huang, L. Wang, B. Liu, S. Wan, and Q. Xue, In Vitro Evaluation of Tribological Response of Mo Doped GLC Film in Different Biological Mediums, Acs Appl. Mater. Inter., 2015, 7(4), p 2772–2783CrossRefGoogle Scholar
  36. 36.
    L. Mattei, F. Di Puccio, B. Piccigallo, and E. Ciulli, Lubrication and Wear Modelling of Artificial Hip Joints: A Review, Tribol. Int., 2011, 44, p 532–549CrossRefGoogle Scholar
  37. 37.
    S. Wang, Y. Liu, C. Zhang, Z. Liao, and W. Liu, The Improvement of Wettability, Biotribological Behavior and Corrosion Resistance of Titanium Alloy Pretreated by Thermal Oxidation, Tribol. Int., 2014, 79, p 174–182CrossRefGoogle Scholar
  38. 38.
    R.M. Hall and A. Unsworth, Friction in Hip Prostheses, Biomaterials, 1997, 18, p 1017–1026CrossRefGoogle Scholar
  39. 39.
    P. Thissen, T. Peixoto, R.C. Longo, W. Peng et al., Activation of Surface Hydroxyl Groups by Modification of H-Terminated Si (111) Surfaces, J. Am. Chem. Soc., 2012, 134, p 8869–8874CrossRefGoogle Scholar
  40. 40.
    M. Palacio and B. Bhushan, A Review of Ionic Liquids for Green Molecular Lubrication in Nanotechnology, Tribol. Lett., 2010, 40, p 247–268CrossRefGoogle Scholar
  41. 41.
    M.C. Kuo, C.M. Tsai, J.C. Huang, and M. Chen, PEEK Composites Reinforced by Nano-sized SiO2 and Al2O3 Particulates, Mater. Chem. Phys., 2005, 90, p 185–195CrossRefGoogle Scholar

Copyright information

© ASM International 2015

Authors and Affiliations

  • Jian Song
    • 1
    • 2
  • Zhenhua Liao
    • 2
    • 3
  • Song Wang
    • 2
    • 3
  • Yuhong Liu
    • 1
    • 2
  • Weiqiang Liu
    • 1
    • 3
  • Rajnesh Tyagi
    • 4
  1. 1.State Key Laboratory of TribologyTsinghua UniversityBeijingPeople’s Republic of China
  2. 2.Department of Mechanical EngineeringTsinghua UniversityBeijingPeople’s Republic of China
  3. 3.Biomechanics and Biotechnology LabResearch Institute of Tsinghua University in ShenzhenShenzhenPeople’s Republic of China
  4. 4.Department of Mechanical EngineeringIndian Institute of Technology (BHU) VaranasiVaranasiIndia

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