Journal of Electronic Materials

, Volume 28, Issue 6, pp 683–687 | Cite as

Recent progress in CdZnTe crystals

  • A. Koyama
  • A. Hichiwa
  • R. Hirano
Special Issue Paper

Abstract

CdZnTe crystals were grown by vertical gradient freezing (VGF) method with a Cd reservoir for controlling the Cd pressure under conditions such that the crystals are in equilibrium with a Cd vapor corresponding to the minimum deviation from stoichiometry. The precipitate size became smaller by a post growth annealing method in the VGF furnace after the crystal growth without using wafer annealing. The size became less than 2 µm. Precipitate-free crystals were also grown by controlling the cooling method. In addition, the carrier concentration of p-type CdZnTe crystals was reduced using polycrystals grown in pBN boats. We have found that the carrier concentration of p-type ingots is dependent on Na and Li impurity concentrations.

Key words

Carrier concentration CdZnTe Li Na precipitates 

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Copyright information

© TMS-The Minerals, Metals and Materials Society 1999

Authors and Affiliations

  • A. Koyama
    • 1
  • A. Hichiwa
    • 1
  • R. Hirano
    • 1
  1. 1.Compound Semiconductor Materials DepartmentJapan Energy CorporationIbarakiJapan

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