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Ternary CuCo2S4 Thiospinel Nanocrystal-Coated Photodiode with Improved Photoresponsivity and Acceptance Angles for Optoelectronic Applications

  • Murat YıldırımEmail author
  • Adem Kocyigit
  • Adem Sarilmaz
  • Sultan Suleyman Ozel
  • Mahmut Kus
  • Faruk OzelEmail author
Article
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Abstract

Ternary-structured thiospinels have attracted great attention in recent years for energy applications due to their attractive characteristics such as simple production, earth-abundant components and non-toxic nature. In this work, copper cobalt sulfide (CuCo2S4 or carrollite) thiospinel nanocrystals were synthesized by a hot-injection method, and detailed electrical and optoelectronic characterizations were performed in a Schottky device. The synthesized nanocrystals were used as an interfacial layer between the Au metal and p-Si semiconductor to obtain an Au/CuCo2S4/p-Si device. The structural and morphological characterizations confirmed the crystallinity, nanostructure and composition of the CuCo2S4 nanocrystals. The IV and CV measurements were employed to characterize the Au/CuCo2S4/p-Si device for various illumination intensities. The obtained device exhibited good rectifying and photodiode properties as well as good photocapacitance. The Au/CuCo2S4/p-Si device can be used and improved for optoelectronic applications.

Keywords

CuCo2S4 carrollite photodiode optoelectronic properties hot-injection method 

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Notes

Acknowledgments

This work is supported by TUBITAK (The Scientific and Technological Research Council of Turkey) under Project Number 217M212.

References

  1. 1.
    A.N. Buckley, W.M. Skinner, S.L. Harmer, A. Pring, and L.J. Fan, Geochim. Cosmochim. Acta 73, 4452 (2009).CrossRefGoogle Scholar
  2. 2.
    M. Chauhan, K. Soni, P.E. Karthik, K.P. Reddy, C.S. Gopinath, and S. Deka, J. Mater. Chem. A 7, 6985 (2019).CrossRefGoogle Scholar
  3. 3.
    S. Hariganesh, S. Vadivel, D. Maruthamani, M. Kumaravel, and A. Habibi-Yangjeh, J. Inorg. Organomet. Polym Mater. 28, 1276 (2018).CrossRefGoogle Scholar
  4. 4.
    Y. Ge, J. Wu, X. Xu, M. Ye, and J. Shen, Int. J. Hydrogen Energy 41, 19847 (2016).CrossRefGoogle Scholar
  5. 5.
    M. Chauhan, K.P. Reddy, C.S. Gopinath, and S. Deka, ACS Catal. 7, 5871 (2017).CrossRefGoogle Scholar
  6. 6.
    A.M. Wiltrout, C.G. Read, E.M. Spencer, and R.E. Schaak, Inorg. Chem. 55, 221 (2016).CrossRefGoogle Scholar
  7. 7.
    X. Du, X. Zhang, Z. Yang, and Y. Gong, Chem. Asian J. 13, 266 (2018).CrossRefGoogle Scholar
  8. 8.
    L. Chen, Y. Zuo, Y. Zhang, and Y. Gao, Int. J. Electrochem. Sci. 13, 1343 (2018).CrossRefGoogle Scholar
  9. 9.
    X. Xu, Y. Liu, P. Dong, P.M. Ajayan, J. Shen, and M. Ye, J. Power Sour. 400, 96 (2018).CrossRefGoogle Scholar
  10. 10.
    S. Cheng, T. Shi, C. Chen, Y. Zhong, Y. Huang, X. Tao, J. Li, G. Liao, and Z. Tang, Sci. Rep. 7, 6681 (2017).CrossRefGoogle Scholar
  11. 11.
    Q. Li, Q. Jiao, X. Feng, Y. Zhao, H. Li, C. Feng, D. Shi, H. Liu, H. Wang, and X. Bai, ChemElectroChem 6, 1558 (2019).CrossRefGoogle Scholar
  12. 12.
    B. Li, F. Yuan, G. He, X. Han, X. Wang, J. Qin, Z.X. Guo, X. Lu, Q. Wang, I.P. Parkin, and C. Wu, Adv. Funct. Mater. 27, 1606218 (2017).CrossRefGoogle Scholar
  13. 13.
    Y. Chen, X. Ji, V. Sethumathavan, and B. Paul, Materials 11, 2303 (2018).CrossRefGoogle Scholar
  14. 14.
    A. Sarilmaz and F. Ozel, J. Alloys Compd. 780, 518 (2019).CrossRefGoogle Scholar
  15. 15.
    M. Yıldırım, M.O. Erdal, and A. Kocyigit, Phys. B 572, 153 (2019).CrossRefGoogle Scholar
  16. 16.
    M.O. Erdal, M. Yıldırım, and A. Kocyigit, J. Mater. Sci.: Mater. Electron. 30, 13617 (2019).Google Scholar
  17. 17.
    S. Uruş, M. Çaylar, and İ. Karteri, Chem. Eng. J. 306, 961 (2016).CrossRefGoogle Scholar
  18. 18.
    F. Özel, A. Sarilmaz, B. Istanbullu, A. Aljabour, M. Kuş, and S. SÖnmezoğlu, Sci. Rep. 6, 29207 (2016).CrossRefGoogle Scholar
  19. 19.
    M. Yıldırım and A. Kocyigit, J. Alloys Compd. 768, 1064 (2018).CrossRefGoogle Scholar
  20. 20.
    A.S. Dahlan, A. Tataroğlu, A.A. Al-Ghamdi, A.A. Al-Ghamdi, S. Bin-Omran, Y. Al-Turki, F. El-Tantawy, and F. Yakuphanoglu, J. Alloys Compd. 646, 1151 (2015).CrossRefGoogle Scholar
  21. 21.
    A. Mekki, R.O. Ocaya, A. Dere, A.A. Al-Ghamdi, K. Harrabi, and F. Yakuphanoglu, Synth. Met. 213, 47 (2016).CrossRefGoogle Scholar
  22. 22.
    S. Kyoung, E.-S. Jung, and M.Y. Sung, Microelectron. Eng. 154, 69 (2016).CrossRefGoogle Scholar
  23. 23.
    M. Gökçen, T. Tunç, S. Altndal, and I. Uslu, Curr. Appl. Phys. 12, 525 (2012).CrossRefGoogle Scholar
  24. 24.
    Ş. Aydoğan, M.L. Grilli, M. Yilmaz, Z. Çaldiran, and H. KaÇuŞ, J. Alloys Compd. 708, 55 (2017).CrossRefGoogle Scholar
  25. 25.
    Y.-X. Luo and C.-H. Shih, Semicond. Sci. Technol. 29, 115006 (2014).CrossRefGoogle Scholar
  26. 26.
    İ. Taşçıoğlu, S.O. Tan, F. Yakuphanoğlu, and ş. Altındal, J. Electron. Mater. 47, 6059 (2018).CrossRefGoogle Scholar
  27. 27.
    A. Kocyigit, M. Yılmaz, Ş. Aydoğan, and Ü. İncekara, J. Alloys Compd. 790, 388 (2019).CrossRefGoogle Scholar
  28. 28.
    F. Djeffal, H. Ferhati, A. Benhaya, and A. Bendjerad, Superlattices Microstruct. 128, 382 (2019).CrossRefGoogle Scholar
  29. 29.
    M.A. Yeganeh, S. Rahmatollahpur, R. Sadighi-Bonabi, and R. Mamedov, Phys. B 405, 3253 (2010).CrossRefGoogle Scholar
  30. 30.
    S.K. Cheung and N.W. Cheung, Appl. Phys. Lett. 49, 85 (1986).CrossRefGoogle Scholar
  31. 31.
    M.O. Erdal, A. Kocyigit, and M. Yıldırım, Mater. Sci. Semicond. Process. (2019).  https://doi.org/10.1016/j.mssp.2019.104620.CrossRefGoogle Scholar
  32. 32.
    D.E. Yildiz, Ş. Altindal, and H. Kanbur, J. Appl. Phys. 103, 124502 (2008).CrossRefGoogle Scholar
  33. 33.
    A.K. Bilgili, T. Güzel, and M. Özer, J. Appl. Phys. 125, 035704 (2019).CrossRefGoogle Scholar
  34. 34.
    I. Orak, A. Kocyigit, and A. Turut, J Alloys Compd 691, 873 (2017).CrossRefGoogle Scholar
  35. 35.
    O.S. Cifci, M. Bakir, J.L. Meyer, and A. Kocyigit, Mater. Sci. Semicond. Process. 74, 175 (2018).CrossRefGoogle Scholar
  36. 36.
    H. Norde, J. Appl. Phys. 50, 5052 (1979).CrossRefGoogle Scholar
  37. 37.
    B.A. Gozeh, A. Karabulut, A. Yildiz, and F. Yakuphanoglu, J. Alloys Compd. 732, 16 (2018).CrossRefGoogle Scholar
  38. 38.
    R. Mirzanezhad-Asl, A. Phirouznia, S. Altındal, Y. Badali, and Y. Azizian-Kalandaragh, Physica B Condens. Matter 561, 1 (2019).CrossRefGoogle Scholar
  39. 39.
    Y. Şafak-Asar, T. Asar, Ş. Altındal, and S. Özçelik, J Alloys Compd 628, 442 (2015).CrossRefGoogle Scholar
  40. 40.
    D. Korucu, A. Turut, R. Turan, and Ş. Altindal, Mater. Sci. Semicond. Process. 16, 344 (2013).CrossRefGoogle Scholar
  41. 41.
    R.H. AlOrainy and A.A. Hendi, Microelectron. Eng. 127, 14 (2014).CrossRefGoogle Scholar
  42. 42.
    E. ErbilenTanrıkulu, Ş. Altındal, and Y. Azizian-Kalandaragh, J. Mater. Sci.: Mater. Electron. 29, 11801 (2018).Google Scholar
  43. 43.
    R.H. AlOrainy, J. Optoelectron. Adv. Mater. 16, 793 (2014).Google Scholar
  44. 44.
    S.M. Sze, Physics of Semiconductor Devices, 2nd ed. (Newyork: Wiley, 1981), pp. 45–46.Google Scholar
  45. 45.
    W.A. Hill and C.C. Coleman, Solid State Electron. 23, 987 (1980).CrossRefGoogle Scholar
  46. 46.
    E.H. Nicollian and J.R. Brews, Solid-State Electron. 27, 953 (1984).CrossRefGoogle Scholar
  47. 47.
    S. Zeyrek, E. Acaroğlu, Ş. Altındal, S. Birdoğan, and M.M. Bülbül, Curr. Appl. Phys. 13, 1225 (2013).CrossRefGoogle Scholar
  48. 48.
    S. Demirezen, Z. Sönmez, U. Aydemir, and Ş. Altındal, Curr. Appl. Phys. 12, 266 (2012).CrossRefGoogle Scholar
  49. 49.
    I. Orak, A. Kocyigit, and S. Alindal, Chin. Phys. B 26, 028102 (2017).CrossRefGoogle Scholar
  50. 50.
    N. Baraz, İ. Yücedağ, Y. Azizian-Kalandaragh, and Ş. Altındal, J. Mater. Sci.: Mater. Electron. 28, 1315 (2017).Google Scholar
  51. 51.
    A. Mekki, A. Dere, K. Mensah-Darkwa, A. Al-Ghamdi, R.K. Gupta, K. Harrabi, W.A. Farooq, F. El-Tantawy, and F. Yakuphanoglu, Synth. Met. 217, 43 (2016).CrossRefGoogle Scholar

Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  • Murat Yıldırım
    • 1
    Email author
  • Adem Kocyigit
    • 2
  • Adem Sarilmaz
    • 3
  • Sultan Suleyman Ozel
    • 3
  • Mahmut Kus
    • 4
  • Faruk Ozel
    • 3
    • 5
    Email author
  1. 1.Department of Biotechnology, Faculty of ScienceSelcuk UniversityKonyaTurkey
  2. 2.Department of Electrical Electronics Engineering, Engineering FacultyIgdir UniversityIgdirTurkey
  3. 3.Department of Metallurgical and Materials Engineering, Faculty of EngineeringKaramanoglu Mehmetbey UniversityKaramanTurkey
  4. 4.Department of Chemical Engineering, Faculty of Engineering and Natural SciencesKonya Technical UniversityKonyaTurkey
  5. 5.Scientific and Technological Research and Application CenterKaramanoglu Mehmetbey UniversityKaramanTurkey

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