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Chemical Interaction of InAs with Zinc

  • A. V. VishnyakovEmail author
  • V. A. Popov
  • A. V. Grebennik
Article

Abstract

The partial pressure of Zn over the system including three condensed phases [(In-Zn)-InAs(s)-Zn3As2(s)] has been determined between 617 K and 740 K by optical absorption of a vapor phase at 307.6 nm using a Zn hollow cathode lamp as a source of radiation. The array of experimental data contained 52 values of Zn pressure from 0.32 Pa up to 20 Pa at different temperatures. Using this information the activity of zinc and its mole fraction in metal phase (from 4.6 at.% to 8.3 at.%) were founded. The dependences of ln p and \( \ln K_{a}^{ \circ } \) against reciprocal temperature for reaction: 1/3Zn3As2(s) + 2/3In(liquid) = Zn(g) + 2/3InAs(s) were approximated by linear functions. For considered temperature range the standard enthalpy of reaction was calculated as equal to 126 ± 1 kJ/mol.

Keywords

Interaction InAs zinc phase equilibrium pressure 

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Notes

Acknowledgments

We are grateful to Cand. Sci. (Chem.) O. Mezhuev for his assistance in the technical design of the experimental setup.

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Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  • A. V. Vishnyakov
    • 1
    Email author
  • V. A. Popov
    • 2
  • A. V. Grebennik
    • 1
  1. 1.Mendeleev University of Chemical TechnologyMoscowRussia
  2. 2.North-Eastern State UniversityMagadanRussia

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