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Journal of Electronic Materials

, Volume 48, Issue 1, pp 271–277 | Cite as

Optical and Structural Characterization of TiO-Zn-V Thin Films Synthesized Using the Sol–Gel Method

  • C. SolanoEmail author
  • Julio Mass Varela
  • Amner Muñoz Acevedo
  • Humberto Gómez Vega
  • José Antonio Henao Martínez
Article
  • 22 Downloads

Abstract

We report structural and optical properties of thin films grown by the sol–gel method and spin-coating technique. We synthesized thin films of Tiox-Zn-V with varying concentrations of vanadium and titanium. The resulting thin films are characterized by x-ray diffraction (XRD), wavelength-dispersive x-ray fluorescence, and ultraviolet–visible spectrophotometry. XRD results indicate that the majority phase of the resulting structure was Tiox-Zn with a crystallographic plane (020) and an angular position 2θ of 42.38°. The presence of vanadium was confirmed by x-ray fluorescence, and transmittance measurements in the 300–800-nm range showed that the transmittance of this material was over 80%, but reduced in the presence of vanadium. We also found the width of the energy gap to decrease as the concentration of vanadium is increased, thereby suggesting an increase in conductivity and the introduction of a certain amount of disorder into the Tiox-Zn structure according to the Wemple–DiDomenico (WDD) formulation of energy dispersion. Thus, the influence of vanadium on the optical properties of the Tiox-Zn system could be advantageous for the fabrication of smart windows.

Keywords

Metal oxide films x-ray diffraction optical properties smart windows 

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References

  1. 1.
    G.S. Chen, C.C. Lee, H. Niu, W. Huang, R. Jann, and T. Schütte, Thin Solid Films 560, 8473 (2008).CrossRefGoogle Scholar
  2. 2.
    M. Zribi, M. Kanzari, and B. Rezig, Thin Solid Films 516, 1476 (2008).CrossRefGoogle Scholar
  3. 3.
    Y.V. Kolenko, K.A. Kovnir, A.I. Gavrilov, A.V. Garshev, P.E. Meskin, B.R. Churagulov, M. Bouchard, C. Colbeau-Justin, O.I. Lebedev, G. Van Tendeloo, and M. Yoshimura, J. Phys. Chem. B 109, 20303 (2005).CrossRefGoogle Scholar
  4. 4.
    A. Arunachalam, S. Dhanapandian, C. Manoharan, and G. Sivakumar, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 138, 105 (2015).CrossRefGoogle Scholar
  5. 5.
    E.M. Assim, J. Alloys Compd. 463, 55 (2008).CrossRefGoogle Scholar
  6. 6.
    T. Ivanova, A. Harizanova, T. Koutzarova, and B. Vertruyen, J. Non-Cryst. Solids 357, 2840 (2011).CrossRefGoogle Scholar
  7. 7.
    K. Tong, R. Li, J. Zhu, H. Yao, H. Zhou, X. Zeng, S. Ji, and P. Jin, Ceram. Int. 43, 4055 (2017).CrossRefGoogle Scholar
  8. 8.
    R.A. Patil, R.S. Devan, Y. Liou, and Y.-R. Maa, Sol. Energy Mater. Sol. Cells 147, 240 (2016).CrossRefGoogle Scholar
  9. 9.
    A.U.H.S. Rana, S.-B. Chang, H.U. Chae, and H.-S. Kim, J. Alloys Compd. 729, 571 (2017).CrossRefGoogle Scholar
  10. 10.
    Z. Liang, L. Zhao, W. Meng, C. Zhong, S. Wei, B. Dong, Z. Xu, L. Wan, and S. Wang, J. Alloys Compd. 694, 124 (2017).CrossRefGoogle Scholar
  11. 11.
    J.K. Gamarra, C. Solano, I. Pieres, H. Gmez, J. Mass, and D.N. Montenegro, Conf. Ser. J. Phys. 786, 1 (2017).CrossRefGoogle Scholar
  12. 12.
    E.R. Shaaban, I.S. Yahiab, and E.G. El-Metwally, Acta Phys. Pol., A 121, 628 (2012).CrossRefGoogle Scholar
  13. 13.
    E.M. Assim, J. Alloys Compd. 465, 1 (2008).CrossRefGoogle Scholar
  14. 14.
    A.K. Zak, W.H.A. Majid, M.E. Abrishami, and R. Youse, Solid State Sci. 13, 251 (2011).CrossRefGoogle Scholar
  15. 15.
    D. Fang, K. Lin, T. Xue, C. Cui, X. Chen, P. Yao, and H. Li, J. Alloys Compd. 589, 346 (2014).CrossRefGoogle Scholar
  16. 16.
    J. Tauc, R. Grigorovici, and A. Vancu, Phys. Status Sol 15, 627 (1966).CrossRefGoogle Scholar
  17. 17.
    A. Enesca, L. Andronic, A. Duta, and S. Manolache, Rom. J. Inf. Sci. Technol. 10, 269 (2007).Google Scholar
  18. 18.
    A.M. Shehap and D.S. Akil, Int. J. Nanoelectron. Mater. 9, 17 (2016).Google Scholar
  19. 19.
    B.D. Viezbicke, S. Patel, B.E. Davis, and D.P. Birnie III, Phys. Status Solidi B 252, 1 (2015).CrossRefGoogle Scholar
  20. 20.
    S.H. Wemple and M. DiDomenico Jr., Phys. Rev. B 3, 1338 (1971).CrossRefGoogle Scholar
  21. 21.
    S. Singh, P. Dey, J.N. Roy, and S.K. Mandal, J. Alloys Compd. 642, 15 (2015).CrossRefGoogle Scholar
  22. 22.
    T. Arumanayagam and P. Murugakoothan, J. Miner. Mater. Charact. Eng. 10, 1225 (2011).Google Scholar

Copyright information

© The Minerals, Metals & Materials Society 2018

Authors and Affiliations

  1. 1.Departamento de Ciencias Naturales y ExactasUniversidad de la CostaBarranquillaColombia
  2. 2.Departamento de FísicaUniversidad del NorteBarranquillaColombia
  3. 3.Departamento de Química y BiologíaUniversidad del NorteBarranquillaColombia
  4. 4.Departamento de Ingeniería MecánicaUniversidad del NorteBarranquillaColombia
  5. 5.Departamento de QuímicaUniversidad Industrial de SantanderBucaramangaColombia

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