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Influence of Surface Modification and Dispersive Additives on Dielectric and Electrical Properties of BiFeO3/Poly(methyl methacrylate) Composite Films

  • Srikanta Moharana
  • Manoj Kumar Chopkar
  • Ram Naresh Mahaling
Article
  • 6 Downloads

Abstract

Surface modification plays an important role to enhance the dielectric constant and minimize the dielectric loss. In this study, poly(methyl methacrylate) (PMMA) composites filled with 2-aminoethanesulfonic acid-modified bismuth ferrite (BiFeO3; BFO) have been prepared via solution casting technique. The surface morphology of the composites provides a better homogeneous dispersion of the particles in the polymer matrix and increases interface compatibility between modified BFO and PMMA matrix. The experimental results show that the composites have high dielectric constant (≈ 147), alternating current (AC) conductivity (1 × 10−5) and relatively low loss (< 1) at 100 Hz. The percolation phenomenon is well observed in the composite having less than 30 wt.% of BFO particles. Further, the composites produce passivation layers on the surface of modified BFO particles which might improve the morphology and promote the space charges, interface effects and dielectric properties. Our strategy is to provide a simple and efficient approach to fabricate high-performance dielectric composites for energy storage applications.

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Keywords

Poly(methyl methacrylate) dielectric properties morphology surface treatment 

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Notes

Acknowledgments

The authors gratefully acknowledge the financial support obtained from the DST-FIST and UGC-DRS grant for the development of research work in the School of Chemistry, Sambalpur University, and project grant of DST Government of Odisha, India. One of the authors (SM) thanks UGC, New Delhi, for financial support through a BSR Research fellowship.

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Copyright information

© The Minerals, Metals & Materials Society 2018

Authors and Affiliations

  • Srikanta Moharana
    • 1
  • Manoj Kumar Chopkar
    • 3
  • Ram Naresh Mahaling
    • 1
    • 2
  1. 1.Laboratory of Polymeric and Materials Chemistry, School of ChemistrySambalpur UniversityBurlaIndia
  2. 2.Nano Research CentreSambalpur UniversityBurlaIndia
  3. 3.Department of Metallurgical EngineeringNational Institute of Technology (NIT) RaipurRaipurIndia

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