Journal of Electronic Materials

, Volume 47, Issue 2, pp 917–926 | Cite as

Deposition of Methylammonium Lead Triiodide by Resonant Infrared Matrix-Assisted Pulsed Laser Evaporation

  • E. Tomas Barraza
  • Wiley A. Dunlap-Shohl
  • David B. Mitzi
  • Adrienne D. Stiff-RobertsEmail author
Topical Collection: 59th Electronic Materials Conference 2017
Part of the following topical collections:
  1. 59th Electronic Materials Conference 2017


Resonant infrared matrix-assisted pulsed laser evaporation (RIR-MAPLE) was used to deposit the metal-halide perovskite (MHP) CH3NH3PbI3 (methylammonium lead triiodide, or MAPbI), creating phase-pure films. Given the moisture sensitivity of these crystalline, multi-component organic–inorganic hybrid materials, deposition of MAPbI by RIR-MAPLE required a departure from the use of water-based emulsions as deposition targets. Different chemistries were explored to create targets that properly dissolved MAPbI components, were stable under vacuum conditions, and enabled resonant laser energy absorption. Secondary phases and solvent contamination in the resulting films were studied through Fourier transform infrared (FTIR) absorbance and x-ray diffraction (XRD) measurements, suggesting that lingering excess methylammonium iodide (MAI) and low-vapor pressure solvents can distort the microstructure, creating crystalline and amorphous non-perovskite phases. Thermal annealing of films deposited by RIR-MAPLE allowed for excess solvent to be evaporated from films without degrading the MAPbI structure. Further, it was demonstrated that RIR-MAPLE does not require excess MAI to create stoichiometric films with optoelectronic properties, crystal structure, and film morphology comparable to films created using more established spin-coating methods for processing MHPs. This work marks the first time a MAPLE-related technique was used to deposit MHPs.


RIR-MAPLE matrix-assisted pulsed laser evaporation metal-halide perovskites methylammonium lead iodide 


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This work was supported by the National Science Foundation, Research Triangle MRSEC (DMR-1121107). We would like to acknowledge the contributions of Wangyao Ge, Yuankai Liu, and Chenqi Zhao from the Stiff-Roberts group at Duke University in developing the RIR-MAPLE methods described within this work.

Conflict of interest

The authors declare that they have no conflicts of interest.

Supplementary material

11664_2017_5814_MOESM1_ESM.pdf (162 kb)
Supplementary material 1 (PDF 162 kb)


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Copyright information

© The Minerals, Metals & Materials Society 2017

Authors and Affiliations

  1. 1.Department of Electrical and Computer EngineeringDuke UniversityDurhamUSA
  2. 2.Department of Mechanical Engineering and Materials ScienceDuke University DurhamUSA
  3. 3.Department of ChemistryDuke UniversityDurhamUSA

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