Journal of Electronic Materials

, Volume 44, Issue 10, pp 3603–3611 | Cite as

Molybdenum, Tungsten, and Aluminium Substitution for Enhancement of the Thermoelectric Performance of Higher Manganese Silicides

  • D. Y. Nhi Truong
  • David Berthebaud
  • Franck Gascoin
  • Holger Kleinke


An easy and efficient process involving ball milling under soft conditions and spark plasma sintering was used to synthesize higher manganese silicide (HMS)-based compounds, for example MnSi1.75Ge0.02, with different molybdenum, tungsten, and aluminium substitution. The x-ray diffraction patterns of the samples after sintering showed the main phase to be HMS with the presence of some side products. Molybdenum substitution enlarges the unit cells more than tungsten substitution, owing to its greater solubility in the HMS structure, whereas substitution with aluminium did not substantially alter the cell parameters. The electrical resistivity of HMS-based compounds was reduced by <10% by this substitution, because of increased carrier concentrations. Changes of the Seebeck coefficient were insignificant after molybdenum and aluminium substitution whereas tungsten substitution slightly reduced the thermopower of the base material by approximately 8% over the whole temperature range; this was ascribed to reduced carrier mobility as a result of enhanced scattering. Substitution with any combination of two of these elements resulted in no crucial modification of the electrical properties of the base material. Large decreases of lattice thermal conductivity were observed, because of enhanced phonon scattering, with the highest reduction up to 25% for molybdenum substitution; this resulted in a 20% decrease of total thermal conductivity, which contributed to improvement of the figure of merit ZT of the HMS-based materials. The maximum ZT value was approximately 0.40 for the material with 2 at.% molybdenum substitution at the Mn sites.


Manganese silicon semiconductor thermoelectric physical properties 


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The authors would like to thank the Region Basse Normandie for financial support of D.Y. Nhi Truong. The authors are grateful for technical assistance with the SPS experiments provided by Francois-Xavier Lefevre and Jérome Lecourt. The work was also supported by the Natural Sciences and Engineering Research Council of Canada in the form of a Discovery Grant.

Supplementary material

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Supplementary material 1 (DOCX 165 kb)


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Copyright information

© The Minerals, Metals & Materials Society 2015

Authors and Affiliations

  • D. Y. Nhi Truong
    • 1
    • 2
  • David Berthebaud
    • 1
  • Franck Gascoin
    • 1
  • Holger Kleinke
    • 2
  1. 1.Laboratoire CRISMAT UMR 6508 CNRS ENSICAENCaen Cedex 04France
  2. 2.Department of Chemistry and Waterloo Institute for NanotechnologyUniversity of WaterlooWaterlooCanada

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