Journal of Electronic Materials

, Volume 41, Issue 7, pp 1941–1947

Growth of CdS Nanoneedles by Pulsed Laser Deposition

  • Li Chen
  • Xiaoniu Fu
  • Jushui Lai
  • Jian Sun
  • Zhifeng Ying
  • Jiada Wu
  • Ning Xu


CdS nanoneedles have been grown on Ni-coated Si (100) substrates by pulsed laser deposition. Substrate temperature and Ni-catalyst layer thickness were found to have great effects on the density and morphology of the as-grown CdS nanoneedles. Crystalline CdS nanoneedles with middle diameter and length of about 40 nm to 100 nm and 400 nm to 1000 nm, respectively, could be obtained at 350°C to 450°C on Ni-coated silicon (100) substrates, and nanoneedles with good shapes were obtained at 400°C substrate temperature. From the cross-section morphologies, it was found that the CdS nanoneedles grew out of the base CdS crystallite layer with thickness of about 500 nm. Based on the experimental results, vapor–solid and vapor–liquid–solid growth modes describe the CdS nanoneedle growth.


CdS nanoneedles pulsed laser deposition Ni-catalyst 


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  1. 1.
    X.Z. Wu, Sol. Energy 77, 803 (2004).CrossRefGoogle Scholar
  2. 2.
    A. Morales-Acevedo, Sol. Energy 80, 675 (2006).CrossRefGoogle Scholar
  3. 3.
    N.D. Kumar, M.P. Joshi, C.S. Friend, P.N. Prasad, and R. Burzynski, Appl. Phys. Lett. 71, 1388 (1997).CrossRefGoogle Scholar
  4. 4.
    J.L. Zhao, J.A. Bardecker, A.M. Munro, M.S. Liu, Y.H. Niu, I.-K. Ding, J.D. Luo, B.Q. Chen, A.K.-Y. Jen, and D.S. Ginger, Nano Lett. 6, 463 (2006).CrossRefGoogle Scholar
  5. 5.
    V. Smyntyna, V. Golovanov, S. Kačiulis, G. Mattogno, and G. Righini, Sens. Actuat. B 25, 628 (1995).CrossRefGoogle Scholar
  6. 6.
    Y.R. Roh, H.B. Kim, Y.J. Lee, H.M. Cho, J.S. Chung, and S. Baik, Proc. IEEE Ultrason. Symp. 1, 473 (1995).Google Scholar
  7. 7.
    J.N. Ross, Meas. Sci. Technol. 6, 405 (1995).CrossRefGoogle Scholar
  8. 8.
    J.S. Jang, W. Li, S.H. Oh, and J.S. Lee, Chem. Phys. Lett. 425, 278 (2006).CrossRefGoogle Scholar
  9. 9.
    K.G. Kanade, J.-O. Baeg, U.P. Mulik, D.P. Amalnerkar, and B.B. Kale, Mater. Res. Bull. 41, 2219 (2006).CrossRefGoogle Scholar
  10. 10.
    J.-C. Lee, W. Lee, S.-H. Han, T.G. Kim, and Y.-M. Sung, Electrochem. Commun. 11, 231 (2009).CrossRefGoogle Scholar
  11. 11.
    D.S. Xu, Y.J. Xu, D.P. Chen, G.L. Guo, L.L. Gui, and Y.Q. Tang, Adv. Mater. 12, 520 (2000).CrossRefGoogle Scholar
  12. 12.
    D. Routkevitch, T. Bigioni, M. Moskovits, and J.M. Xu, J. Phys. Chem. 100, 14037 (1996).CrossRefGoogle Scholar
  13. 13.
    J.S. Suh and J.S. Lee, Chem. Phys. Lett. 281, 384 (1997).CrossRefGoogle Scholar
  14. 14.
    J. Yang, J.H. Zeng, S.H. Yu, L. Yang, G.E. Zhou, and Y.T. Qian, Chem. Mater. 12, 3259 (2000).CrossRefGoogle Scholar
  15. 15.
    Y.D. Li, H.W. Liao, Y. Ding, Y.T. Qian, L. Yang, and G.E. Zhou, Chem. Mater. 10, 2301 (1998).CrossRefGoogle Scholar
  16. 16.
    X.L. Shi, M.S. Cao, J. Yuan, Q.L. Zhao, Y.Q. Kang, X.Y. Fang, and Y.J. Chen, Appl. Phys. Lett. 93, 183118 (2008).CrossRefGoogle Scholar
  17. 17.
    Y.W. Wang, G.W. Meng, L.D. Zhang, C.H. Liang, and J. Zhang, Chem. Mater. 14, 1773 (2002).CrossRefGoogle Scholar
  18. 18.
    X.F. Duan and C.M. Lieber, Adv. Mater. 12, 298 (2000).CrossRefGoogle Scholar
  19. 19.
    T. Yoshitake, T. Nagamoto, and K. Nagayama, Thin Solid Films 381, 236 (2001).CrossRefGoogle Scholar
  20. 20.
    Y.R. Ryu, S. Zhu, S.W. Han, H.W. White, P.F. Miceli, and H.R. Chandrasekhar, Appl. Surf. Sci. 128, 496 (1998).CrossRefGoogle Scholar
  21. 21.
    J.W. Park, C.M. Rouleau, and D.H. Lowndes, J. Cryst. Growth 193, 516 (1998).CrossRefGoogle Scholar
  22. 22.
    J.P. Zheng, Z.Q. Huang, D.T. Shaw, and H.S. Kwok, Appl. Phys. Lett. 54, 280 (1989).CrossRefGoogle Scholar
  23. 23.
    A. Bylica, P. Sagan, I. Virt, G. Wisz, M. Bester, I. Stefaniuk, and M. Kuzma, Thin Solid Films 512, 439 (2006).CrossRefGoogle Scholar
  24. 24.
    D. Kulik, H. Htoon, and C.K. Shih, J. Appl. Phys. 95, 1056 (2004).CrossRefGoogle Scholar
  25. 25.
    J.S. Lee, S. Brittman, D. Yu, and H.K. Park, J. Am. Chem. Soc. 130, 6252 (2008).CrossRefGoogle Scholar
  26. 26.
    J.S. Lai, L. Chen, X.N. Fu, J. Sun, Z.F. Ying, J.D. Wu, and N. Xu, Appl. Phys. A 102, 477 (2010).CrossRefGoogle Scholar

Copyright information

© TMS 2012

Authors and Affiliations

  • Li Chen
    • 1
  • Xiaoniu Fu
    • 1
  • Jushui Lai
    • 1
  • Jian Sun
    • 1
  • Zhifeng Ying
    • 1
  • Jiada Wu
    • 1
  • Ning Xu
    • 1
  1. 1.Key Laboratory for Micro and Nanophotonic Structures of Ministry of Education, Department of Optical Science and EngineeringFudan UniversityShanghaiPeople’s Republic of China

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