Journal of Electronic Materials

, Volume 38, Issue 7, pp 1423–1426 | Cite as

Thermal Stability and Phase Purity in Polycrystalline Ba8GaxGe46−x

  • Ali Saramat
  • Eric S. Toberer
  • Andrew F. May
  • G. Jeffery Snyder
Article

Polycrystalline Ba8GaxGe46−x exhibits promising thermoelectric performance with the figure of merit ZT close to that of single crystals. Polycrystalline Ba8GaxGe46−x is promising for applications, but reproducibility and thermal stability of thermoelectric properties need to be demonstrated. Polycrystalline samples of Ba8+dGaxGe46−x-type clathrates (15.0 ≤ x ≤ 16.8 with varied nominal Ga content and d = 0 or 0.2) were prepared by direct reaction of the elements, followed by ball milling and hot pressing. Trace Ge impurity was observed (<1.0 wt.%) depending on the synthesis method. The electrical resistivity was stable in measurements up to 1000 K, regardless of Ge impurity. However, measurements to 1050 K resulted in irreversible increase in carrier concentration while the carrier mobility remained unchanged.

Keywords

Clathrate electrical resistivity carrier concentration Ba8Ga16Ge30 thermoelectricity 

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Copyright information

© TMS 2009

Authors and Affiliations

  • Ali Saramat
    • 1
  • Eric S. Toberer
    • 1
  • Andrew F. May
    • 1
  • G. Jeffery Snyder
    • 1
  1. 1.Materials ScienceCalifornia Institute of TechnologyPasadenaUSA

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