Mathematical modeling of microstructural development in hypoeutectic cast iron
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Abstract
A mathematical heat-transfer/microstructural model has been developed to predict the evolution of proeutectic austenite, white iron eutectic, and gray iron eutectic during solidification of hypoeutectic cast iron, based on the commercial finite-element code ABAQUS. Specialized routines which employ relationships describing nucleation and growth of equiaxed primary austenite, gray iron eutectic, and white iron eutectic have been formulated and incorporated into ABAQUS through user-specified subroutines. The relationships used in the model to describe microstructural evolution have been adapted from relationships describing equiaxed growth in the literature. The model has been validated/fine tuned against temperature data collected from a QuiK-Cup sample, which contained a thermocouple embedded approximately in the center of the casting. The phase distribution predicted with the model has been compared to the measured phase distribution inferred from the variation in hardness within the QuiK-Cup sample and from image analysis of photomicrographs of the polished and etched microstructure. Overall, the model results were found to agree well with the measured distribution of the microstructure.
Keywords
Austenite Material Transaction Cast Iron Gray Iron White IronTable of Symbols
- A
nucleation coefficient (m−3 K−2)
- pct C, Si, and P
concentration carbon, silicon, and phosphorus in liquid (wt pct)
- CL
liquid composition (wt pct)
- C0
initial liquid composition (wt pct)
- Cp
specific heat (J kg−1 K−1)
- fcond
fraction of gap heat transfer via conduction
- flim
fraction limit of gap heat transfer via conduction
- fs
volume fraction transformed
- fs
rate of solidification (s−1)
- hconv
film coefficient for free convection (W m−2 K−1)
- heff
effective heat-transfer coefficient (W m−2 K−1)
- hcond
conductive component of h eff (W m−2 K−1)
- hrad
radiative component of h eff (W m−2 K−1)
- k
segregation coefficient, or conductivity (W m−1 K−1)
- L
volumetric latent heat (J m−3)
- N
number of grains per unit volume (m−3)
- Q
volumetric heat-source term (W m−3)
- q″
heat flux (W m−2)
- R
grain radius (m)
- T
temperature (°C)
- TL
liquidus temperature (°C)
- Teut
graphite eutectic temperature (°C)
- Tcarb
iron carbide eutectic temperature (°C)
- Tcast
temperature of the casting surface (°C)
- Tmold
temperature of the mold surface (°C)
- Tsurf and T∞
surface and ambient temperature (°C)
- ΔT
liquid undercooling (K)
- t
time (S)
- tcast
casting time (S)
- V
growth velocity (m s−1)
Greek Symbols
- εeff
effective radiation emissivity
- εcast and εmold
emissivity of cast and mold
- øe
total extended volume fraction
- øe,j
extended volume fraction of phase j
- μ
growth coefficient
- ρ
density (Kg m−3)
- σ
Stefan-Boltzmann constant (5.6696(10)−8) (W m−2 K−4)
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