Metallurgical and Materials Transactions A

, Volume 50, Issue 10, pp 4665–4676 | Cite as

Experimental and Theoretical Research on the Corrosion Resistance of Ferrous Alloys in Aluminum Melts

  • Gaopeng Xu
  • Kui WangEmail author
  • Xianping Dong
  • Haiyan Jiang
  • Qudong Wang
  • Bing Ye
  • Wenjiang Ding


The resistance of three ferrous alloys (HT150, QT500, and H13) to corrosion caused by exposure to aluminum melts has been systematically studied using experiments and modeling. Results show that the exfoliation and dissolution of intermetallic compounds like Fe2Al5 and FeAl3 formed by the interdiffusion between aluminum melts and ferrous alloys are responsible for the corrosive attack. Based on the thermodynamics and kinetics of intermetallic compounds, an analytical model has been established to quantitatively account for the corrosion behavior between the ferrous alloys and aluminum melts, and the diffusion inhibition factor λ is first introduced in this work to quantitatively estimate the extent to which the existence of carbon can influence the diffusion of aluminum melts to the ferrous alloys. Theoretical analysis demonstrates that the flake graphite in HT150 can reduce the corrosion rate most effectively, followed by spheroidal graphite in QT500. Both outperform H13.



  1. 1.
    H. Yang, W.T. Tsai, J.C. Kuo and C. Yang: J. Alloys Compd., 2011, vol. 509, pp. 8176-82.CrossRefGoogle Scholar
  2. 2.
    V. Nunes, F.J.G. Silva, M.F. Andrade, R. Alexandre and A.P.M. Baptista: Surf. Coat. Technol., 2017, vol. 332, pp. 319-31.CrossRefGoogle Scholar
  3. 3.
    N.L. Okamoto, J. Okumura, M. Higashi and H. Inui: Acta Mater., 2017, vol. 129, pp. 290-99.CrossRefGoogle Scholar
  4. 4.
    M. Yousaf, J. Iqbal and M. Ajmal: Mater. Charact., 2011, vol. 62, pp. 517-25.CrossRefGoogle Scholar
  5. 5.
    X. Zhang, W. Chen, H. Luo, S. Li, T. Zhou and L. Shi: Corros. Sci., 2017, vol. 125, pp. 20-28.CrossRefGoogle Scholar
  6. 6.
    D. Alonso-Peña, M.E. Arnáiz-García, J.L. Valero-Gasalla, A.M. Arnáiz-García, R. Campillo-Campaña, J. Alonso-Peña, J.M. González-Santos, A.L. Fernández-Díaz and J. Arnáiz: Burns, 2015, vol. 41, pp. 1122-25.CrossRefGoogle Scholar
  7. 7.
    S. Komarov and D. Kuznetsov: Int. J. Refract. Met. Hard Mater., 2012, vol. 35, pp. 76-83.CrossRefGoogle Scholar
  8. 8.
    N. Tunca, G.W. Delamore and R.W. Smith: Metall. Mater. Trans. A, 1990, vol. 21, pp. 2919-28.CrossRefGoogle Scholar
  9. 9.
    N. Tang, Y.P. Li, S. Kurosu, H. Matsumoto and A. Chiba: Corros. Sci., 2012, vol. 60, pp. 32-37.CrossRefGoogle Scholar
  10. 10.
    Y. Li, N. Tang, P. Tunthawiroon, Y. Koizumi and A. chiba: Corros. Sci., 2013, vol. 73, pp. 72-79.Google Scholar
  11. 11.
    H. Xiao, W. Chen and Z. Liu: Trans. Nonferrous Met. Soc. China, 2012, vol. 22, pp. 2320-26.CrossRefGoogle Scholar
  12. 12.
    M.B. Lin, C.J. Wang and A.A. Volinsky: Surf. Coat. Technol., 2011, vol. 206, pp. 1595-99.CrossRefGoogle Scholar
  13. 13.
    D. Cong, H. Zhou, Z. Ren, H. Zhang, L. Ren, C. Meng and C. Wang: Opt. Laser. Eng., 2014, vol. 54, pp. 55-61.CrossRefGoogle Scholar
  14. 14.
    M.S. Sidhu: PhD thesis, University of Canterbury, 2012.Google Scholar
  15. 15.
    D. Balloy, J.C. Tissier, M.L. Giorgi, M.L. Giorgi and M. Briant: Metall. Mater. Trans. A, 2010, vol. 41, pp. 2366-76.CrossRefGoogle Scholar
  16. 16.
    J. Rong, Z. Kang, S. Chen, D. Yang, J. Huang and J. Yang: Mater. Charact., 2017, vol. 132, pp. 413-21.CrossRefGoogle Scholar
  17. 17.
    A.V. Alboom, B. Lemmens, B. Breitbach, E.D. Grave, S. Cottenier and K. Verbeken: Surf. Coat. Technol., 2017, vol. 324, pp. 419-28.CrossRefGoogle Scholar
  18. 18.
    Z. Ding, Q. Hu, W. Lu, X. Ge, S. Gao, S. Sun, T. Yang, M. Xia and J. Li: Mater. Charact., 2018, vol. 136, pp. 157-64.CrossRefGoogle Scholar
  19. 19.
    K. Bouche, F. Barbier and A. Coulet: Mater. Sci. Eng. A, 1998, vol. 249, pp. 167-75.CrossRefGoogle Scholar
  20. 20.
    T. Heumann and S. Dittrich: Z. Metallkunde, 1959, vol. 50, pp. 617-25.Google Scholar
  21. 21.
    S. Chen, D. Yang, M. Zhang, J. Huang and X. Zhao: Metall. Mater. Trans. A, 2016, vol. 47, pp. 5088-100.CrossRefGoogle Scholar
  22. 22.
    M.S. Sidhu, C.M. Bishop and M.V. Kral: Int. J. Cast Met. Res., 2014, vol. 27, pp. 321-28.CrossRefGoogle Scholar
  23. 23.
    H. Springer, A. Kostka, E.J. Payton, D. Raabe, A. Kaysser-Pyzalla and G. Eggeler: Acta Mater., 2011, vol. 59, pp. 1586-600.CrossRefGoogle Scholar
  24. 24.
    T. Etter, P. Schulz, M. Weber, J. Metz, M. Wimmler, J.F. Löffler and P.J. Uggowitzer: Mater. Sci. Eng. A, 2007, vol. 448, pp. 1-6.CrossRefGoogle Scholar
  25. 25.
    A. Ureña, J. Rams, M.D. Escalera and M. Sánchez: Compos. Sci. Technol., 2005, vol. 65, pp. 2025-38.CrossRefGoogle Scholar
  26. 26.
    B. Liu, Hot dip aluminizing of steel, Metallurgical Industry Press, Beijing, 1995, pp. 21-23.Google Scholar
  27. 27.
    G. Wang, A. Meng, and Z. Ren: Physical Chemistry, 3rd ed., Shanghai Scientific & Technical Publishers, Shanghai, 2007, pp. 293–302.Google Scholar
  28. 28.
    S. Mei, M. Gao, J. Yan, C. Zhang, G. Li and X. Zeng: Sci. Technol. Weld. Joining, 2013, vol. 18(4), pp. 293-300.CrossRefGoogle Scholar
  29. 29.
    R.W. Richards, R.D. Jones, P.D. Clements and H. Clarke: Int. Mater. Rev, 1994, vol.39, pp. 191-212.CrossRefGoogle Scholar
  30. 30.
    N. Tang, Y. Li, Y. Koizumi, S. Kurosu and A. Chiba: Corros. Sci., 2013, vol. 73, pp. 54-61.CrossRefGoogle Scholar
  31. 31.
    L.L. Bircumshaw and A.C. Riddiford: Q. Rev. Chem. Soc., 1952, vol. 6, pp. 157-85.CrossRefGoogle Scholar
  32. 32.
    V.N. Yeremenko, Y.V. Natanzon and V.I. Dybkov: J. Mater. Sci., 1981, vol. 16, pp. 1748-56.CrossRefGoogle Scholar
  33. 33.
    J.R. Davis, Metals Handbook Desk Edition. ASM, USA, 1998.Google Scholar
  34. 34.
    V.N. Eremenko, Y.V. Natanzon and V.I. Dybkov: J. Mater. Sci., 1985, vol. 20, pp. 501-07.CrossRefGoogle Scholar
  35. 35.
    H. Rezaei, M.R. Akbarpour and H.R. Shahverdi: JOM, 2015, vol. 67, pp. 1443-50.CrossRefGoogle Scholar
  36. 36.
    J. Mackowiak and L.L. Shreir (1959) J Less Common Met 1(6):456-466.CrossRefGoogle Scholar

Copyright information

© The Minerals, Metals & Materials Society and ASM International 2019

Authors and Affiliations

  • Gaopeng Xu
    • 1
  • Kui Wang
    • 1
    Email author
  • Xianping Dong
    • 1
  • Haiyan Jiang
    • 1
  • Qudong Wang
    • 1
  • Bing Ye
    • 1
  • Wenjiang Ding
    • 1
  1. 1.National Engineering Research Center of Light Alloy Net Forming and the State Key Laboratory of Metal Matrix CompositesShanghai Jiao Tong UniversityShanghaiP.R. China

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