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Metallurgical and Materials Transactions A

, Volume 49, Issue 11, pp 5277–5287 | Cite as

Carbon Clustering in Low-Temperature Bainite

  • Rosalia Rementeria
  • Carlos Capdevila
  • Ricardo Domínguez-Reyes
  • Jonathan D. Poplawsky
  • Wei Guo
  • Esteban Urones-Garrote
  • Carlos Garcia-Mateo
  • Francisca G. Caballero
Article

Abstract

The bainitic ferrite phase formed at temperatures below 573 K (300 °C) in high-carbon high-silicon steels holds an amount of carbon well above that expected from the thermodynamic paraequilibrium with austenite. Diffraction experiments have shown that the ferrite lattice is sufficiently Zener-ordered to possess a tetragonal symmetry, which allows the structures to be supersaturated in carbon. It could be expected that carbon undergoes ordering beyond that indicated by the Zener-ordering temperature as in the early stages of tempering of Fe-based martensites. This study examines the formation of cluster arrangements of carbon within bainitic ferrite and their relationship to the tetragonal distortion.

Notes

Acknowledgments

This research was supported by the Spanish Ministerio de Economia y Competitividad (MINECO) in the form of two Coordinate Projects (ENE2015-70300-C3-2-R and MAT2016-80875-C3-1-R); and the Research Fund for Coal and Steel under the Contract RFSR-CT- 2014-00019. APT was conducted as a part of a user proposal at ORNL’s Center for Nanophase Materials Sciences (CNMS), which is a U.S. Department of Energy Office of Science User Facility. R.R. heartfully thanks R.E. Hackenberg, who provided a good piece of history and insight that greatly assisted the course of this research.

Supplementary material

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Supplementary material 1 (MP4 19891 kb)

References

  1. 1.
    H. K. D. H. Bhadeshia: Proc. R. Soc. A 2010, vol. 466, pp. 3-18.CrossRefGoogle Scholar
  2. 2.
    E. Kozeschnik and H. K. D. H. Bhadeshia: Mater. Sci. Technol. 2008, vol. 24, pp. 343-347.CrossRefGoogle Scholar
  3. 3.
    F. G. Caballero, M. K. Miller, S. S. Babu and C. Garcia-Mateo: Acta Mater. 2007, vol. 55, pp. 381-390.CrossRefGoogle Scholar
  4. 4.
    F. G. Caballero, M. K. Miller and C. Garcia-Mateo: Acta Mater. 2010, vol. 58, pp. 2338-2343.CrossRefGoogle Scholar
  5. 5.
    F. G. Caballero, M. K. Miller, C. Garcia-Mateo, J. Cornide and M. J. Santofimia: Scr. Mater. 2012, vol. 67, pp. 846-849.CrossRefGoogle Scholar
  6. 6.
    I. B. Timokhina, H. Beladi, X. Y. Xiong, Y. Adachi and P. D. Hodgson: Acta Mater. 2011, vol. 59, pp. 5511-5522.CrossRefGoogle Scholar
  7. 7.
    C. Garcia-Mateo, J. A. Jimenez, H. W. Yen, M. K. Miller, L. Morales-Rivas, M. Kuntz, S. P. Ringer, J. R. Yang and F. G. Caballero: Acta Mater. 2015, vol. 91, pp. 162-173.CrossRefGoogle Scholar
  8. 8.
    C. N. Hulme-Smith, I. Lonardelli, A. C. Dippel and H. K. D. H. Bhadeshia: Scr. Mater. 2013, vol. 69, pp. 409-412.CrossRefGoogle Scholar
  9. 9.
    C. N. Hulme-Smith, M. J. Peet, I. Lonardelli, A. C. Dippel and H. K. D. H. Bhadeshia: Mater. Sci. Technol. 2015, vol. 31, pp. 254-256.CrossRefGoogle Scholar
  10. 10.
    I. B. Timokhina, K. D. Liss, D. Raabe, K. Rakha, H. Beladi, X. Y. Xiong and P. D. Hodgson: J. Appl. Crystallogr. 2016, vol. 49.CrossRefGoogle Scholar
  11. 11.
    R. Rementeria, J. D. Poplawsky, M. M. Aranda, W. Guo, J. A. Jimenez, C. Garcia-Mateo and F. G. Caballero: Acta Mater. 2017, vol. 125, pp. 359-368.CrossRefGoogle Scholar
  12. 12.
    F. D. Geuser and W. Lefebvre: Microsc. Res. Tech. 2011, vol. 74, pp. 257-263.CrossRefGoogle Scholar
  13. 13.
    T. Philippe, F. De Geuser, S. Duguay, W. Lefebvre, O. Cojocaru-Mirédin, G. Da Costa and D. Blavette: Ultramicroscopy 2009, vol. 109, pp. 1304-1309.CrossRefGoogle Scholar
  14. 14.
    K. Han, M. J. Van Genderen, A. Böttger, H. W. Zandbergen and E. J. Mittemeijer: Philosophical Magazine A: Physics of Condensed Matter, Structure, Defects and Mechanical Properties 2001, vol. 81, pp. 741–757.CrossRefGoogle Scholar
  15. 15.
    C. Zener: Trans. Am. Inst. Min. Metall. Eng. 1946, vol. 167, pp. 550-95.Google Scholar
  16. 16.
    G. R. Speich and W. C. Leslie: Metall. Trans. A 1972, vol. 3, pp. 1043-54.CrossRefGoogle Scholar
  17. 17.
    D. Kalish and M. Cohen: Mater. Sci. Eng. A 1970, vol. 6, pp. 156-66.CrossRefGoogle Scholar
  18. 18.
    S. Nagakura, K. Shiraishi and Y. Hirotsu: Trans. JIM 1975, vol. 16, pp. 601-02.CrossRefGoogle Scholar
  19. 19.
    K. A. Taylor, L. Chang, G. B. Olson, G. D. Smith, M. Cohen and J. B. V. Sande: Metall. Mater. Trans. A 1989, vol. 20, pp. 2717-2737.CrossRefGoogle Scholar
  20. 20.
    M.J. Van Genderen, M. Isac, A. Bottger and E.J. Mittemeijer: Metall. Mater. Trans. A 1997, vol. 28 A, pp. 545–61.Google Scholar
  21. 21.
    M. Kusunoki and S. Nagakura: J. Appl. Crystallogr. 1981, vol. 14, pp. 329-336.CrossRefGoogle Scholar
  22. 22.
    Y. Hirotsu and S. Nagakura: Trans. JIM 1974, vol. 15, pp. 129-134.CrossRefGoogle Scholar
  23. 23.
    S. Nagakura, Y. Hirotsu, M. Kusunoki, T. Suzuki and Y. Nakamura: Metall. Trans. A 1983, vol. 14, pp. 1025-1031.CrossRefGoogle Scholar
  24. 24.
    S. Kajiwara, S. Uehara and Y. Nakamura: Philos. Mag. Lett. 1989, vol. 60, pp. 147-153.CrossRefGoogle Scholar
  25. 25.
    Y. Hirotsu and S. Nagakura: Acta Metall. 1972, vol. 20, pp. 645-655.CrossRefGoogle Scholar
  26. 26.
    Y. Hirotsu, Y.I. Itakura, K.-C. Su and S. Nagakura: Trans. JIM 1976, vol. 17, pp. 503–13.CrossRefGoogle Scholar
  27. 27.
    K. A. Taylor, G. B. Olson, M. Cohen and J. B. V. Sande: Metall. Trans. A 1989, vol. 20, pp. 2749-2765.CrossRefGoogle Scholar
  28. 28.
    T. Sourmail, F. Danoix, C. Garcia-Mateo, F.G. Caballero, R. Rementeria, L. Morales-Rivas, R. Pizzaro, R. Janisch, S. Sampath, I. Mueller, E. Kerscher, and M. Kuntz: Understanding basic mechanism to optimize and predict in service properties of nanobainitic steels (MECBAIN). (European Commission Directorate-General for Research and Innovation Directorate D—Industrial Technologies Unit D.4—Coal and Steel, 2017).Google Scholar
  29. 29.
    L. Morales-Rivas: Advisors: Carlos Garcia-Mateo and Caballero Francisca G (2016).Google Scholar
  30. 30.
    R. Rementeria, I. García, M. M. Aranda and F. G. Caballero: Wear 2015, vol. 338–339, pp. 202-09.CrossRefGoogle Scholar
  31. 31.
    K. Thompson, D. Lawrence, D. J. Larson, J. D. Olson, T. F. Kelly and B. Gorman: Ultramicroscopy 2007, vol. 107, pp. 131-39.CrossRefGoogle Scholar
  32. 32.
    K.A. Taylor: Massachusetts Institute of Technology. Department of Materials Science and Engineering. Advisors: Gregory B. Olson and Morris Cohen John B. Vander Sande (1985).Google Scholar
  33. 33.
    Y. Tanaka, K. Shimizu: rsquo and ichi: Trans. JIM 1981, vol. 22, pp. 779-88.Google Scholar
  34. 34.
    B. P. J. Sandvik and C. M. Wayman: Metallography 1983, vol. 16, pp. 429-447.CrossRefGoogle Scholar
  35. 35.
    R. Rementeria, J. A. Jimenez, S. Y. P. Allain, G. Geandier, J. D. Poplawsky, W. Guo, E. Urones-Garrote, C. Garcia-Mateo and F. G. Caballero: Acta Mater. 2017, vol. 133, pp. 333-345.CrossRefGoogle Scholar
  36. 36.
    J. Wilde, A. Cerezo and G. D. W. Smith: Scripta Materialia 2000, vol. 43, pp. 39-48.CrossRefGoogle Scholar
  37. 37.
    F. G. Caballero, M. K. Miller and C. Garcia-Mateo: Materials Science and Technology 2010, vol. 26, pp. 889-898.CrossRefGoogle Scholar
  38. 38.
    O. C. Hellman, J. A. Vandenbroucke, J. Rüsing, D. Isheim and D. N. Seidman: Microsc. Microanal. 2000, vol. 6, pp. 437-444.Google Scholar
  39. 39.
    D. J. Larson, T. J. Prosa, R. M. Ulfig, B. P. Geiser, T. F. Kelly and C. J. Humphreys: Local Electrode Atom Probe Tomography: A User’s Guide. (Springer New York, 2013).CrossRefGoogle Scholar
  40. 40.
    M.K. Miller and R.G. Forbes: Atom Probe Tomography: The Local Electrode Atom Probe. (Springer, New York, 2014).Google Scholar
  41. 41.
    O. C. Hellman, J. B. du Rivage and D. N. Seidman: Ultramicroscopy 2003, vol. 95, pp. 199-205.CrossRefGoogle Scholar
  42. 42.
    F. Danoix, P. Auger, A. Bostel and D. Blavette: Surf. Sci. 1991, vol. 246, pp. 260-265.CrossRefGoogle Scholar
  43. 43.
    J. M. Cairney, K. Rajan, D. Haley, B. Gault, P. A. J. Bagot, P.-P. Choi, P. J. Felfer, S. P. Ringer, R. K. W. Marceau and M. P. Moody: Ultramicroscopy 2015, vol. 159, Part 2, pp. 324-337.CrossRefGoogle Scholar
  44. 44.
    F. G. Caballero, M. K. Miller, C. Garcia-Mateo, C. Capdevila and S. S. Babu: Acta Mater. 2008, vol. 56, pp. 188-199.CrossRefGoogle Scholar
  45. 45.
    F. G. Caballero, M. K. Miller and C. Garcia-Mateo: Metall. Mater. Trans. B 2011, vol. 42A, pp. 3660-3668.CrossRefGoogle Scholar
  46. 46.
    J. Takahashi, K. Kawakami and Y. Kobayashi: Ultramicroscopy 2011, vol. 111, pp. 1233-1238.CrossRefGoogle Scholar
  47. 47.
    G. Miyamoto, K. Shinbo and T. Furuhara: Scr. Mater. 2012, vol. 67, pp. 999-1002.CrossRefGoogle Scholar
  48. 48.
    L. Cheng, A. Boeattger, T. H. de Keijser and E. J. Mittemeijer: Scr. Metall. Mater. 1990, vol. 24, pp. 509-514.CrossRefGoogle Scholar
  49. 49.
    L. Chang, A. Cerezo, G. Smith, M. Miller, M. Burke, S. Brenner, K. Taylor, T. Abe and G. Olson: Le Journal de Physique Colloques 1984, vol. 45, pp. C9-409–C9-416.Google Scholar
  50. 50.
    C. W. Sinclair, M. Perez, R. G. A. Veiga and A. Weck: Phys. Rev. B 2010, vol. 81, p. 224204.CrossRefGoogle Scholar
  51. 51.
    M. J. Van Genderen, A. Böttger, R. J. Cernik and E. J. Mittemeijer: Metall. Trans. A 1993, vol. 24, pp. 1965-1973.CrossRefGoogle Scholar
  52. 52.
    M. J. Van Genderen, A. Böttger and E. J. Mittemeijer: Metall. Mater. Trans. A 1997, vol. 28, pp. 63-77.CrossRefGoogle Scholar
  53. 53.
    53. Jack KH (1951) Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 208:200–215CrossRefGoogle Scholar
  54. 54.
    S. Allain, F. Danoix, M. Goune, K. Hoummada and D. Mangelinck: Philos. Mag. Lett. 2013, vol. 93, pp. 68-76.CrossRefGoogle Scholar
  55. 55.
    B. Kim, J. Sietsma and M. J. Santofimia: Philos. Mag. 2016, vol. 96, pp. 2632-2648.CrossRefGoogle Scholar
  56. 56.
    C. Zhu, A. Cerezo and G. D. W. Smith: Ultramicroscopy 2009, vol. 109, pp. 545-552.CrossRefGoogle Scholar
  57. 57.
    M. Herbig, R.K.W. Marceau, L. Morsdorf, and D. Raabe: In PTM 2015 - Proceedings of the International Conference on Solid-Solid Phase Transformations in Inorganic Materials 2015, (2015), pp 299–300.Google Scholar
  58. 58.
    S. Curelea, S. Cazottes, T. Epicier, F. Danoix, H. Zapolsky, M. Lavrskyi, P. Maugis, S. Chentouf and M. Goune: In European Microscopy Congress 2016, (Wiley-VCH Verlag GmbH & Co. KGaA: Lyon, France, 2016).Google Scholar
  59. 59.
    59. Kurdjumov GV, Khachaturyan AG (1972) Metall. Trans. A 3(5):1069–1076CrossRefGoogle Scholar
  60. 60.
    M. Kusunoki and S. Nagakura: Trans. JIM 1984, vol. 25, pp. 517-522.CrossRefGoogle Scholar
  61. 61.
    A. M. Sherman, G. T. Eldis and M. Cohen: Metall. Trans. A 1983, vol. 14, pp. 995-1005.CrossRefGoogle Scholar
  62. 62.
    D. W. Hoffman and M. Cohen: Acta Metall. 1973, vol. 21, pp. 1215-1223.CrossRefGoogle Scholar
  63. 63.
    P. Ferguson and K. H. Jack: Scr. Metall. 1984, vol. 18, pp. 1189-1194.CrossRefGoogle Scholar
  64. 64.
    S. B. Ren and S. T. Wang: Metall. Trans. A 1988, vol. 19, pp. 2427-2432.CrossRefGoogle Scholar
  65. 65.
    R. Kaplow, M. Ron and N. DeCristofaro: Metall. Trans. A 1983, vol. 14, pp. 1135-1145.CrossRefGoogle Scholar
  66. 66.
    M. Hayakawa, M. Tanigami and M. Oka: Metall. Trans. A 1985, vol. 16, pp. 1745-1750.CrossRefGoogle Scholar
  67. 67.
    G. B. Olson and M. Cohen: Metall. Trans. A 1983, vol. 14, pp. 1057-1065.CrossRefGoogle Scholar
  68. 68.
    K. A. Taylor and M. Cohen: Prog. Mater. Sci. 1992, vol. 36, pp. 151-272.CrossRefGoogle Scholar
  69. 69.
    Y. Ni, W. Rao and A. G. Khachaturyan: Nano Lett. 2009, vol. 9, pp. 3275-3281.CrossRefGoogle Scholar
  70. 70.
    R. Naraghi, M. Selleby and J. Ågren: Calphad 2014, vol. 46, pp. 148-158.CrossRefGoogle Scholar
  71. 71.
    K. A. Taylor, J. B. V. Sande and M. Cohen: Metall. Mater. Trans. A 1993, vol. 24, pp. 2585-2588.CrossRefGoogle Scholar
  72. 72.
    Y. Ohmori and I. Tamura: Metall. Mater. Trans. A 1992, vol. 23, pp. 2147-2158.CrossRefGoogle Scholar
  73. 73.
    73. Miller MK, Beaven PA, Brenner SS, Smith GDW (1983) Metall. Trans. A 14A:1021–1024Google Scholar
  74. 74.
    M. Herbig, D. Raabe, Y. J. Li, P. Choi, S. Zaefferer and S. Goto: Phys. Rev. Lett. 2014, vol. 112, p. 126103.CrossRefGoogle Scholar
  75. 75.
    M. Herbig, M. Kuzmina, C. Haase, R. K. W. Marceau, I. Gutierrez-Urrutia, D. Haley, D. A. Molodov, P. Choi and D. Raabe: Acta Mater. 2015, vol. 83, pp. 37-47.CrossRefGoogle Scholar
  76. 76.
    D. H. Sherman, S. M. Cross, S. Kim, F. Grandjean, G. J. Long and M. K. Miller: Metall. Mater. Trans. A 2007, vol. 38, pp. 1698-1711.CrossRefGoogle Scholar
  77. 77.
    S. B. Hosseini, M. Thuvander, U. Klement, G. Sundell and K. Ryttberg: Acta Mater. 2017, vol. 130, pp. 155-163.CrossRefGoogle Scholar
  78. 78.
    B. Hutchinson, J. Hagström, O. Karlsson, D. Lindell, M. Tornberg, F. Lindberg and M. Thuvander: Acta Mater. 2011, vol. 59, pp. 5845-5858.CrossRefGoogle Scholar
  79. 79.
    G. A. Thomas, F. Danoix, J. G. Speer, S. W. Thompson and F. Cuvilly: ISIJ Int. 2014, vol. 54, pp. 2900-2906.CrossRefGoogle Scholar
  80. 80.
    A. J. Clarke, M. K. Miller, R. D. Field, D. R. Coughlin, P. J. Gibbs, K. D. Clarke, D. J. Alexander, K. A. Powers, P. A. Papin and G. Krauss: Acta Mater. 2014, vol. 77, pp. 17-27.CrossRefGoogle Scholar
  81. 81.
    S. Sampath, R. Rementeria, X. Huang, J. D. Poplawsky, C. Garcia-Mateo, F. G. Caballero and R. Janisch: J. Alloys Compd. 2016, vol. 673, pp. 289-294.CrossRefGoogle Scholar
  82. 82.
    G. Martin: Phys. Rev. B 1980, vol. 21, pp. 2122-2130.CrossRefGoogle Scholar
  83. 83.
    R. Cauvin and G. Martin: J. Nucl. Mater. 1979, vol. 83, pp. 67-78.CrossRefGoogle Scholar
  84. 84.
    R. Naraghi and M. Selleby: In Proceedings of the 1st World Congress on Integrated Computational Materials Engineering (ICME), ed. Peter Collins and George Spanos John Allison (John Wiley & Sons: 2011), pp 235–40.Google Scholar
  85. 85.
    J. W. Cahn: Acta Metall. 1962, vol. 10, pp. 179-183.CrossRefGoogle Scholar
  86. 86.
    W. C. Leslie: Acta Metall. 1961, vol. 9, pp. 1004-1022.CrossRefGoogle Scholar
  87. 87.
    Z. Mathalone, M. Ron and S. Niedzwiedz: J. Mater. Sci. 1971, vol. 6, pp. 957-963.CrossRefGoogle Scholar

Copyright information

© The Minerals, Metals & Materials Society and ASM International 2018

Authors and Affiliations

  • Rosalia Rementeria
    • 1
    • 2
  • Carlos Capdevila
    • 1
  • Ricardo Domínguez-Reyes
    • 3
  • Jonathan D. Poplawsky
    • 4
  • Wei Guo
    • 4
  • Esteban Urones-Garrote
    • 5
  • Carlos Garcia-Mateo
    • 1
  • Francisca G. Caballero
    • 1
  1. 1.Department of Physical MetallurgySpanish National Center for Metallurgical Research (CENIM-CSIC)MadridSpain
  2. 2.Additive Manufacturing – New FrontierArcelorMittal Global R&DAvilésSpain
  3. 3.Departamento de FísicaUniversidad Carlos III de MadridLeganésSpain
  4. 4.Center for Nanophase Materials SciencesOak Ridge National LaboratoryOak RidgeUSA
  5. 5.Spanish National Centre for Electron Microscopy (CNME), Facultad de Ciencias QuímicasUniversidad Complutense de MadridMadridSpain

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