Quantifying the Solute Drag Effect of Cr on Ferrite Growth Using Controlled Decarburization Experiments
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Abstract
The effect of Cr on the kinetics of ferrite growth from austenite was studied using the technique of controlled decarburization over the temperature range 850 °C to 775 °C. At 850 °C, the observed ferrite growth kinetics is in excellent agreement with the predictions of the local equilibrium negligible partition (LENP) model. At temperatures below 850 °C, the growth kinetics becomes increasingly slower than the predictions of the LENP model. This was interpreted in terms of the solute-drag effect of Cr, and the cross-boundary diffusion coefficient of Cr was estimated.
Keywords
Ferrite Austenite Decarburization Solute Drag Ferrite Growth
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Notes
Acknowledgment
One of the authors (HSZ) gratefully acknowledges the financial support of the Natural Science and Engineering Research Council of Canada.
References
- 1.H.K.D.H. Bhadeshia: Prog. Mater. Sci., 1985, vol. 29, pp. 321–86CrossRefGoogle Scholar
- 2.A. Van der Ven, L. Delaey: Prog. Mater. Sci., 1996, vol. 40, pp. 181–264CrossRefGoogle Scholar
- 3.G.R. Purdy, J.S. Kirkaldy: Trans. AIME, 1963, vol. 227, pp. 1255–66Google Scholar
- 4.S. Crusius, L. Hoglund, U. Knoop, G. Inden, J. Ågren: Z. Metallkd., 1992, vol. 83, pp. 729–38Google Scholar
- 5.Available from Thermo-Calc Software, http://www.thermocalc.com
- 6.J. Ågren: Acta Metall., 1982, vol. 30, pp. 841–51CrossRefGoogle Scholar
- 7.J. Ågren: Scripta Metall., 1986, vol. 20, pp. 1507–10CrossRefGoogle Scholar
- 8.G.R. Purdy, D.H. Weichert, J.S. Kirkaldy: Trans. AIME, 1964, vol. 230, pp. 1025–34Google Scholar
- 9.H.I. Aaronson, H.A. Domian: Trans. AIME, 1966, vol. 236, pp. 781–96Google Scholar
- 10.J.B. Gilmour, G.R. Purdy, J.S. Kirkaldy: Metall. Trans., 1972, vol. 3, pp. 3213–22CrossRefGoogle Scholar
- 11.M. Hillert: “Paraequilibrium,” Internal Report, Swedish Institute of Metals, Stockholm, Sweden, 1953Google Scholar
- 12.J.S. Kirkaldy: Can. J. Phys., 1958, vol. 36, pp. 907–17Google Scholar
- 13.M. Hillert: The Mechanism of Phase Transformation in Crystalline Solids, Institute of Metals, London, 1969, pp. 231–47Google Scholar
- 14.A. Phillion, H.S. Zurob, C.R. Hutchinson, H. Guo, D.V. Malakhov, J. Nakano, G.R. Purdy: Metall. Mater. Trans. A, 2004, vol. 35A, pp. 1237–42CrossRefGoogle Scholar
- 15.C.R. Hutchinson, H.S. Zurob, Y. Brechet: Metall. Mater. Trans. A, 2006, vol. 37A, pp. 1711–20CrossRefGoogle Scholar
- 16.H.S. Zurob, C.R. Hutchinson, Y. Bréchet, and G.R. Purdy: in Solid-Solid Phase Transformations in Inorganic Materials, TMS, Warrendale, PA, 2005, pp. 111–16Google Scholar
- 17.W.D. Murry, F. Landis: Trans. ASME, 1959, vol. 81D, pp. 106–12Google Scholar
- 18.B. Jönsson: Z. Metallkd., 1992, vol. 83, pp. 349–55Google Scholar
- 19.J.W. Cahn: Acta Metall., 1962, vol. 10, pp. 789–98CrossRefGoogle Scholar
- 20.M. Hillert, B. Sundman: Acta Metall., 1976, vol. 24, pp. 731–43CrossRefGoogle Scholar
- 21.G.R. Purdy, Y.J.M. Brechet: Acta Metall. Mater., 1995, vol. 43, pp. 3763–74CrossRefGoogle Scholar
- 22.C.R. Hutchinson, A. Fuchsmann, Y. Brechet: Metall. Mater. Trans. A, 2004, vol. 35A, pp. 1211–21CrossRefGoogle Scholar
- 23.E.D. Hondros, M.P. Seah: Int. Met. Rev., 1977, vol. 22, pp. 262–301Google Scholar
- 24.Smithells Metals Reference Book, 8th ed., W.F. Gale and T.C. Totemeier, eds., Elsevier, New York, NY, 2004Google Scholar
- 25.P. Maugis, G. Martin: Phys. Rev. B: Condens. Matter Mater. Phys., 1994, vol. 49, pp. 11580–87Google Scholar
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