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Organic geochemistry of the Lower Permian Tak Fa Formation in Phetchabun Province, Thailand: implications for its paleoenvironment and hydrocarbon generation potential

  • Piyaphong ChenraiEmail author
  • Supawich Fuengfu
Original Article
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Abstract

The outcrop samples of the Tak Fa Formation (Lower Permian) in Phetchabun Province have been studied to determine their organic geochemical characteristic, depositional paleoenvironment, and hydrocarbon generation potential. The total organic carbon (TOC) values ranging from 1.42  to 4.58 wt% and extractable organic matter values ranging from 76.84 to 197.65 ppm of the Tak Fa Formation were generally low and associated with low S2 values (0.00–0.50 mg HC/g rock) and hydrogen index values in range of 0–32 mg/g TOC, although this could reflect highly thermal maturity and complex tectonic history. Thus, kerogen classification can be based on a non-biomarker study for these outcrop samples instead. The non-biomarker plot, Pr/n-C17 and Ph/n-C18 from this study indicates that organic matter originally comes from type II/III kerogen. The samples were also investigated and indicated that the organic matter inputs were derived from mixed marine and terrigenous sources and deposited under suboxic to oxic conditions. The depositional environment of the Tak Fa Formation in this study is interpreted to be an estuarine environment or restricted lagoonal carbonate platforms. This has been achieved from normal alkane and isoprenoids distributions, terpane, and sterane biomarkers. Thus, the Tak Fa Formation is considered to be a hydrocarbon source rock during the time of the deposition. Although the geochemical data in this study indicate that the Tak Fa Formation has experienced high maturation, one or more locations could meet a condition that places this formation to be an active source rock. The approach and concepts presented in this study can be applied to similar evaporite-carbonate deposits in Thailand to find more petroleum plays.

Keywords

Biomarker Depositional environment Source inputs Tak Fa Formation Khao Khwang Platform 

Notes

Acknowledgements

The authors gratefully acknowledge the financial support from the Ratchadaphisek Somphot Endowment Fund under Outstanding Research Performance Program, Science Super III (Department)-009, Chulalongkorn University. Anonymous reviewers are thanked for their useful and constructive comments.

References

  1. Adelzadeh MR, Hatampour A, Ghiasi-Freez J (2014) Hydrocarbon potential of Kangan and Dalan formations using organic geochemistry, mineralogy, and petrography. Pet Sci Technol 32:2159–2167CrossRefGoogle Scholar
  2. Akande WG (2012) A review of experimental procedures of gas chromatography-mass spectrometry (GC-MS) and possible sources of analytical errors. Earth Sci 1(1):1–9Google Scholar
  3. Alkhafaji MW, Aljubouri ZA, Aldobouni IA, Littke R (2015) Hydrocarbon potential of Ordovician–Silurian successions in Akkas field, western desert of Iraq. AAPG Bull 9:617–637CrossRefGoogle Scholar
  4. Amane W, Hideki N (1997) Geochemical characteristics of terrigenous and marine sourced oils in Hokkaido, Japan. Org Geochem 28:27–41Google Scholar
  5. Behar F, Beaumont V, De B, Penteado HL (2001) Rock-Eval 6 Technology: performances and developments. Oil & Gas Science and Technology 56:111–134CrossRefGoogle Scholar
  6. Booth JE, Sattayarak N (2011) Subsurface Carboniferous-Cretaceous geology of northeast Thailand. In: Ridd MF, Barber AJ, Crow MJ (eds) The geology of Thailand. Geological Society, London, pp 184–222Google Scholar
  7. Bunopas S (1983) Palaeozoic succession in Thailand. In: Nutalaya P (ed) Proceedings of the workshop on stratigraphic correlation of Thailand and Malaysia: Haad Yai, Thailand, vol 1, pp 39–76Google Scholar
  8. Chandra K, Mishra CS, Samanta U, Gupta A, Mehrotra KL (1994) Correlation of different maturity parameters in the AhmedabadeMehsana block of the Cambay basin. Org Geochem 21:313–321CrossRefGoogle Scholar
  9. Chitnarin A, Crasquin S, Chonglakmani C, Broutin J, Grote PJ, Thanee N (2008) Middle Permian ostracods from Tak Fa Limestone, Phetchabun Province, central Thailand. Geobios 41(3):341–353CrossRefGoogle Scholar
  10. Chitnarin A, Crarquin S, Charoentitirat T, Tepnarong P, Thanee N (2012) Ostracods (Crustacea) of the early-Middle Permian from Central thailand (indochina block). Part I. Order Palaeocopida. Geodiversitas 34:801–836CrossRefGoogle Scholar
  11. Chonglakmani C, Fontaine H (2000) The lam Narai-Phetchabun region: a platform of Early Carboniferous to Late Permian age. In: Proceedings of the development geology of Thailand into the year 2000, pp 39–98Google Scholar
  12. Chonglakmani C, Helmcke D (2001) Geodynamic Evolution of Loei and Phetchabun Regions—Does the Discovery of Detrital Chromian Spinels from the Nam Duk Formation (Permian, North-Central Thailand) Provide New Constraint? Gondwana Res 3:437–442CrossRefGoogle Scholar
  13. Chonglakmani C, Sattayarak N (1984) Geological map of sheet Changwat Phetchabun (NE 47-16), scale 1:250,000: Department of Mineral Resources. Bangkok, ThailandGoogle Scholar
  14. Erik NY (2016) Paleoenvironment characteristics and hydrocarbon potential of the Lower Miocene bituminous shales in Sivas Basin (Central Anatolia, Turkey). Arab J Geosci 9(1):18CrossRefGoogle Scholar
  15. Gerdes G, Krumbein WE, Reineck HE (1991) Biolaminations: Ecological versus depositional dynamics. In: Einsele G, Ricken W, Seilacher A (eds) Cycles and events in stratigraphy. Springer, Berlin, pp 592–607Google Scholar
  16. Hakimi MH, Abdullah WH, Shalaby MR (2012) Molecular composition and organic petrographic characterization of Madbi source rocks from the Kharir oilfield of the Masila Basin (Yemen): palaeoenvironmental and maturity interpretation. Arab J Geosci 5:817–831CrossRefGoogle Scholar
  17. Hatampour A (2014) Using Rock Eval pyrolysis for studying the hydrocarbon potential of the Pabdeh Formation in Ziluee oilfield, south west of Iran. Pet Sci Technol 32:1586–1597CrossRefGoogle Scholar
  18. Hunt JM (1996) Petroleum geochemistry and geology, 2nd edn. W.H. Freeman and Company, New York, p 743Google Scholar
  19. Kenig F, Huc AY, Purser BH, Oudin JL (1990) Sedimentation, distribution and diagenesis of organic matter in a recent carbonate environment, Abu Dhabi, United Arab Emirates. Org Geochem 16:735–747CrossRefGoogle Scholar
  20. Large DJ, Gize AP (1996) Pristane/phytane ratios in the mineralized Kupferschiefer of the Fore-Sudetic Monocline, southwest Poland. Ore Geol Rev 11:89–103CrossRefGoogle Scholar
  21. Li H, Jiang L, Chen X, Zhang M (2015) Identification of the four rearranged hopane series in geological bodies and their geochemical significances. Chin J Geochem 34:550–557CrossRefGoogle Scholar
  22. Lijmbach W (1975) SP (1) on the origin of petroleum. In: 9th World petroleum congressGoogle Scholar
  23. Littke R, Klussmann U, Krooss B, Leythaeuser D (1991) Quantification of loss of calcite, pyrite, and organic matter due to weathering of Toarcian black shales and effects on kerogen and bitumen characteristics. Geochim Cosmochim Acta 55(11):3369–3378CrossRefGoogle Scholar
  24. Mackenzie A, Li RW, Maxwell J, Moldowan J, Seifert W (1981) Molecular measurements of thermal maturation of Cretaceous shales from the Overthrust Belt, Wyoming. Adv Org Geochem, USA, p 503Google Scholar
  25. Marynowski L, Kurkiewicz S, Rakociński M, Simoneit BR (2011) Effects of weathering on organic matter: I. Changes in molecular composition of extractable organic compounds caused by paleoweathering of a Lower Carboniferous (Tournaisian) marine black shale. Chem Geol 285:144–156CrossRefGoogle Scholar
  26. Metcalfe I, Sone M (2008) Biostratigraphy and palaeobiogeography of Lower Permian (lower Kungurian) conodonts from the Tak Fa Formation (Saraburi Limestone), Thailand. Palaeogeogr Palaeoclimatol Palaeoecol 257(1–2):139–151CrossRefGoogle Scholar
  27. Miles JA (1989) Illustrated glossary of petroleum geochemistry. Oxford University, OxfordGoogle Scholar
  28. Moldowan JM, Seifert WK, Gallegos EJ (1985) Relationship between petroleum composition and depositional environment of petroleum source rocks. AAPG Bull 69:1255–1268Google Scholar
  29. Moldowan JM, Sundararaman P, Schoell M (1986) Sensitivity of biomarker properties to depositional environment and/or source input in the Lower Toarcian of SW-Germany. Org Geochem 10:915–926CrossRefGoogle Scholar
  30. Morley CK, Ampaiwan P, Thanudamrong S, Kuenphan N, Warren J (2013) Development of the Khao Khwang fold and thrust belt: implications for the geodynamic setting of Thailand and Cambodia during the Indosinian orogeny. J Asian Earth Sci 62:705–719CrossRefGoogle Scholar
  31. Moustafa YM, Morsi RE (2012) Biomarkers. In: Dhanarasu S (ed) Chromatography and its applications. Intech, Croatia, pp 165–186Google Scholar
  32. Murray AP, Boreham CJ (1992) Organic geochemistry in petroleum exploration. Australian Geological Survey Organization, Canberra, p 230Google Scholar
  33. Peters KE (1986) Guidelines for evaluating petroleum source rock using programmed pyrolysis. AAPG Bull 70:318–329Google Scholar
  34. Peters KE, Cassa MR (1994) Applied source rock geochemistry. In: Magoon LB, Dow WG (eds) The petroleum system from source to trap. American Association of Petroleum Geologists, Tulsa, pp 93–120Google Scholar
  35. Peters KE, Moldowan JM (1993) The biomarker guide: interpreting molecular fossils in petroleum and ancient sediments. Pentice Hall, Englewood CliffGoogle Scholar
  36. Peters KE, Clark ME, Das Gupta U, McCaffrey MA, Lee CY (1995) Recognition of an Infracambrian source rock based on biomarkers in the Baghewala-1 oil, India. AAPG Bull 79:1481–1494Google Scholar
  37. Peters KE, Walters CC, Moldowan JM (2005) The biomarker guide, vol 1. Cambridge University Press, Cambridge, pp 1–471Google Scholar
  38. Peters KE, Walters CC, Moldowan JM (2007) The biomarker guide, vol 2. Cambridge University Press, Cambridge, pp 475–708Google Scholar
  39. Powell TG (1988) Pristane/phytane ratio as environmental indicator. Nature 333:604CrossRefGoogle Scholar
  40. Racey A (2011) Petroleum geology. In: Ridd MF, Barber AJ, Crow MJ (eds) The geology of Thailand. The Geological Society, London, pp 351–392CrossRefGoogle Scholar
  41. Racey A, Love MA, Canham AC, Goodall JGS, Polachan S, Jones PD (1996) Stratigraphy and reservoir potential of the Mesozoic Khorat Group, NE Thailand: part 1: stratigraphy and sedimentary evolution. J Pet Geol 19(1):5–39CrossRefGoogle Scholar
  42. Ridd MF, Barber AJ, Crow MJ (2011) The geology of Thailand. The Geological Society, London, pp 71–136CrossRefGoogle Scholar
  43. Sachse VF, Littke R, Heim S, Kluth O, Schober J, Boutib L, Jabour H, Perssen F, Sindern S (2011) Petroleum source rocks of the Tarfaya Basin and adjacent areas, Morocco. Org Geochem 42(3):209–227CrossRefGoogle Scholar
  44. Seifert WK, Moldowan JM (1986) Use of biological markers in petroleum exploration. In: Johns RB (ed) Methods in geochemistry and geophysics, vol 24. Elsevier, Amsterdam, pp 261–290Google Scholar
  45. Shanmugam G (1985) Significance of coniferous rain forests and related organic matter in generating commercial quantities of oil, Gippsland Basin, Australia. AAPG Bull 69:1241–1254Google Scholar
  46. Sivan P, Datta GC, Singh RR (2008) Aromatic biomarkers as indicators of source, depositional environment, maturity and secondary migration in the oils of Cambay Basin, India. Org Geochem 39:1620–1630CrossRefGoogle Scholar
  47. Sleutel S, De Neve S, Singier B, Hofman G (2007) Quantification of organic carbon in soils: a comparison of methodologies and assessment of the carbon content of organic matter. Commun Soil Sci Plant Anal 38(19–20):2647–2657CrossRefGoogle Scholar
  48. Tissot B, Welte D (1984) Petroleum formation and occurrence: a new approach to oil and gas exploration. Springer, BerlinCrossRefGoogle Scholar
  49. Tissot BP, Deroo G, Hood A (1978) Geochemical study of the Uinta Basin: formation of petroleum from Green river formation. Geochim Cosmochim Acta 42:1469–1485CrossRefGoogle Scholar
  50. Udchachon M, Burrett C, Thassanapak H, Chonglakmani C, Campbell H, Feng Q (2014) Depositional setting and paleoenvironment of an alatoconchid-bearing Middle Permian carbonate ramp sequence in the Indochina Terrane. J Asian Earth Sci 87:37–55CrossRefGoogle Scholar
  51. Villar HJ, Püttmann W, Wolf M (1988) Organic geochemistry and petrography of Tertiary coals and carbonaceous shales from Argentina. Org Geochem 13:1011–1021CrossRefGoogle Scholar
  52. Volkman JK (1986) A review of sterol markers for marine and terrigenous organic matter. Org Geochem 9:83–99CrossRefGoogle Scholar
  53. Volkman JK (2003) Sterols in microorganisms. Appl Microbiol Biotechnol 60(5):495–506CrossRefGoogle Scholar
  54. Volkman JK, Maxwell JR (1986) Acyclic isoprenoids as biological markers. In: Johns RB (ed) Biological markers in the sedimentary record. Elsevier, Amsterdam, pp 1–42Google Scholar
  55. Volkman K, Allen DI, Stevenson PL, Burton HR (1986) Bacterial and algal hydrocarbons from a saline Antarctic lake, Ace Lake. Org Geochem 10:671–681CrossRefGoogle Scholar
  56. Waples DW, Machihara T (1991) Biomarkers for geologists. In: American association of petroleum geologists methods in exploration series, vol 9, pp 91–99Google Scholar
  57. Wieldchowsky CC, Young JD (1985) Regional facies variation in Permian rocks of the Phetchabun Fold and Thrust Belt, Thailand. In: Thanvarachorn P, Hokjaroen S, Youngme W (eds) Procedings on geology and mineral resources development of northeastern Thailand. Khon Kaen University, Khon Kaen, pp 41–55Google Scholar
  58. Yan Y, Huang B, Zhang D, Charusiri P, Veeravinantanakul A (2018) Paleomagnetic study on the Permian rocks of the Indochina Block and its implications for paleogeographic configuration and northward drifting of Cathaysialand in the Paleo-Tethys. J Geophys Res Solid Earth 4523–4538Google Scholar

Copyright information

© Science Press and Institute of Geochemistry, CAS and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Petroleum Geoscience, Faculty of ScienceChulalongkorn UniversityBangkokThailand
  2. 2.Basin Analysis and Structural Evolution Special Task Force for Activating Research (BASE STAR), Department of Geology, Faculty of ScienceChulalongkorn UniversityBangkokThailand

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