Advertisement

Adsorption of Quaternized-chitosan-modified Reduced Graphene Oxide

  • Chuanhang Guo (郭传航)
  • Mingyang Liu (刘明阳)
  • Yuanling Xia
  • Xiaoqiang Fan
  • Yanjun Chen (陈艳军)
  • Chaocan Zhang
Organic Materials

Abstract

A novel quaternized-chitosan-modified reduced graphene oxide (HACC-RGO) combined the adsorption advantages of RGO and 2-Hydroxypropyltrimethyl ammonium chloride chitosan (HACC). The adsorption property of HACC-RGO sheets for methyl orange (MO) was demonstrated and compared with RGO and HACC. The removal ratios of HACC-RGO sheets reached 92.6% for MO after a 24 h adsorption. The adsorption kinetics, isotherms and thermodynamics were investigated to indicate that the kinetics and equilibrium adsorptions were well-described by pseudo-second-order kinetic and Freundlich isotherm model, respectively. The thermodynamic parameters suggested that the adsorption process was spontaneous and endothermic in nature. Moreover, monodisperse HACC-RGO/CS beads were fabricated by the microfluidic method. The adsorption and desorption of HACC-RGO/CS beads for MO were studied. After three adsorption-desorption cycles, the adsorption capacity remained above 55% and the desorption capacity was not below 70%. The HACC-RGO/CS beads can be reused and have great potential applications in removing organic dyes from polluted water.

Key words

reduced graphene oxide chitosan adsorption adsorption kinetic 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. [1]
    Luk CJ, Yip J, Yuen CM, et al. A Comprehensive Study on Adsorption Behaviour of Direct, Reactive and Acid Dyes on Crosslinked and Non-crosslinked Chitosan Beads[J]. Journal of Fiber Bioengineering and Informatics, 2014, 7 (1): 35–52Google Scholar
  2. [2]
    Chiou MS, Li HY. Adsorption Behavior of Reactive Dye in Aqueous Solution on Chemical Cross-linked Chitosan Beads[J]. Chemosphere, 2003, 50 (8): 1095–1105CrossRefGoogle Scholar
  3. [3]
    Chiou MS, Li HY. Equilibrium and Kinetic Modeling of Adsorption of Reactive Dye on Cross-linked Chitosan Beads[J]. Journal of Hazardous Materials, 2002, 93 (2): 233–248CrossRefGoogle Scholar
  4. [4]
    Wu T, Cai X, Tan S, et al. Adsorption Characteristics of Acrylonitrile, p-toluenesulfonic Acid, 1-naphthalenesulfonic Acid and Methyl Blue on Graphene in Aqueous Solutions[J]. Chemical Engineering Journal, 2011, 173 (1): 144–149CrossRefGoogle Scholar
  5. [5]
    Zhao G, Li J, Wang X. Kinetic and Thermodynamic Study of 1-naphthol Adsorption from Aqueous Solution to Sulfonated Graphene Nanosheets[J]. Chemical Engineering Journal, 2011, 173 (1): 185–190CrossRefGoogle Scholar
  6. [6]
    Tang Y, Hu T, Zeng Y, et al. Effective Adsorption of Cationic Dyes by Lignin Sulfonate Polymer Based on Simple Emulsion Polymerization: Isotherm and Kinetic Studies[J]. Rsc. Advances, 2014, 5 (5): 3757–3766CrossRefGoogle Scholar
  7. [7]
    Georgakilas V, Otyepka M, Bourlinos AB, et al. Functionalization of Graphene: Covalent and Non-covalent Approaches, Derivatives and Applications[J]. Chemical Reviews, 2012, 112 (11): 6156–6214CrossRefGoogle Scholar
  8. [8]
    Stankovich S, Piner RD, Chen X, et al. Stable Aqueous Dispersions of Graphitic Nanoplatelets Via the Reduction of Exfoliated Graphite Oxide in the Presence of Poly (sodium 4-styrenesulfonate)[J]. Journal of Materials Chemistry, 2006, 16 (2): 155–158CrossRefGoogle Scholar
  9. [9]
    Kim TY, Lee HW, Stoller M, et al. High-performance Supercapacitors Based on Poly (ionic liquid)-modified Graphene Electrodes[J]. ACS Nano, 2010, 5 (1): 436–442CrossRefGoogle Scholar
  10. [10]
    Hefti M, Joss L, Marx D, et al. An Experimental and Modeling Study of the Adsorption Equilibrium and Dynamics of Water Vapor on Activated Carbon[J]. Industrial & Engineering Chemistry Research, 2015, 54 (48): 12165–12176CrossRefGoogle Scholar
  11. [11]
    Liu L, Guo Z, Dai L, et al. Organic Modification of Carbon Nanotubes[J]. Chinese Science Bulletin, 2002, 47 (6): 441–447CrossRefGoogle Scholar
  12. [12]
    Ji L, Wu Y, Ma L, et al. Noncovalent Functionalization of Graphene with Pyrene-terminated Liquid Crystalline Polymer[J]. Composites Part A: Applied Science and Manufacturing, 2015, 72: 32–39CrossRefGoogle Scholar
  13. [13]
    Li MD, Wang L, Zhao B, et al. Adsorption of Humic Acid from Aqueous Solution Using Composite Magnetic Microspheres of Chitosan and Quaternary Ammonium Chitosan Derivative[J]. Applied Mechanics and Materials, 2014, 700: 216–219CrossRefGoogle Scholar
  14. [14]
    Chen YJ, Xia YL, Wang HP, et al. Preparation and Electrochemical Properties of Graphene Modified by Quaternary Ammonium Chitosan[J]. Acta Polymerica Sinica, 2015, (9): 1085–1091Google Scholar
  15. [15]
    Chen Y, Yao R, Wang Y, et al. CdS QDs-chitosan Microcapsules with Stimuli-responsive Property Generated by Gas–liquid Microfluidic Technique[J]. Colloids and Surfaces B: Biointerfaces, 2015, 125: 21–27CrossRefGoogle Scholar
  16. [16]
    Vazquez, OFG, Virgen, MDM, Montoya, VH, et al. Adsorption of Heavy Metals in the Presence of a Magnetic Field on Adsorbents with Different Magnetic Properties[J]. Industrial & Engineering Chemistry Research, 2016, 55 (34): 9323–9331CrossRefGoogle Scholar
  17. [17]
    Lagergren S. About the Theory of So-called Adsorption of Soluble Substances[J]. Handlingar, 1898, 24: 1–39Google Scholar
  18. [18]
    O’Shannessy DJ, Winzor DJ. Interpretation of Deviations from Pseudo-first-order Kinetic Behavior in the Characterization of Ligand Binding by Biosensor Technology[J]. Analytical Biochemistry, 1996, 236 (2): 275–283CrossRefGoogle Scholar
  19. [19]
    Ho YS, McKay G. Sorption of Dye from Aqueous Solution by Peat[J]. Chemical Engineering Journal, 1998, 70 (2): 115–124CrossRefGoogle Scholar
  20. [20]
    Khambhaty Y, Mody K, Basha S, et al. Pseudo-second-order Kinetic Models for the Sorption of Hg(II) Onto Dead Biomass of Marine Aspergillus Niger: Comparison of Linear and Non-linear Methods[J]. Colloids & Surfaces A: Physicochemical & Engineering Aspects, 2008, 328 (1-3): 40–43CrossRefGoogle Scholar
  21. [21]
    Lu X, Wang F, Li X, et al. Adsorption and Thermal Stabilization of Pb2+ and Cu2+ by Zeolite[J]. Industrial & Engineering Chemistry Research, 2016, 55 (32): 8767–8773CrossRefGoogle Scholar
  22. [22]
    Huang S, Liang C, Chen YJ, et al. Persulfate Chemical Functionalization of Carbon Nanotubes and Associated Adsorption Behavior in Aqueous Phase[J]. Industrial & Engineering Chemistry Research, 2016, 55(21): 6060–6068CrossRefGoogle Scholar
  23. [23]
    Geundi MSE, Nassar M, Farrag T, et al. Kinetic Models for Uptake of Pesticide (methomyl) from Aqueous Solutions Using Cotton Stalks Activated Carbon[J]. International Ground Water Technology, 2014, 4 (2): 124–134Google Scholar
  24. [24]
    El-Geundi MS, Nassar MM, Farrag TE, et al. Methomyl Adsorption onto Cotton Stalks Activated Carbon (csac): Equilibrium and Process Design[J]. Procedia Environmental Sciences, 2013, 17: 630–639CrossRefGoogle Scholar
  25. [25]
    Li K, Zheng Z, Ye L, et al. Characterization and Lead Adsorption Properties of Activated Carbons Prepared from Cotton Stalk by Onestep H3PO4 Activation[J]. Journal of Hazardous Materials, 2010, 181 (1-3): 440–447CrossRefGoogle Scholar
  26. [26]
    Klionsky DJ, Abdalla FC, Abeliovich H, et al. Guidelines for the Use and Interpretation of Assays for Monitoring Autophagy[J]. Autophagy, 2012, 8 (4): 445–544CrossRefGoogle Scholar
  27. [27]
    Kumar ASK, Kakan SS, Rajesh N, et al. A Novel Amine Impregnated Graphene Oxide Adsorbent for the Removal of Hexavalent Chromium[J]. Chemical Engineering Journal, 2013, 230: 328–337CrossRefGoogle Scholar
  28. [28]
    Ge H, Chen H, Huang S, et al. Microwave Preparation and Properties of O-crosslinked Maleic Acyl Chitosan Adsorbent for Pb2+ and Cu2+[J]. Journal of Applied Polymer Science, 2012, 125 (4): 2716–2723CrossRefGoogle Scholar

Copyright information

© Wuhan University of Technology and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Chuanhang Guo (郭传航)
    • 1
  • Mingyang Liu (刘明阳)
    • 1
  • Yuanling Xia
    • 1
  • Xiaoqiang Fan
    • 1
  • Yanjun Chen (陈艳军)
    • 1
  • Chaocan Zhang
    • 1
  1. 1.School of Material Science and EngineeringWuhan University of TechnologyWuhanChina

Personalised recommendations