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Optimized preparation of LiNi0.6Mn0.2Co0.2O2 with single crystal morphology cathode material for lithium-ion batteries

  • Bing Huang
  • Meng WangEmail author
  • Xiangwu Zhang
  • Guodong Xu
  • Yijie GuEmail author
Original Paper

Abstract

Single crystal LiNi0.6Mn0.2Co0.2O2 cathode materials with excellent electrochemical properties were synthesized by adjusting the calcination, ball milling, and reheating procedures. The results showed that the particle size of single crystal material obtained by the optimization method was 1.2–4.4 μm. And the material exhibited a superior discharge capacity of 190.1 mAh g−1 with high capacity retention of 96.0% after 50 cycles at 1.0 C. And the material had a discharge capacity of 162.6 mAh g−1 at 5.0 C with the capacity retention of 83.0% compared with its capacity at 0.1 C. The diffusion coefficient of lithium ions in the single crystal material reached to 10−13 cm2 s−1 after 50 cycles. By proper reheating process, the particle morphology was optimized to form a smooth particle surface, and the lattice arrangement was more orderly, which was conductive to improving electrochemical performance of the material.

Keywords

Single crystal morphology Primary particles Cathode material Lithium-ion diffusion Lithium-ion batteries 

Notes

Funding information

This work was supported by the National Natural Science Foundation of China (Grant Nos. 51772119 and 51202083), Natural Science Research Project of Jiangsu Higher Education Institutions (Grant Nos. 19KJB430041 and 19KJB480012), and Talent Plan for Innovation and Entrepreneurial Doctor in Jiangsu Province.

References

  1. 1.
    Yang H, Wu HH, Ge M, Li L, Yuan Y, Yao Q, Chen J, Xia L, Zheng J, Chen Z, Duan J, Kisslinger K, Zeng XC, Lee WK, Zhang Q, Lu J (2019) Simultaneously dual modification of Ni-rich layered oxide cathode for high-energy lithium-ion batteries. Adv Funct Mater 29:1808825–1808837CrossRefGoogle Scholar
  2. 2.
    Becker D, Borner B, Nolle R, Diehl M, Klein S, Rodehorst U, Schmuch R, Winter M, Placke T (2019) Surface modification of Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode material by tungsten oxide coating for improved electrochemical performance in lithium-ion batteries. ACS Appl Mater Interfaces 5:18404–18414CrossRefGoogle Scholar
  3. 3.
    Qiu L, Xiang W, Tian W, Xu C, Li YC, Wu ZG, Chen TR, Jia K, Wang D, He FR, Guo XD (2019) Polyanion and cation co-doping stabilized Ni-rich Ni-Co-Al material as cathode with enhanced electrochemical performance for Li-ion battery. Nano Energy 63:103818–103826CrossRefGoogle Scholar
  4. 4.
    Ryu WH, Lim SJ, Kim WK, Kwon HS (2014) 3-D dumbbell-like LiNi1/3Mn1/3Co1/3O2 cathode materials assembled with nano-building blocks for lithium-ion batteries. J Power Sources 257:186–191CrossRefGoogle Scholar
  5. 5.
    Manthiram A, Song B, Li W (2017) A perspective on nickel-rich layered oxide cathodes for lithium-ion batteries. Energy Storage Mater 6:125–139CrossRefGoogle Scholar
  6. 6.
    Wang L, Wu B, Mu D, Liu X, Peng Y, Xu H, Gai L, Wu F (2016) Single-crystal LiNi0.6Co0.2Mn0.2O2 as high performance cathode materials for Li-ion batteries. J Alloys Compd 674:360–367CrossRefGoogle Scholar
  7. 7.
    Zhao N, Chen J, Liu ZQ, Ban KJ, Duan WJ (2018) Porous LiNi1/3Co1/3Mn1/3O2 microsheets assembled with single crystal nanoparticles as cathode materials for lithium ion. J Alloy Compd 768:782–788CrossRefGoogle Scholar
  8. 8.
    Zeng X, Zhu J, Yang L, Zhou L, Shao L, Hu S, Huang C, Yang C, Qian D, Xi X (2019) Electrochemical stabilities of surface aluminum-doped LiNi0.5Co0.2Mn0.3O2 single crystals under different cutoff voltages. J Electroanal Chem 838:94–100CrossRefGoogle Scholar
  9. 9.
    Xu Z, Xiao L, Wang F, Wu K, Zhao L, Li MR, Zhang HL, Wu Q, Wang J (2014) Effects of precursor, synthesis time and synthesis temperature on the physical and electrochemical properties of Li(Ni1-x-yCoxMny)O2 cathode materials. J Power Sources 248:180–189CrossRefGoogle Scholar
  10. 10.
    Geder J, Hoster HE, Jossen A, Garche J, Yu DYW (2014) Impact of active material surface area on thermal stability of LiCoO2 cathode. J Power Sources 257:286–292CrossRefGoogle Scholar
  11. 11.
    Zhu X, Li X, Zhu Y, Jin S, Wang Y, Qian Y (2014) Porous LiNi0.5Mn1.5O4 microspheres with different pore conditions: preparation and application as cathode materials for lithium-ion batteries. J Power Sources 261:93–100CrossRefGoogle Scholar
  12. 12.
    Yi TF, Wang Y, Xue J, Meng J, Yue CB, Zhu RS (2011) Effect of treated temperature on structure and performance of LiCoO2 coated by Li4Ti5O12. Surf Coat Technol 205:3885–3889CrossRefGoogle Scholar
  13. 13.
    Nara H, Morita K, Mukoyama D, Yokashima T, Momma T, Osaka T (2017) Impedance analysis of LiNi1/3Mn1/3Co1/3O2 cathodes with different secondary-particle size distribution in lithium-ion battery. Electrochim Acta 241:323–330CrossRefGoogle Scholar
  14. 14.
    Zheng Z, Guo XD, Chou SL, Hua WB, Liu HK, Dou SX, Yang XS (2016) Uniform Ni-rich LiNi0.6Co0.2Mn0.2O2 porous microspheres: facile designed synthesis and their improved electrochemical performance. Electrochim Acta 191:401–410CrossRefGoogle Scholar
  15. 15.
    Huang B, Wang M, Zuo Y, Zhao Z, Zhang X, Gu Y (2020) The effects of reheating process on the electrochemical properties of single crystal LiNi0.6Mn0.2Co0.2O2. Solid State Ionics 345:115200–115208CrossRefGoogle Scholar
  16. 16.
    Jiang X, Sha Y, Cai R, Shao Z (2015) The solid-state chelation synthesis of LiNi1/3Co1/3Mn1/3O2 as a cathode material for lithium-ion batteries. J Mater Chem A 3:10536–10544CrossRefGoogle Scholar
  17. 17.
    Lee SH, Lee S, Jin BS, Kim HS (2019) Preparation and electrochemical performance of Ni-rich LiNi0.91Co0.06Mn0.03O2 cathode for high-energy LIBs. Int J Hydrog Energy 44:13684–13689CrossRefGoogle Scholar
  18. 18.
    Li N, An R, Su Y, Wu F, Bao L, Chen L, Zheng Y, Shou H, Chen S (2013) The role of yttrium content in improving electrochemical performance of layered lithium-rich cathode materials for Li-ion batteries. J Mater Chem A 1:9760–9767CrossRefGoogle Scholar
  19. 19.
    Fu C, Li G, Luo D, Li Q, Fan J, Li L (2014) Nickel-rich layered microspheres cathodes: lithium/nickel disordering and electrochemical performance. ACS Appl Mater Interfaces 6:15822–15831CrossRefGoogle Scholar
  20. 20.
    Huang Z, Wang Z, Jing Q, Guo H, Li X, Yang Z (2016) Investigation on the effect of Na doping on structure and Li-ion kinetics of layered LiNi0.6Co0.2Mn0.2O2 cathode material. Electrochim Acta 192:120–126CrossRefGoogle Scholar
  21. 21.
    Qu Y, Mo Y, Jia X, Zhang L, Du B, Lu Y, Li D, Chen Y (2019) Flux growth and enhanced electrochemical properties of LiNi0.5Co0.2Mn0.3O2 cathode material by excess lithium carbonate for lithium-ion batteries. J Alloy Compd 788:810–818CrossRefGoogle Scholar
  22. 22.
    Yi TF, Han X, Chen B, Zhu YR, Xie Y (2017) Porous sphere-like LiNi0.5Mn1.5O4-CeO2 composite with high cycling stability as cathode material for lithium-ion battery. J Alloy Compd 703:103–113CrossRefGoogle Scholar
  23. 23.
    Yang J, Hou M, Haller S, Mang Y, Wang C, Xia Y (2016) Improving the cycling performance of the layered Ni-rich oxide cathode by introducing low-content Li2MnO3. Electrochim Acta 189:101–110CrossRefGoogle Scholar
  24. 24.
    Yuan J, Wen J, Zhang J, Chen D, Zhang D (2017) Influence of calcination atmosphere on structure and electrochemical behavior of LiNi0.6Co0.2Mn0.2O2 cathode material for lithium-ion batteries. Electrochim Acta 230:116–122CrossRefGoogle Scholar
  25. 25.
    Zhang JT, Tan XH, Guo LM, Jiang Y, Liu SN, Wang HF, Kang XH, Chu WG (2019) Controllable formation of lithium carbonate surface phase during synthesis of nickel-rich LiNi0.9Mn0.1O2 in air and its protection role in electrochemical reaction. J Alloy Compd 771:42–50CrossRefGoogle Scholar
  26. 26.
    Dong S, Zhou Y, Hai C, Zeng J, Sun Y, Shen Y, Li X, Ren X, Qi G, Zhang X, Ma L (2019) Ultrathin CeO2 coating for improved cycling and rate performance of Ni-rich layered LiNi0.7Co0.2Mn0.1O2 cathode materials. Ceram Int 45:144–152CrossRefGoogle Scholar
  27. 27.
    Zhang X, Chen Z, Schwarz B, Sigel F, Ehrenberg H, An K, Zhang Z, Zhang Q, Li Y, Li J (2017) Kinetic characteristics up to 4.8 V of layered LiNi1/3Co1/3Mn1/3O2 cathode materials for high voltage lithium-ion batteries. Electrochim Acta 227:152–161CrossRefGoogle Scholar
  28. 28.
    Jo JH, Jo CH, Yashiro H, Kim SJ, Myung ST (2016) Re-heating effect of Ni-rich cathode material on structure and electrochemical properties. J Power Sources 313:1–8CrossRefGoogle Scholar
  29. 29.
    Cho DH, Jo CH, Cho W, Kim YJ, Yashiro H, Sun YK, Myung ST (2014) Effect of residual lithium compounds on layer Ni-rich Li[Ni0.7Mn0.3]O2. J Electrochem Soc 161:A920–A926CrossRefGoogle Scholar
  30. 30.
    Visbal H, Fujiki S, Aihara Y, Watanabe T, Park Y, Doo S (2016) The influence of the carbonate species on LiNi0.8Co0.15Al0.05O2 surface for all-solid-state lithium ion battery performance. J Power Sources 269:396–402CrossRefGoogle Scholar
  31. 31.
    Ding Y, Deng B, Wang H, Li X, Chen T, Yan X, Wan Q, Qu M, Peng G (2019) Improved electrochemical performances of LiNi0.6Co0.2Mn0.2O2 cathode material by reducing lithium residues with the coating of Prussian blue. J Alloy Compd 774:451–460CrossRefGoogle Scholar
  32. 32.
    Kim J, Lee H, Cha H, Yoon M, Park M, Cho J (2018) Prospect and reality of Ni-rich cathode for commercialization. Adv Energy Mater 8:1702028–1702053CrossRefGoogle Scholar
  33. 33.
    Zhang XL, Cheng FY, Zhang K, Liang YL, Yang SQ, Liang J, Chen J (2012) Facile polymer-assisted synthesis of LiNi0.5Mn0.5O4 with a hierarchical micro-nanostructure and high rate capability. RSC Adv 2:5669–5675CrossRefGoogle Scholar
  34. 34.
    He W, Yuan DD, Qian JF, Ai XP, Yang HX, Cao YL (2013) Enhanced high-rate capability and cycling stability of Na-stabilized layered Li1.2[Co0.13Ni0.13Mn0.54]O2 cathode material. J Mater Chem A 1:11397–11403CrossRefGoogle Scholar
  35. 35.
    Li L, Chen Z, Zhang Q, Xu M, Zhou X, Zhu H, Zhang K (2015) A hydrolysis-hydrothermal route for the synthesis of ultrathin LiAlO2-inlaid LiNi0.5Co0.2Mn0.3O2 as a high-performance cathode material for lithium ion batteries. J Mater Chem A 3:894–904CrossRefGoogle Scholar
  36. 36.
    Wang M, Gong Y, Gu Y, Chen Y, Chen L, Shi H (2019) Effects of fast lithium-ion conductive coating layer on the nickel rich layered oxide cathode material. Ceram Int 45:3177–3185CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2020

Authors and Affiliations

  1. 1.Institute of New Energy on Chemical Storage and Power SourcesYancheng Teachers UniversityYanchengChina
  2. 2.Wilson College of TextilesNorth Carolina State UniversityRaleighUSA
  3. 3.China Academy of Machinery Science and Technology Group Co. Ltd.BeijingChina
  4. 4.School of Mechanical-Electronic and Vehicle EngineeringWeifang UniversityWeifangChina

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